Argon and nitrogen isotopes of trapped air in the GISP2 ice core during the Holocene epoch (0-11,500 B.P.): Methodology and implications for gas loss processes

Argon and nitrogen isotopes of air in polar ice cores provide constraints on past temperature and firn thickness, with relevance to past climate. We developed a method to simultaneously measure nitrogen and argon isotopes in trapped air from the same sample of polar ice. This method reduces the time required for analysis, allowing large numbers of measurements. We applied this method to the entire Holocene sequence of the GISP2 ice core (82.37-1692.22 m) with a 10-20 year sampling interval (670 depths). δ⁴⁰Ar and δ¹⁵N show elevated values in the oldest part of the dataset, consistent with a thicker firn layer and increased temperature gradient in the firn due to the legacy of the abrupt warming at the end of the Younger Dryas interval and the gradual warming during the Preboreal interval (11.5-10.0 ka). The Preboreal Oscillation and the 8.2k event are clearly recorded. The data show remarkable stability after the 8.2k event.Available data suggests that post-coring gas loss involves two distinct types of fractionation. First, smaller molecules with less than a certain threshold size leak through the ice lattice with little isotopic fractionation. Second, gas composition changes via gas loss through microcracks, which induces isotopic fractionation. These two gas loss processes can explain most trends in our data and in other ice core records.     

Experimental study on prevention of acid mine drainage by silica coating of pyrite waste rocks with amorphous silica solution

Acid mine drainage (AMD) is a widespread environmental problem associated with working and abandoned mining operations. It results from the microbial oxidation of pyrite in the presence of water and air, affording an acidic solution that contains toxic metal ions. Pyrite microencapsulation, utilizing silica coating, is a novel approach for controlling AMD that has been shown to be very effective in controlling pyrite oxidation. The roles of the solution pH and silica concentration in the formation mechanism for the AMD-preventing coating were investigated. A silica coating can be formed from silica solution at pH 7, at which the amount of Fe eluted from pyrite into the solution is small. No coating was formed at other pH values, and the amounts of eluted Fe were larger than at pH 7, especially at pH 11. The silica coating forms from 2,500 to 5,000 mg/L silica solutions, but not from 0 or 1,000 mg/L silica solutions. The coating formation rate was slower in the 2,500 mg/L silica solution than in the 5,000 mg/L silica solution. The formation of silica coating on pyrite surfaces depends on three main steps: formation of Fe(OH)₃ on the surface of pyrite, reaction between Fe(OH)₃ and silicate in the solution on the pyrite surface, and growth of the silica layer on the first layer of silica. The best pH condition to enable these steps was around 7, and the silica coating formation rate can be controlled by the concentration of silica.     

GIS-based weights-of-evidence modelling of rainfall-induced landslides in small catchments for landslide susceptibility mapping

Landslide susceptibility mapping is a vital tool for disaster management and planning development activities in mountainous terrains of tropical and subtropical environments. In this paper, the weights-of-evidence modelling was applied, within a geographical information system (GIS), to derive landslide susceptibility map of two small catchments of Shikoku, Japan. The objective of this paper is to evaluate the importance of weights-of-evidence modelling in the generation of landslide susceptibility maps in relatively small catchments having an area less than 4 sq km. For the study area in Moriyuki and Monnyu catchments, northeast Shikoku Island in west Japan, a data set was generated at scale 1:5,000. Relevant thematic maps representing various factors (e.g. slope, aspect, relief, flow accumulation, soil depth, soil type, land use and distance to road) that are related to landslide activity were generated using field data and GIS techniques. Both catchments have homogeneous geology and only consist of Cretaceous granitic rock. Thus, bedrock geology was not considered in data layering during GIS analysis. Success rates were also estimated to evaluate the accuracy of landslide susceptibility maps and the weights-of-evidence modelling was found useful in landslide susceptibility mapping of small catchments.     

