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Daniel A. Deeds Martin K. Vollmer Justin T. Kulongoski Benjamin R. Miller 《Geochimica et cosmochimica acta》2008,72(4):999-1013
Dissolved tetrafluoromethane (CF4) and sulfur hexafluoride (SF6) concentrations were measured in groundwater samples from the Eastern Morongo Basin (EMB) and Mojave River Basin (MRB) located in the southern Mojave Desert, California. Both CF4 and SF6 are supersaturated with respect to equilibrium with the preindustrial atmosphere at the recharge temperatures and elevations of the Mojave Desert. These observations provide the first in situ evidence for a flux of CF4 from the lithosphere. A gradual basin-wide enhancement in dissolved CF4 and SF6 concentrations with groundwater age is consistent with release of these gases during weathering of the surrounding granitic alluvium. Dissolved CF4 and SF6 concentrations in these groundwaters also contain a deeper crustal component associated with a lithospheric flux entering the EMB and MRB through the underlying basement. The crustal flux of CF4, but not of SF6, is enhanced in the vicinity of local active fault systems due to release of crustal fluids during episodic fracture events driven by local tectonic activity. When fluxes of CF4 and SF6 into Mojave Desert groundwaters are extrapolated to the global scale they are consistent, within large uncertainties, with the fluxes required to sustain the preindustrial atmospheric abundances of CF4 and SF6. 相似文献
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Benjamin A.S Van Mooy Richard G KeilAllan H Devol 《Geochimica et cosmochimica acta》2002,66(3):457-465
Fluxes of particulate organic carbon (POC) through the oxygen deficient waters in the eastern tropical North Pacific were found to be relatively less attenuated with depth than elsewhere in the eastern North Pacific. The attenuation coefficient (b) for the flux was found to be 0.40 versus the composite value of 0.86 determined by Martin et al. (1987). To examine this further, sinking POC was collected using sediment traps and allowed to degrade in oxic and suboxic experiments. Using a kinetic model, it was found that degradation proceeded at similar rates (roughly 0.8 day−1) under oxic and suboxic conditions, but a greater fraction of bulk POC was resistant to degradation in the suboxic experiments (61% vs. 23%). Amino acids accounted for 37% of POC collected at 75m, but following degradation the value dropped to 17% and 16% in the oxic and suboxic experiments respectively. POC collected from 500m was 10% amino acids. The non-AA component of POC collected at 75m was not degraded under suboxic conditions, while under oxic conditions it was. These results suggest that microbes degrading OC under suboxic conditions via denitrification preferentially utilize nitrogen-rich amino acids. This preferential degradation of amino acids suggests that 9% more nitrogen may be lost via water column denitrification than is accounted for when a more “Redfieldian” stoichiometry for POC is assumed. 相似文献
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Benjamin J. Kadlec David A. Yuen Xili L. Yang Evan F. Bollig Yunsong Wang Gordon Erlebacher Maxwell Rudolph 《Visual Geosciences》2004,9(1):61
We report here our experiences from using easily acquired web-cam components for collaborative ventures in the Earth sciences. We have used a variety of hardware and different software. We demonstrate from various locations in the U.S.A. the feasibility of using web-cam in multitudinous activities, relevant for conducting research and knowledge dissemination. We summarize the quality of the connections from the various combinations of communicating parties. Today, web-cams can be utilized as an economical and viable means of point-to-point communication in the Earth science community. Greater bandwidth is sorely needed for activities such as multi-party conferencing on the present internet network. We propose that web-cam can be readily deployed as a web-service for facilitating collaborative research over the GRID infrastructure, using the middleware Narada-Brokering. Web-cam will play an important role in the emerging field of geoinformatics. 相似文献
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Urban land transformation for pro-poor economies 总被引:1,自引:0,他引:1
Solomon Benjamin 《Geoforum》2004,35(2):177-187
The transformation of land into a setting for clustering local economies can become an important cornerstone of poverty policy. This transformation has several functional aspects, which in turn have important institutional and political aspects. Underlying both the functional and institutional factors is the role of local government and local democracy. Such a conceptualization puts to center stage several paradoxes: A terrain that seems “slum-like” turns out to be highly productive and employment generating. Complex tenure forms and mixed land use seen as “unplanned” turn out to be pre-requisites for economic development. There are institutional paradoxes that contrast efforts at “transparency” and managerial “best practices”. Here, the messiness of local bureaucracies in municipal government turns out to be critical for poor groups to influence interventions in their favor. Influencing the public process may be more effective in stealth-like ways rather taking a more visible approach. Most fundamentally these issues remind us that the potential of cities to reinforce or reduce poverty moved far beyond projects and programs and the normative frameworks used by planners and administrators. Instead, it is the transformative process of turning land into economic settings that might be at the center stage. This is a stage where poor groups are the central actors who stealth-like draw on complex alliances across ethnic and class lines to shapes cities in their interests. 相似文献
