Isotopic composition of nitrate in five German rivers discharging into the North Sea

We determined concentrations and isotopic composition of nitrate in five German rivers (Rhine, Elbe, Weser, Ems, and Eider) that discharge into the North Sea. Samples were obtained on a biweekly to monthly basis and chemical and isotopic analyses were conducted for the period January 2006 to March 2007 at sampling stations situated before estuarine mixing with North Sea water. We observed maximum nitrate loads in winter and fall, when both discharge and concentration of nitrate are highest. Mean annual isotope values in nitrate ranged from 8.2‰ to 11.3‰ for and 0.4‰ to 2.2‰ for . The ranges of isotope values suggest that nitrate in these rivers derives from soil nitrification, sewage, and/or manure. These and published data on other rivers in northern Europe and northern America reveal a correlation between agricultural land use (>60% in the catchment areas of rivers examined) and values. The rivers Rhine, Elbe, Weser and Ems show similar seasonal patterns of the isotopic fractionation of nitrate with increasing values and simultaneously decreasing concentrations during summer months, indicating that assimilation of nitrate is the main fractionation process of riverine nitrate. Isotopic signals in winter are more depleted than the mean summer isotope values, attributed to less microbial activity and assimilative processes. Load weighted nitrate δ¹⁵N of the riverine input to the German Bight Coastal Water mass before estuarine mixing and processing is between 8‰ and 12‰. The high δ¹⁵N value of river nitrate is matched by high δ¹⁵N of nitrate in surface sediments in the German Bight.     

Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.     

The impact process in aeolian saltation: two-dimensional simulations

ABSTRACT
A critical event in the trajectory of a sand grain saltating in air is its interaction with the surface. We examine the phenomenon of grain-bed impacts in two dimensions using a combination of dynamical computer simulations, analytical models and physical reasoning. The results indicate that the grain-bed collisions can be treated as two-body collisions with the bed particle assuming an effective mass greater than its true mass. Also, the presence of geometrical surface irregularities has a strong bearing on the interaction between saltating and surface grain populations, as well as on the formation of small-scale bedforms.     

The carbonate compaction law: a new tool

Carbonate content, compaction, and porosity are evaluated from a large number of samples using micritic marl-limestone alternations from Germany, France, and Italy. Compaction is measured directly by utilizing both deformed, originally cylindrical bioturbation tubes and steinkerns of ammonites. Additionally, a method is developed to indirectly evaluate the total compaction of the rock matrix by using early, selectively cemented burrows and fossils. Plots representing measurements of compaction versus carbonate content display distinctly non-linear relationships which show increasing compaction with decreasing carbonate content. These relationships are found to clearly correspond with the carbonate compaction law. The compaction law is introduced as a theoretical derivation for sediments and rocks which calculates the carbonate and non-carbonate content, compaction, and porosity. It is based on the assumption that the non-carbonate fraction standardized to the primary sediment-volume remains constant during carbonate diagenesis. The compaction law is used to calculate the most commonly found sediment/rock transformations (e.g. mechanical compaction, cementation, and chemical compaction) and to simulate the diagenetic processes of given examples. Decompaction formulas are developed to evaluate the porosity and carbonate content of the primary sediment. An example of calculating decompaction and determining the original composition of the sediment is given utilizing carbonates spanning the Cretaceous-Tertiary boundary at Gubbio (Italy).     

COMBISWEEP—A CONTRIBUTION TO SWEEP TECHNIQUES*

Nonlinear sweeps have often successfully been employed in the 1960s. However, this area of sweep technology has been neglected since the introduction of digital recording techniques in the Vibroseis system. Now the advent of computerized recording instruments yields a new economical possibility of forming approximately nonlinear sweeps by combining several linear sweeps with or without time gaps to a “Combisweep”. The total duration of a Combisweep may be as long as the maximum available recording time, for example 32 s. Beside the attenuation of correlation noise, the new method has further merits, such as the weighting of predetermined frequency ranges, in order to effect a certain kind of optimum filtering on the emitter side, or in order to compensate to some degree for frequency dependent absorption. In all these applications the Combisweep is considered as one signal in the correlation process. But by correlating with the individual sweeps or a partial combination of them and by applying automatic switching at predetermined times within the gaps between the individual sweeps additional possibilities arise, such as obtaining in one run with a twenty-four channel recording unit twenty-four traces with small distances between vibrators and geophones for shallow reflections and another twenty-four traces with larger distances for deeper reflections. Various Combisweeps and their applications are presented.     