A fluidized landslide on a natural slope by artificial rainfall

An experiment to induce a fluidized landslide by artificial rainfall was conducted on a natural slope at Mt. Kaba-san in the village of Yamato, Ibaraki Prefecture, Japan. The experimental slope was 30 m long, 5 m wide, and the average slope gradient was 33°. A landslide initiated 24,627.5 s (410 m/27.5 s) after the start of sprinkling at a rainfall intensity of 78 mm/h. The landslide mass was 14 m long and 1.2 m deep (at maximum). It first slid, then fluidized, and changed into a debris flow. The travel distance was up to 50 m in 17s. The apparent friction angle of the fluidized landslide was 16.7°. Formation of the sliding surface was detected by soil-strain probes. Motion of the surface of the failed landslide mass was determined by stereo photogrammetry.     

Attenuation of peak ground acceleration,velocity and displacement based on multiple regression analysis of japanese strong motion records

This paper presents the result of multiple regression analysis of 197 sets of two orthogonal horizontal strong motion acceleration records. They were obtained at 67 free field sites in Japan from 90 earthquakes with focal depth less than 60 km. Because sensitivity of the Japanese SMAC accelerograph is appreciably low at the high frequency range, instrument correction was performed on the original data. Each pair of two orthogonal horizontal components was combined in the time domain to get the maximum peak ground motions in the horizontal plane. The records were classified into three groups due to subsoil condition. With the use of multiple regression analysis, empirical formulae of attenuation of the maximum peak ground acceleration, velocity and displacement were proposed for three subsoil conditions.     

Rapid development of arctic cyclone in June 2008 simulated by the cloud resolving global model NICAM

In this study, we conducted a numerical simulation of a rapid development of an arctic cyclone (AC) that appeared in June 2008 using a cloud resolving global model, Nonhydrostatic ICosahedral Atmospheric Model (NICAM). We investigated the three dimensional structure and intensification mechanism of the simulated AC that developed to the minimum sea level pressure of 971 hPa in the model. According to the result, the AC indicates a barotropic structure with a warm core in the lower stratosphere and a cold core in the troposphere. The development of the AC is accompanied by an intense mesoscale cyclone (MC) showing baroclinic structure with a marked local arctic front. The upper level warm core of the AC is formed by an adiabatic heating associated with the downdraft in the lower stratosphere. The rapid development of the AC is caused by the combination of the intensification of the upper level warm core and the merging with the baroclinically growing MC in the lower level. The merging of the AC and MC and the vertical vortex coupling with the upper air polar vortex are the most important mechanisms for the rapid development of the arctic cyclone.     

Structural controls on the 1998 volcanic unrest at Iwate volcano: Relationship between a shallow, electrically resistive body and the possible ascent route of magmatic fluid

Magnetotelluric (MT) measurements were conducted at Iwate volcano, across the entirety of the mountain, in 1997, 1999, 2003, 2006, and 2007. The survey line was 18 km in length and oriented E–W, comprising 38 measurements sites. Following 2D inversion, we obtained the resistivity structure to a depth of 4 km. The surface resistive layer (~ several hundreds of meters thick) is underlain by extensive highly conductive zones. Based on drilling data, the bottom of the highly conductive zone is interpreted to represent the 200 °C isotherm, below which (i.e., at higher temperatures) conductive clay minerals (smectite) are rare. The high conductivity is therefore mainly attributed to the presence of hydrothermally altered clay. The focus of this study is a resistive body beneath the Onigajo (West-Iwate) caldera at depths of 0.5–3 km. This body appears to have impeded magmatic fluid ascent during the 1998 volcanic unrest, as inferred from geodetic data. Both tectonic and low-frequency earthquakes are sparsely distributed throughout this resistive body. We interpret this resistive body as a zone of old, solidified intrusive magma with temperatures in excess of 200 °C. Given that a similar relationship between a resistive body and subsurface volcanic activity has been suggested for Asama volcano, structural controls on subsurface magmatic fluid movement may be a common phenomenon at shallow levels beneath volcanoes.     