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Is the prospect of possible climate change relevant to water resources decisions being made today? And, if so, how ought that prospect be considered? These questions can be addressed by decision analysis, which we apply to two investments in the Great Lakes region: a regulatory structure for Lake Erie, and breakwaters to protect Presque Isle State Park, PA. These two decisions have the elements that potentially make climate change relevant: long lived, "one shot" investments; benefits or costs that are affected by climate-influenced variables; and irreversibilities. The decision analyses include the option of waiting to obtain better information, using Bayesian analysis to detect whether climate change has altered water supplies. The analyses find that beliefs about climate change can indeed affect optimal decisions. Furthermore, ignoring the possibility of climate change can lead to significant opportunity losses—in the cases here, as much as 10% or more of the construction cost. Yet the consequences of climate uncertainty for Great Lakes management do not appear to be qualitatively different from those of other risks, and thus do not deserve different treatment. The methods of sensitivity analysis, scenario planning, and decision analysis, all of which are encouraged under US federal guidelines for water planning, are applicable. We recommend increased use of decision trees and Bayesian analysis to consider not only climate change risks, but also other important social and environmental uncertainties. 相似文献
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Current designs for nuclear-waste repositories rely primarily upon subsurface geologic barriers for long-term containment. Because water and air are generally considered to be the mechanisms most likely to transport radioactivity to the surface environment, flow and transport models are important tools in repository assessment. Most models assume that the geologic medium can be treated as a continuum. A substantial body of recent work has focused on applying these models to difficult-to-solve problems, such as the simulation of variably dense or variably saturated flow and transport, large and complex flow systems, sharp solute concentration fronts, and fractured rock systems. The complex chemical interactions between the transport fluid and solid particles within the system have been analyzed using geochemical flow models, most of which assume that the system is at chemical equilibrium. The role of colloids in contaminant transport is a relatively new area of research. The large-scale effects of small-scale variability within the geologic system have been the subject of intense investigation. Inherent limitations of the continuum approach have prompted the design of models in which the flow occurs in discrete fractures. The difficulty and complexity of simulating transport has led to the development of network transport models, which represent the flow field as a series of 1-D path segments. The widespread use of models for prediction and analysis has prompted investigations of their reliability and relative merits. 相似文献
10.
Secondary ferrimagnetic minerals in Welsh soils: a comparison of mineral magnetic detection methods and implications for mineral formation 总被引:20,自引:0,他引:20
J. A. Dearing P. M. Bird R. J. L. Dann S. F. Benjamin 《Geophysical Journal International》1997,130(3):727-736
A study of mineral magnetic parameters was carried out on a Late Pleistocene and Holocene sedimentary sequence (of nearly 18 m) from Lake Bledowo (central Poland). Sediments of Lake Bledowo have already been analysed for bulk sediment mineralogy and biogenic materials. The mineral magnetic stratigraphy confirms the major changes in palaeo-environmental conditions that have been deduced from other methods. The most important mineral magnetic change results from the authigenetic formation of ferrimagnetic greigite, Fe3 S4 , during the beginning of lacustrine conditions (± 12 000 yr BP). Our data also indicate a detrital origin of overlying ferrimagnetic iron oxides. It is suggested that they originate from brown soils developed on the boulder clay constituting the west side of the lake shore. Variations of ferrimagnetic iron oxide size are related to the early diagenetic processes in the sediment. Larger particles are present in periods with early diagenesis of organic matter in anoxic conditions. This indicates the dissolution of fine magnetic particles by iron-oxide-reducing bacteria and results in homogeneous magnetic grain sizes, despite their origin from soils, characterized by a multimodal grain-size distribution. 相似文献