Saraca indica leaf powder for decontamination of Pb: removal, recovery, adsorbent characterization and equilibrium modeling

The present study explores the effectiveness of Saraca indica leaf powder, a surplus low value agricultural waste, in removing Pb ions from aqueous solution. The influence of pH, biomass dosage, contact time, particle size and metal concentration on the removal process were investigated. Batch studies indicated that maximum biosorption capacity for Pb was 95.37% at the pH 6.5. The sorption process followed the first order rate kinetics. The adsorption equilibrium data fitted best to both Langmuir and Freundlich isotherms. Morphological changes observed in scanning electron micrographs of untreated and metal treated biomass confirmed the phenomenon of biosorption. Fourier transform infrared spectroscopy of native and exhausted leaf powder confirmed lead biomass interactions responsible for sorption. Acid regeneration was tried for several cycles with a view to recover the sorbed metal ion and also to restore the sorbent to its original state. The findings showed that Saraca indica leaf powder can easily be envisaged as a new, vibrant, low cost biosorbent for metal clean up operations.     

Mixed-layer characteristics as related to the monsoon climate of New Delhi,India

Annual variations of mixed-layer characteristics at New Delhi, India have been studied for a weak monsoon (1987) and a strong monsoon (1988) year. In the weak monsoon year (1987), the maximum mixing depthh _max was found to have a value of around 3000 m during the pre-monsoon, less than 2000 m during the summer monsoon, around 2000 m during the post-monsoon, and less than 1000 m in the winter season. For the strong monsoon year (1988),h _max values were less than 1987 values for comparable periods throughout the year. The seasonal and yearly differences ofh _max were explained by the surface energy balance and potential temperature gradient at a time close to sunrise. According to the spatial patterns of obtained by an objective analysis of the 850 to 700 hPa layers. mixed-layer characteristics obtained at New Delhi are representative of the north and central regions of India.     

Classification and Potential Utilization of Eocene Coals of Meghalaya,North East India

In the present study, petrographic and geochemical investigation of Meghalayan coal deposits have been carried out to classify these coals in terms of rank, type and grade, using Indian and International classification schemes. Based on petrographic and geochemical characteristics, an attempt has also been made to identify the potential utilization of Meghalayan coals for various industrial applications. According to the study, these coals have been classified as sub-bituminous C to high volatile bituminous in rank, vitric in type and clean to ashy in grade. Considering their hydrocarbon potential, these coals are suitable for liquefaction and gasification.     

A Preliminary Evaluation on the Prospects of Hydrocarbon Potential in the Carbonaceous Shales of Spiti and Chikkim Formations,Tethys Himalaya,India

In the present investigation, an attempt has been made to explore the possibility of hydrocarbon prospects in the carbonaceous shale deposits of Spiti and Chikkim formations exposed in the Spiti valley of the Tethys Himalaya. Twenty samples, collected from successive levels of these litho-units, have been subjected to maceral analysis, Rock-Eval Pyrolysis and six samples to Fourier Transform Infra-red Spectroscopy (FTIR) and nuclear magnetic resonance (NMR) analyses. The study reveals the presence of mainly kerogen-III type of organic matter but some of the shale samples have shown a good amount of total organic carbon (TOC) to the tune of 3.19% which is sufficient to produce hydrocarbon. The results indicate the presence of methane occurring as free and fixed hydrocarbon in the shale samples. Few levels are especially rich in hydrocarbon. They have shown encouraging results with potential for generating liquid as well as lighter hydrocarbon. The data is also supported by the FTIR and NMR studies.     

