Upper limits to trace constituents in Jupiter's atmosphere from an analysis of its 5-μm spectrum

A high-resolution (0.6 cm^?1) spectrum of Jupiter at 5 μm recorded at the Kuiper Airborne Observatory is used to determine upper limits to the column density of 19 molecules. The upper limits to the mixing ratios of SiH₄, H₂S, HCN, and simple hydrocarbons are discussed with respect to current models of Jupiter's atmosphere. These upper limits are compared to expectations based upon the solar abundance of the elements. This analysis permits upper limit measurements (SiH₄), or actual detections (GeH₄), of molecules with mixing ratios with hydrogen as low as 10^?9. In future observations at 5 μm the sensitivity of remote spectroscopic analyses should permit the study of constituents with mixing ratios as low as 10^?10, which would include the hydrides of such elements as Sn and As as well as numerous organic molecules.     

The age of the Roter Kamm impact crater,Namibia: Constraints from 40Ar-39Ar,K-Ar,Rb-Sr,fission track,and 10Be-26Al studies

Abstract The well-preserved 2.5 km diameter Roter Kamm impact crater is located in the Namib desert in Namibia. The impact has occurred in Precambrian granitic and granodioritic orthogneisses of the 1200–900 Ma old Namaqualand Metamorphic Complex which were partly covered by Gariep metasediments; the granites are invaded by quartz veins and quartz-feldspar-pegmatites. Previous geological field evidence suggested a crater age of about 5–10 Ma. In order to constrain this age, we selected a set of basement rocks (granites, granodiorites) exposed at the crater rim and studied the Rb-Sr, K-Ar, ⁴⁰Ar-³⁹Ar, and ¹⁰Be-²⁶Al isotopic systems as well as apatite fission track ages of these samples. The Rb-Sr isotopic systematics confirm the derivation of these samples from the Namaqualand basement (age about 1.29 Ga), which underwent Damaran orogenesis at about 650 Ma. No basement rocks with Rb-Sr ages younger than about 410 Ma were identified. The K-Ar ages of pseudotachylite and melt breccia samples show that these samples are dominated by incompletely degassed fragments of basement rocks, with some retaining their original metamorphic ages of about 470 Ma. The apatite fission track ages range from 20–28 Ma, which may be interpreted as an extension of the 25 Ma Burdigalian peneplanation event, or as incomplete resetting of the apatite fission tracks during the impact event. The ¹⁰Be and ²⁶Al exposure age of a quartz sample isolated from a quartz-pegmatite was found to be 150 ka; it is likely that the exposure of the sample began after material covering it had been removed by erosion 150 ka ago. Two glassy fractions extracted from a rim granite were dated by ⁴⁰Ar-³⁹Ar analysis. One sample gives practically a plateau age of 3.7 ± 0.3 Ma, while the other gives a minimum age of 3.6 Ma. The best available age estimate for the Roter Kamm crater is therefore 3.7 ± 0.3 Ma.     

Geochemical studies of the SUBO 18 (Enkingen) drill core and other impact breccias from the Ries crater,Germany

Suevite and melt breccia compositions in the boreholes Enkingen and Polsingen are compared with compositions of suevites from other Ries boreholes and surface locations and discussed in terms of implications for impact breccia genesis. No significant differences in average chemical compositions for the various drill cores or surface samples are noted. Compositions of suevite and melt breccia from southern and northeastern sectors of the Ries crater do not significantly differ. This is in stark contrast to the published variations between within‐crater and out‐of‐crater suevites from northern and southern sectors of the Bosumtwi impact structure, Ghana. Locally occurring alteration overprint on drill cores—especially strong on the carbonate‐impregnated suevite specimens of the Enkingen borehole—does affect the average compositions. Overall, the composition of the analyzed impact breccias from Ries are characterized by very little macroscopically or microscopically recognized sediment‐clast component; the clast populations of suevite and impact melt breccia are dominated consistently by granitic and intermediate granitoid components. The Polsingen breccia is significantly enriched in a dioritic clast component. Overall, chemical compositions are of intermediate composition as well, with dioritic‐granodioritic silica contents, and relatively small contributions from mafic target components. Selected suevite samples from the Enkingen core have elevated Ni, Co, Cr, and Ir contents compared with previously analyzed suevites from the Ries crater, which suggest a small meteoritic component. Platinum‐group element (PGE) concentrations for some of the enriched samples indicate somewhat elevated concentrations and near‐chondritic ratios of the most immobile PGE, consistent with an extraterrestrial contribution of 0.1–0.2% chondrite‐equivalent.     

Scanning electron microscopy,cathodoluminescence, and Raman spectroscopy of experimentally shock‐metamorphosed quartzite

Abstract— We studied unshocked and experimentally (at 12, 25, and 28 GPa, with 25, 100, 450, and 750°C pre‐shock temperatures) shock‐metamorphosed Hospital Hill quartzite from South Africa using cathodoluminescence (CL) images and spectroscopy and Raman spectroscopy to document systematic pressure or temperature‐related effects that could be used in shock barometry. In general, CL images of all samples show CL‐bright luminescent patchy areas and bands in otherwise nonluminescent quartz, as well as CL‐dark irregular fractures. Fluid inclusions appear dominant in CL images of the 25 GPa sample shocked at 750°C and of the 28 GPa sample shocked at 450°C. Only the optical image of our 28 GPa sample shocked at 25°C exhibits distinct planar deformation features (PDFs). Cathodoluminescence spectra of unshocked and experimentally shocked samples show broad bands in the near‐ultraviolet range and the visible light range at all shock stages, indicating the presence of defect centers on, e.g., SiO₄ groups. No systematic change in the appearance of the CL images was obvious, but the CL spectra do show changes between the shock stages. The Raman spectra are characteristic for quartz in the unshocked and 12 GPa samples. In the 25 and 28 GPa samples, broad bands indicate the presence of glassy SiO₂, while high‐pressure polymorphs are not detected. Apparently, some of the CL and Raman spectral properties can be used in shock barometry.     