Modification of sediment characteristics during glacial transport in high-alpine catchments: Mount Cook area, New Zealand

The Mount Cook area in the Southern Alps of New Zealand is heavily glacierized with numerous peaks over 3000 m a.s.l. feeding several large valley glaciers. The region is subject to rapid tectonic uplift and heavy precipitation (up to 15 m per year). This paper describes the clast roundness, clast shape and textural characteristics associated with five glaciers (Fox, Franz Josef, Hooker, Mueller and Tasman) in terms of inputs to the glacier system, transport by the glaciers and reworking following glacial deposition. Inputs include rockfall, alluvial fan and avalanche material delivered to the surface of valley glaciers. Basal debris, where observed at the terminus of two glaciers, consists mainly of incorporated fluvial material. Following deposition, reworking is mainly by subglacial and proglacial streams. The dominant facies are (i) boulder gravel with mainly angular clasts on the steep slopes above the glaciers, (ii) sandy boulder gravel, with mainly angular and subangular clasts, forming lateral and end moraines, and (iii) sandy boulder/cobble gravel with mainly subrounded clasts, and sand, which represent glacially transported sediment reworked by braided rivers. Diamicton is rare in the contemporary glacial environment. Since most sediment associated with glaciers in the Southern Alps lacks unambiguous indications of glacial transport, interpretation of similar sediments in the geological record should not necessarily exclude the involvement of glacial processes.     

Combined Trace Element and Pb-Nd-Sr-O Isotope Evidence for Recycled Oceanic Crust (Upper and Lower) in the Iceland Mantle Plume

We present the results of a comprehensive major element, traceelement and Sr–Nd–Pb–O isotopic study of post-glacialvolcanic rocks from the Neovolcanic zones on Iceland. The rocksstudied range in composition from picrites and tholeiites, whichdominate in the main rift systems, to transitional and alkalicbasalts confined to the off-rift and propagating rift systems.There are good correlations of rock types with geochemical enrichmentparameters, such as La/Sm and La/Yb ratios, and with long-termradiogenic tracers, such as Sr–Nd–Pb isotope ratios,indicating a long-lived enrichment/depletion history of thesource region. ⁸⁷Sr/⁸⁶Sr vs ¹⁴³Nd/¹⁴⁴Nd defines a negative array.Pb isotopes define well-correlated positive arrays on both ²⁰⁶Pb/²⁰⁴Pbvs ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb diagrams, indicating mixing ofat least two major components: an enriched component representedby the alkali basalts and a depleted component represented bythe picrites. In combined Sr–Nd–Pb isotopic spacethe individual rift systems define coherent mixing arrays withslightly different compositions. The enriched component hasradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb > 19·3) and very similargeochemistry to HIMU-type ocean island basalts (OIB). We ascribethis endmember to recycling of hydrothermally altered upperbasaltic oceanic crust. The depleted component that is sampledby the picrites has unradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb < 17·8),but geochemical signatures distinct from that of normal mid-oceanridge basalt (N-MORB). Highly depleted tholeiites and picriteshave positive anomalies in mantle-normalized trace element diagramsfor Ba, Sr, and Eu (and in some cases also for K, Ti and P),negative anomalies for Hf and Zr, and low ¹⁸O_olivine values(4·6–5·0) below the normal mantle range.All of these features are internally correlated, and we, therefore,interpret them to reflect source characteristics and attributethem to recycled lower gabbroic oceanic crust. Regional compositionaldifferences exist for the depleted component. In SW Icelandit has distinctly higher Nb/U (68) and more radiogenic ²⁰⁶Pb/²⁰⁴Pbratios (18·28–18·88) compared with the NErift (Nb/U 47; ²⁰⁶Pb/²⁰⁴Pb = 18·07–18·47).These geochemical differences suggest that different packagesof recycled oceanic lithosphere exist beneath each rift. A thirdand minor component with relatively high ⁸⁷Sr/⁸⁶Sr and ²⁰⁷Pb/²⁰⁴Pbis found in a single volcano in SE Iceland (Öræfajökullvolcano), indicating the involvement of recycled sediments inthe source locally. The three plume components form an integralpart of ancient recycled oceanic lithosphere. The slope in theuranogenic Pb diagram indicates a recycling age of about 1·5Ga with time-integrated Th/U ratios of 3·01. Surprisingly,there is little evidence for the involvement of North AtlanticN-MORB source mantle, as would be expected from the interactionof the Iceland plume and the surrounding asthenosphere in formof plume–ridge interaction. The preferential samplingof the enriched and depleted components in the off-rift andmain rift systems, respectively, can be explained by differencesin the geometry of the melting regions. In the off-rift areas,melting columns are truncated deeper and thus are shorter, whichleads to preferential melting of the enriched component, asthis starts melting deeper than the depleted component. In contrast,melting proceeds to shallower depths beneath the main rifts.The longer melting columns also produce significant amountsof melt from the more refractory (lower crustal/lithospheric)component. KEY WORDS: basalts; trace element and Sr, Nd, Pb, O isotope geochemistry; Iceland plume; isotope ratios; oceanic crustal recycling; partial melting; plume–ridge interaction     

The 16th Workshop on Antarctic Meteorology and Climate and 6th Year of Polar Prediction in the Southern Hemisphere Meeting

1. Overview In June 2021, the 16th Workshop on Antarctic Meteorology and Climate (WAMC) and the 6th Year of Polar Prediction in the Southern Hemisphere (YOPP-SH) Meeting (http://polarmet.osu.edu/WAMC;021/) were held online and hosted by the Polar Meteorology Group at Byrd Polar and Climate Research Center, The Ohio State University, Columbus,Ohio (Fig. 1).