Upper ocean high resolution regional modeling of the Arabian Sea and Bay of Bengal

In this paper, effort is made to demonstrate the quality of high-resolution regional ocean circulation model in realistically simulating the circulation and variability properties of the northern Indian Ocean(10°S–25°N,45°–100°E) covering the Arabian Sea(AS) and Bay of Bengal(BoB). The model run using the open boundary conditions is carried out at 10 km horizontal resolution and highest vertical resolution of 2 m in the upper ocean.The surface and sub-surface structure of hydrographic variables(temperature and salinity) and currents is compared against the observations during 1998–2014(17 years). In particular, the seasonal variability of the sea surface temperature, sea surface salinity, and surface currents over the model domain is studied. The highresolution model's ability in correct estimation of the spatio-temporal mixed layer depth(MLD) variability of the AS and BoB is also shown. The lowest MLD values are observed during spring(March-April-May) and highest during winter(December-January-February) seasons. The maximum MLD in the AS(BoB) during December to February reaches 150 m (67 m). On the other hand, the minimum MLD in these regions during March-April-May becomes as low as 11–12 m. The influence of wind stress, net heat flux and freshwater flux on the seasonal variability of the MLD is discussed. The physical processes controlling the seasonal cycle of sea surface temperature are investigated by carrying out mixed layer heat budget analysis. It is found that air-sea fluxes play a dominant role in the seasonal evolution of sea surface temperature of the northern Indian Ocean and the contribution of horizontal advection, vertical entrainment and diffusion processes is small. The upper ocean zonal and meridional volume transport across different sections in the AS and BoB is also computed. The seasonal variability of the transports is studied in the context of monsoonal currents.     

Assessment of Thermal Maturity,Source Rock Potential and Paleodepositional Environment of the Paleogene Lignites in Barsingsar,Bikaner–Nagaur Basin,Western Rajasthan,India

Natural Resources Research - Investigations on the Paleogene lignites were carried out through geochemical, mineralogical and petrographic analyses to assess their paleodepositional environment,...     

Upper Ocean Four-Dimensional Variational Data Assimilation in the Arabian Sea and Bay of Bengal

A regional ocean circulation model with four-dimensional variational data assimilation scheme is configured to study the ocean state of the Indian Ocean region (65°E–95°E; 5°N–20°N) covering the Arabian Sea (AS) and Bay of Bengal (BoB). The state estimation setup uses 10 km horizontal resolution and 5 m vertical resolution in the upper ocean. The in-situ temperature and salinity, satellite-derived observations of sea surface height, and blended (in-situ and satellite-derived) observations of sea surface temperature alongwith their associated uncertainties are used for data assimilation with the regionally configured ocean model. The ocean state estimation is carried out for 61 days (1 June to 31 July 2013). The assimilated fields are closer to observations compared to other global state estimates. The mixed layer depth (MLD) of the region shows deepening during the period of assimilation with AS showing higher MLD compared to the BoB. An empirical forecast equation is derived for the prediction of MLD using the air–sea forcing variables as predictors. The surface and sub-surface (50 m) heat and salt budget tendencies of the region are also investigated. It is found that at the sub-surface, only the advection and diffusion temperature and salt tendencies are important.     

Imaging Spectropolarimeter for the Multi-Application Solar Telescope at Udaipur Solar Observatory: Characterization of Polarimeter and Preliminary Observations

The Multi-Application Solar Telescope (MAST) is a 50 cm off-axis Gregorian telescope that has recently become operational at the Udaipur Solar Observatory (USO). An imaging spectropolarimeter is being developed as one of the back-end instruments of MAST to gain a better understanding of the evolution and dynamics of solar magnetic and velocity fields. This system consists of a narrow-band filter and a polarimeter. The polarimeter includes a linear polarizer and two sets of liquid crystal variable retarders (LCVRs). The instrument is intended for simultaneous observations in the spectral lines 6173 Å and 8542 Å, which are formed in the photosphere and chromosphere, respectively. In this article, we present results from the characterization of the LCVRs for the spectral lines of interest and the response matrix of the polarimeter. We also present preliminary observations of an active region obtained using the spectropolarimeter. For verification purposes, we compare the Stokes observations of the active region obtained from the Helioseismic Magnetic Imager (HMI) onboard the Solar Dynamics Observatory (SDO) with that of MAST observations in the spectral line 6173 Å. We find good agreement between the two observations, considering the fact that MAST observations are limited by seeing.