“BASS 300 PARACOM”: a “model” underwaterparametric communication system

Parametric transduction offers valuable advantages for underwater acoustic communications. Perhaps the most significant benefit is the fact that high directivity is achieved by means of a physically small transmit transducer. This feature may, ultimately, be employed to permit long-range, low-frequency communication using a compact source. The high directivity is desirable to combat multipath propagation and to achieve data communications in water which is shallow by comparison with range. A real-time, high data-rate “model” differential phase shift keying (DPSK) communication system has been constructed and demonstrated. This system uses parametric transduction, with a 300-kHz primary frequency and a 50-kHz secondary frequency. Experimental results show that the system can be employed to combat multipath propagation in shallow water and can achieve high data-rate text and color image transmission at 10 and 20 kb s^-1 for 2-DPSK and 4-DPSK, respectively, through a transmission bandwidth of 10 kHz. The “model” system was developed to confirm performance predictions for a future, operational long-range link employing a 50-kHz primary frequency and a 5-kHz secondary frequency     

A study on the exchange additivity of zinc in solid mixtures in seawater——Ⅱ.Stepwise exchange in δ-MnO2/montmorrillonite mixture

In this study the zinc exchange process and the reason for the non-additive exchange of δ-MnO2/montmorrillonite have been investigated. The results suggest that with pH increasing from 2 to 8, the stepwise exchange of zinc occurs on δ-MnO. and montmorrillonite in their mixture.At low pH zinc ions are bound on δ-MnO2, while at high pH, the exchange on montmorrillonite dominates the surface interaction in the mixture. The study demonstrates that the stepwise exchange and the heterogeneity of the binding sites on δ-MnO2 surface are the reason for the non-additive exchange. It is also shown that when δ-MnO2 amounts to 5 %, zinc exchange on sea sediments is controlled by 8-MnO2.     

海水中磷酸盐在固体粒子上阴离子交换作用 海水中磷酸盐-固体粒子相互作用的台阶型等温线

通过研究氯化钠溶液中磷酸盐在4种固体粒子（针铁矿、δ－氧化锰、伊利石和高岭石）上的交换等温线及钙对上述交换等温线的影响，发现磷酸盐液－固界面作用的台阶型等温线（2个台阶），可用分级离子／配位子交换等温式定量描述。钙能够促进磷酸盐在针铁矿和δ－氧化锰上的交换作用，其机理是交换在固体粒子上的钙再结合溶液中的磷酸盐，形成表面无机三元络合物。     

Study on copper complexing ligand concentrations in several China’s coastal waters

Copper complexing ligand concentrations in the Daya Bay, Qingdao coast, Jiaozhou Bay, South China Sea and Huanghe Estuary waters were determined by the anodic stripping voltammetry technique. The distribution regularity and the relationship with other parameters were discussed. The results were as follows: Copper complexing ligand concentrations of the South China Sea were a little higher than those of other sea areas, and they were apparently higher than those of the ocean. Compared with the subsurface layer (SSL) in the sea surface microlayer copper complexing ligand concentrations showed an enrichment phenomenon, of which the mechanism is similar to dissolved organic matter. The metal complexing ligand concentration profiles of the South China Sea showed that the value in the sea surface was the highest, then it decreased with depth accruing, and a higher value appeared at the bottom. Copper complexing ligand concentrations were higher than those of cadmium and lead. Ligands in each sea area exhibited a complicated property. In short, the distribution regularity of copper complexing ligand concentrations in China' s coastal waters was consistent with that of other regions in the world. Meanwhile, the positive relationship between the copper complexing ligand concentrations and biological oxygen demand, chemical oxygen demand, dissolved organic carbon, and viscosity were found clearly.     

悬浮沙激光散斑图像处理的研究

本文以统计模式识别为基础，阐述了图像处理在悬浮沙粒粒径流量中的实际应用，提出了用图像层析来确定放大系数的方法，提出了测量的准确度。     

海水中液-固界面的台阶型动力学曲线 Ⅰ.动力学曲线之台阶的消长和变化规律

对海水中Zn(Ⅱ),Ca(Ⅱ),Cd(Ⅱ)与高岭石、伊利石和蒙脱石等粘土矿物;无定形水合氧化铁、α-FeOOH等铁的水合氧化物;δ-MaO_2,γ-MnOOH,水锰矿等锰的水合氧化物等30个左右实验体系的液-固界面台阶型动力学曲线进行了系统的实验测定和全面的条件研究。在实验测定上提出两种方法、互为校核。对动力学曲线之台阶的消长和变化规律作了系统研究,确定主要影响因素是:金属离子初始浓度、固体交换剂量、体系的pH值和温度,以及搅拌速度等。     

海洋中液-固界面作用的分形研究Ⅰ.SAXS法测量固体交换剂的分维

本文将分形作为一个新概念,应用到海洋化学的液-固界面作用的一系列的研究上。根据用SAXS法测定一些常见的粘土矿物(高岭石,蒙脱石)和水合氧化物(水锰矿、δ-MnO_2、氧化铁凝胶、针铁矿、无定形氧化铁)的分维结果,可将这些结果划分成三类:(1)小尺度模量下具有表面分形;大尺度模量下具有质量分形。(2)只有一种分维值的表面分形。(3)在小尺度模量下和大尺度模量下分别具有不同分维值的表面分形。     

海洋水色卫星遥感器特性参数探讨

为了评价海洋水色卫星遥感器特性参数的优劣，确定仪器的计量特性及其使用价值，准确的理解和科学的定义仪器的特性参数是非常重要的。作者曾有幸参加了海洋水色卫星的立项论证工作，本文就作者的一些工作体会，对海洋水色卫星遥感器的特性参数作初步探讨。     

海水中一氧化氮的极谱法测定

本文首次采用 Nafion和 Co(salen) /Nafion修饰铂电极测定海水中的 NO,对实验条件进行了选择 ,确定了最佳实验条件 ,即反应池通氮除氧 30 min,富集时间为 4min。同时用线性扫描法对海水中的 NO进行测定 ,测得海水中 NO的浓度与氧化峰电流之间有一定线性关系。对 Nafion修饰电极而言 ,线性范围 1～ 76.9μmol/L,R2 =0 .991 6,检出限为 1 μmol/L。同时对 2种方法修饰的铂电极进行了比较 ,即当 NO浓度在 1 0 -6mol/L数量级时 2种电极基本上无差别 ,而在 1 0 -7mol/L数量级时 Co(salen) /Nafion修饰电极要明显优于 Nafion修饰电极     

THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.