Classification of self-potential anomalies on volcanoes and possible interpretations for their subsurface structure

Self-potential (SP) surveys were conducted on 10 island-arc-type volcanoes in Japan. Large-scale SP anomalies that covered entire volcanic edifices and had simple shapes were observed. Neglecting the local fluctuations, we named the SP anomaly that shows voltage gradients anywhere on the flank a long spatial wavelength (LSW) SP anomaly. We first classified these anomalies into three types: 1) no anomaly (SP profile is flat): 2) “W”-shaped profile: and 3) “V”-shaped profile. In some volcanoes, one flank with a flat SP profile and another with half of the W-shaped SP profile coexist. Next, we compared LSW-SP anomalies with various factors that may be related to SP generation and found that the SP profile is approximately flat on the flank where geothermal manifestations exist. This relationship, which is new aspect of the SP data on volcanoes, is important because it can impose a constraint on the model for SP generation and the subsurface structure. Based on the discussion that SP is generated by an electrokinetic mechanism, we propose that resistivity, zeta potential, and hydraulic radius are the possible parameters that control the existence of LSW-SP anomalies. The new relationship between SP and geothermal manifestation are understood in terms of the presence of hydrothermal system. Although the structure of volcanic edifice is probably spatially complicated, the insight into the SP data presented in this study implies that the flanks with flat SP profiles are relatively weak and have high potential for sector collapse.     

Seismic Properties of Anita Bay Dunite: an Exploratory Study of the Influence of Water

As a pilot study of the role of water in the attenuation ofseismic waves in the Earth's upper mantle, we have performeda series of seismic-frequency torsional forced-oscillation experimentson a natural (Anita Bay) dunite containing accessory hydrousphases, at high temperatures to 1300°C and confining pressure(P_c) of 200 MPa, within a gas-medium high-pressure apparatus.Both oven-dried and pre-fired specimens wrapped in Ni–Fefoil within the (poorly) vented assembly were recovered essentiallydry after 50–100 h of annealing at 1300°C followedby slow staged cooling. The results for those specimens indicatebroadly similar absorption-band viscoelastic behaviour, butwith systematic differences in the frequency dependence of strain-energydissipation Q^–1, attributed to differences in the smallvolume fraction of silicate melt and its spatial distribution.In contrast, it has been demonstrated that a new assembly involvinga welded Pt capsule retains aqueous fluid during prolonged exposureto high temperatures—allowing the first high-temperaturetorsional forced-oscillation measurements under high aqueousfluid pore pressure P_f. At temperatures >1000°C, a markedreduction in shear modulus, without concomitant increase inQ^–1, is attributed to the widespread wetting of grainboundaries resulting from grain-scale hydrofracturing and themaintenance of conditions of low differential pressure P_d =P_c – P_f . Staged cooling from 1000°C is accompaniedby decreasing P_f and progressive restoration of significantlypositive differential pressure resulting in a microstructuralregime in which the fluid on grain boundaries is increasinglyrestricted to arrays of pores. The more pronounced viscoelasticbehaviour observed within this regime for the Pt-encapsulatedspecimen compared with the essentially dry specimens may reflectboth water-enhanced solid-state relaxation and the direct influenceof the fluid phase. The scenario of overpressurized fluids andhydrofracturing in the Pt-encapsulated dunite specimen may havesome relevance to the high Q^–1 and low-velocity zonesobserved in subduction-zone environments. The outcomes of thisexploratory study indicate that the presence of water can havea significant effect on the seismic wave attenuation in theupper mantle and provide the foundation for more detailed studieson the role of water. KEY WORDS: seismic wave attenuation; water; dunite; hydrous mineral; shear modulus; viscoelasticity; olivine; grain-scale hydrofracturing