Analysis of Triphenyltin in Fish

A procedure to analyse triphenyltin and other organotins in fish tissues is described. The method consists of the following steps: homogenization of the fish, extraction by heating under reflux in a water/hexane mixture, centrifugation, separation of the hexane layer followed by reduction of the volume by evaporation, methylation of the organotin with a Grignard reaction, clean-up of the fish extract by column chromatography, and detection by gas chromatography with flame photometric detection. The extraction was carried out without adding acid or base to the aqueous phase, as the extraction efficiency was independent of pH. The methylation was successfully carried out in the fish extract. For clean-up of the fish extract a florisil column was used, from which the triphenylmethyltin was eluted with hexane. Using this method, triphenyltin has a recovery of 77 ± 10%, with a limit of detection of 0·8 ng/g for 0·1 g fish samples.     

Comparative Assessment of Sludge Pre‐Treatment Techniques to Enhance Sludge Dewaterability and Biogas Production

Effectiveness of ultrasonication, microwave technologies, and enzyme addition prior to anaerobic digestion is investigated using sludge samples taken from the secondary settling tank of a domestic wastewater treatment plant to improve methane production, enhance dewaterability characteristics of the sludge, and to reduce excess sludge. Microwave pre‐treatment (1500 W, 10 min at 175 °C) results in better extra digester performance (compared to the control reactor) in terms of methane production (25 m³ ton^?1 suspended solids (SS)) than ultrasound (no improvement) and enzyme pre‐treatment (11 m³ ton^?1 SS). While methane production is not improved as a result of ultrasonication pre‐treatment (15 000 kJ kg^?1 SS), a noticeable increase (19%) is observed in the case of microwave pre‐treatment. Higher compactibility values are obtained after ultrasonication and microwave application compared to the control (i.e., from 7.1 to 8.7 and 9.2%, respectively) before anaerobic digestion. Although ultrasonication and microwave application decrease the dewaterability of the raw sludge (capillary suction time (CST) from 827 to 1364 and 2290 s, respectively), similar dewaterability results are obtained at the end of the anaerobic digestion process for all pre‐treated sludge samples. An economic assessment of this study shows that pre‐treatment with microwave results in more than 10‐fold less net cost compared to the enzyme application.     

Phytoplankton as an Indicator of Improving Water Quality in the Golden Horn Estuary

The variation in phytoplankton community as a response to improving water quality has been studied in the severely polluted Golden Horn Estuary (GHE). Phytoplankton data collected monthly for 4 years and a detailed set of environmental parameters clearly showed the remarkable change in the GHE. The GHE ecosystem did not respond to numerous rehabilitation efforts to improve water quality, unless strict measures were taken to enhance water circulation. The opening of a bridge operating on large buoys and release of high amounts of fresh water from a dam acted as the turning point for the whole system. The weakening of light limitation and anoxia at upper regions is followed by consecutive blooms of different species/groups and resulted in super-saturated dissolved oxygen concentrations and a significant decrease in nutrient concentrations. When compared to the pre-remediation period, average total eukaryotic phytoplankton abundance increased 11-fold in the lower estuary, while the increase in the upper estuary was over 3 × 10⁴ in the post-remediation period. In addition, species richness continuously increased through the study period and community structure showed very strong variability. Since the estuarine ecosystem is controlled by precipitation in the last decade, the increase in anthropogenic/terrestrial inputs following heavy rainfall had adversely affected water quality and phytoplankton.     

Challenges in developing effective policy for soil carbon sequestration: perspectives on additionality,leakage, and permanence

If carbon sequestration is to be a cost-effective substitute for reducing emissions then it must occur under a framework that ensures that the sequestration is additional to what would otherwise have occurred, the carbon is stored permanently, and any leakage is properly accounted for. We discuss significant challenges in meeting these requirements, including some not previously recognized. Although we focus on sequestration in soil, many of the issues covered are applicable to all types of sequestration. The common-practice method for determining additionality achieves its intention of reducing transaction costs in the short term but not in the medium to long term. Its design results in the least costly, additional abatement-measures being excluded from policy support and fails to address how, in the case of sequestration, revisions to the additionality of sequestering practices should apply not just to the future, but in theory, also retrospectively. Permanence is sometimes approximated as 100 years of sequestration. Re-release of sequestered carbon after this will not only reverse the sequestration, but may raise atmospheric carbon to higher levels than they would have been if the sequestration had never occurred. Leakage associated with sequestration practices can accumulate over time to exceed the total level of sequestration; nonetheless, adoption of such practices can be attractive to landholders, even when they are required to pay for this leakage at contemporary prices.