Geochemical evidence of an extraterrestrial component in impact melt breccia from the Paleoproterozoic Dhala impact structure,India

The Paleoproterozoic Dhala structure with an estimated diameter of ~11 km is a confirmed complex impact structure located in the central Indian state of Madhya Pradesh in predominantly granitic basement (2.65 Ga), in the northwestern part of the Archean Bundelkhand craton. The target lithology is granitic in composition but includes a variety of meta‐supracrustal rock types. The impactites and target rocks are overlain by ~1.7 Ga sediments of the Dhala Group and the Vindhyan Supergroup. The area was cored in more than 70 locations and the subsurface lithology shows pseudotachylitic breccia, impact melt breccia, suevite, lithic breccias, and postimpact sediments. Despite extensive erosion, the Dhala structure is well preserved and displays nearly all the diagnostic microscopic shock metamorphic features. This study is aimed at identifying the presence of an impactor component in impact melt rock by analyzing the siderophile element concentrations and rhenium‐osmium isotopic compositions of four samples of impactites (three melt breccias and one lithic breccia) and two samples of target rock (a biotite granite and a mafic intrusive rock). The impact melt breccias are of granitic composition. In some samples, the siderophile elements and HREE enrichment observed are comparable to the target rock abundances. The Cr versus Ir concentrations indicate the probable admixture of approximately 0.3 wt.% of an extraterrestrial component to the impact melt breccia. The Re and Os abundances and the ¹⁸⁷Os/¹⁸⁸Os ratio of 0.133 of one melt breccia specimen confirm the presence of an extraterrestrial component, although the impactor type characterization still remains inconclusive.     

Multi-stage reaction history in different eclogite types from the Pakistan Himalaya and implications for exhumation processes

Metabasites were sampled from rock series of the subducted margin of the Indian Plate, the so-called Higher Himalayan Crystalline, in the Upper Kaghan Valley, Pakistan. These vary from corona dolerites, cropping out around Saif-ul-Muluk in the south, to coesite–eclogite close to the suture zone against rocks of the Kohistan arc in the north. Bulk rock major- and trace- element chemistry reveals essentially a single protolith as the source for five different eclogite types, which differ in fabric, modal mineralogy as well as in mineral chemistry. The study of newly-collected samples reveals coesite (confirmed by in situ Raman spectroscopy) in both garnet and omphacite. All eclogites show growth of amphiboles during exhumation. Within some coesite-bearing eclogites the presence of glaucophane cores to barroisite is noted whereas in most samples porphyroblastic sodic–calcic amphiboles are rimmed by more aluminous calcic amphibole (pargasite, tschermakite, and edenite). Eclogite facies rutile is replaced by ilmenite which itself is commonly surrounded by titanite. In addition, some eclogite bodies show leucocratic segregations containing phengite, quartz, zoisite and/or kyanite. The important implication is that the complex exhumation path shows stages of initial cooling during decompression (formation of glaucophane) followed by reheating: a very similar situation to that reported for the coesite-bearing eclogite series of the Tso Morari massif, India, 450 km to the south-east.     

Shock deformation confirms the impact origin for the Cerro do Jarau,Rio Grande do Sul,Brazil, structure

Cerro do Jarau is a conspicuous, circular morpho‐structural feature in Rio Grande do Sul State (Brazil), with a central elevated core in the otherwise flat “Pampas” terrain typical for the border regions between Brazil and Uruguay. The structure has a diameter of approximately 13.5 km. It is centered at 30^o12′S and 56^o32′W and was formed on basaltic flows of the Cretaceous Serra Geral Formation, which is part of the Paraná‐Etendeka Large Igneous Province (LIP), and in sandstones of the Botucatu and Guará formations. The structure was first spotted on aerial photographs in the 1960s. Ever since, its origin has been debated, sometimes in terms of an endogenous (igneous) origin, sometimes as the result of an exogenous (meteorite impact) event. In recent years, a number of studies have been conducted in order to investigate its nature and origin. Although the results have indicated a possible impact origin, no conclusive evidence could be produced. The interpretation of an impact origin was mostly based on the morphological characteristics of the structure; geophysical data; as well as the occurrence of different breccia types; extensive deformation/silicification of the rocks within the structure, in particular the sandstones; and also on the widespread occurrence of low‐pressure deformation features, including some planar fractures (PFs). A detailed optical microscopic analysis of samples collected during a number of field campaigns since 2007 resulted in the disclosure of a large number of quartz grains from sandstone and monomict arenite breccia from the central part of the structure with PFs and feather features (FFs), as well as a number of quartz grains exhibiting planar deformation features (PDFs). While most of these latter grains only carry a single set of PDFs, we have observed several with two sets, and one grain with three sets of PDFs. Consequently, we here propose Cerro do Jarau as the seventh confirmed impact structure in Brazil. Cerro do Jarau, together with Vargeão Dome (Santa Catalina state) and Vista Alegre (Paraná State), is one of very few impact structures on Earth formed in basaltic rocks.