Policy relevance

Globally, much has been written and claimed about the ability to offset emissions with sequestration. The Australian Government plans to use sequestration to source much of the abatement required to reach its emissions targets. Designing effective policy for sequestration will be challenging politically, and will involve substantial transaction costs. Compromises in policy design intended to make sequestration attractive and reduce transaction costs can render it highly inefficient as a policy.     

Fate and biodegradability potential of an emerging micropollutant diclofenac in subsurface environment

The present study deals with the assessment of the fate of an emerging contaminant (diclofenac), present in the subsurface environment at specific concentration levels, and its biodegradation potential under different environmental configurations. Diclofenac is a widely consumed nonsteroidal anti-inflammatory drug used as a painkiller prescribed as pills or ointments and among the most frequently detected pharmaceuticals in wastewater treatment plants’ effluents. Fermentative/methanogenic cultures were enriched from previously contaminated sediment samples. Although partial biodegradation was achieved in all enrichment cultures, complete degradation was not observed. The results reflected that less than 6% of the diclofenac sorbed on the solid phase and the rest was either biotransformed (25–40%) or remained in the liquid phase (55–70%) at the end of 45-day incubation period. Although partial cometabolic degradation of diclofenac occurred in the presence of glucose, biodegradation was not observed in the presence of readily biodegradable carbon source (i.e., acetate). Diclofenac concentration up to 1000 µg/L did not affect the methanogenic activity of the enriched culture. The results of this study will have a significant impact in the designation of the permitted concentration limits of diclofenac before the discharge through wastewater treatment plants.     

A reconstruction of extratropical Indo-Pacific sea-level pressure patterns during the Medieval Climate Anomaly

Subtropical and extratropical proxy records of wind field, sea level pressure (SLP), temperature and hydrological anomalies from South Africa, Australia/New Zealand, Patagonian South America and Antarctica were used to reconstruct the Indo-Pacific extratropical southern hemisphere sea-level pressure anomaly (SLPa) fields for the Medieval Climate Anomaly (MCA ~700–1350 CE) and transition to the Little Ice Age (LIA 1350–1450 CE). The multivariate array of proxy data were simultaneously evaluated against global climate model output in order to identify climate state analogues that are most consistent with the majority of proxy data. The mean SLP and SLP anomaly patterns derived from these analogues illustrate the evolution of low frequency changes in the extratropics. The Indo-Pacific extratropical mean climate state was dominated by a strong tropical interaction with Antarctica emanating from: (1) the eastern Indian and south-west Pacific regions prior to 1100 CE, then, (2) the eastern Pacific evolving to the central Pacific La Niña-like pattern interacting with a +ve SAM to 1300 CE. A relatively abrupt shift to –ve SAM and the central Pacific El Niño-like pattern occurred at ~1300. A poleward (equatorward) shift in the subtropical ridge occurred during the MCA (MCA–LIA transition). The Hadley Cell expansion in the Australian and Southwest Pacific, region together with the poleward shift of the zonal westerlies is contemporaneous with previously reported Hadley Cell expansion in the North Pacific and Atlantic regions, and suggests that bipolar climate symmetry was a feature of the MCA.     

Magnetic scanning and interpretation of paleomagnetic data from Prague Synform’s volcanics

Magnetic images have been produced at the distance of 0.1 mm from the polished basaltic thin sections of rocks from Prague Synform in Barrandian area. Three different magnetic textures were seen and when combined with optical imaging could be related to petrological features. The first magnetic texture revealed that most of the magnetic signature is localized within the amygdales formed later after the basalts became part of the sedimentary sequence. The second texture showed that the basaltic body contains large grain size distribution of magnetic carriers possibly with variable viscous magnetizations. The third texture suggested a presence of magnetic anisotropy of igneous origin. Such textural magnetic information along with the paleomagnetic characteristics of the basaltic rocks of Silurian age constrained the overall geological interpretation.     

Prevention of Wellbore Clogging by Intermittent Abstraction

Wellfield “Tull en ’t Waal” (water utility Vitens Midden Nederland) suffers extensively from wellbore (or mechanical) clogging. To prevent this type of clogging, wells have been operated intermittently since August 2005 using a carrousel well operation schedule. Since the introduction of this schedule, wellbore clogging has become minimal.