Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Remarks on dynamical ellipticity at the Earth's

In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series.     

Study on application of polyenzyme method to offal of Harengula zunasi

The new polyenzyme method for making gravy fromHarengula zunasi offal involves protein enzymolysis with flavorase after proper alkaline and neutral protease levels were established by orthogonal trials to select the best hydrolytic conditions for processing offal with alkaline and neutral protease. The conditions for the polyenzyme method were pH of 7.0, temperature of 50°C, alkaline and neutral protease concentration of 1.5% respectively, hydrolysis time of 120 min, and flavorase concentration of 2.0%, for 60 min. The new gravy-making technology yields a nutritious and delicious gravy containing 40.3% of total essential amino acids, with delicious amino acids Glu, Asp, Gly, Ala, Pro and Ser comprising 49.5%, total and amino nitrogen being respectively 1.9 and 1.1 g/100 g (amino acid nitrogen being 61.0% of total nitrogen), The polyenzyme method was used to make 14.8% protein gravy fromHarengula zunasi offal. In addition, inorganic elements, the phosphorus content is the highest. This project was aided financially by the Guangdong Science and Technology Office (No. 2KM06002S).     

黔东震旦系—下寒武统黑色岩系稀土元素地球化学特征

：通过对黔东丹寨南皋剖面和三都渣拉沟剖面的稀土元素分析发现：两条剖面的梅树村期与筇竹寺期 分界处大量稀土元素明显富集,黑色页岩中存在明显的Ｃｅ负异常和Ｅｕ、Ｙ 正异常,表明为缺氧和热水沉积的产物。 这套黑色岩系总体沉积于缺氧和具热水注入的环境中,但发生缺氧和热水注入的时间和强度在不同地方会有不同 的表现。     

无定河流域下游段河冰形成演变的数学模型研究

冰凌是北方河流冬春季常见的现象, 由于环境因素的变化, 河道冰情也在不断的变化, 甚至在一些地区出现凌汛灾害. 根据冰塞形成发展的机理, 利用水力学模型和热力学模型模拟研究了无定河流域下游段丁家沟至白家川的每年春季河流水位、封河日期和开河日期. 模拟结果较为理想, 并分析了形成凌汛的原因, 旨在给该区域水循环研究、水资源的开发利用、水土保持等工作提供有力的科学技术支持.     

舟山国家石油储备基地堆载预压加固效果分析

介绍了舟山国家石油储备基地试验区软基堆载预压大型现场试验结果,根据现场试验测得的数据,分析了软土地基堆载预压下沉降变化规律、分层沉降变化规律、深层土体位移变化规律、超静孔隙水压力变化规律,进一步探讨了根据应力和应变分析得到的地基固结性状,其中通过应变分析得到适用于储备基地的沉降经验系数m。结果表明,打设塑料排水板结合堆载预压处理软弱地基具有良好的效果。     

地面沉降在闸涵工程运行中引起的经济损失的探讨

通过对天津市内主要河流上的4座具有代表性的闸涵进行详细的计算分析,得出闸涵水利工程维护费用中约19%属于地面沉降引起的损失,并将此比重推广到全市的闸涵工程,最后计算得出地面沉降造成的损失约为3.45亿元。     

川藏公路102滑坡群地段基覆界面问题研究

边坡坡体结构中,下伏基岩与上覆松散堆积体间接触界面(即基覆界面)的形态特征对边坡稳定性往往起决定性作用,同时也是边坡稳定性计算和边坡抗滑工程设计的重要依据。本文针对著名的川藏公路102滑坡群路段边坡基覆界面特征问题进行了初步研究,根据该路段河谷冰川地貌特征、2#滑坡后壁地下水渗水带特征和少量物探钻孔资料提出了新的基覆界面位置,即102滑坡群路段边坡基岩与上覆松散堆积体的界面位置在平均海拔2 325m,而不是前人所认为的帕隆藏布江河谷基岩出露处(海拔2 120m)。该新认识对2#滑坡工程整治设计方案选择具有重要指导意义,并建议首先考虑隧道方案。     

深井旋转轴套流场的CFD模拟

旋转轴套在超深井工作时,其井下流动是三维湍流流动,旋转轴套的旋转和表面曲率效应以及随之而来的哥氏力和离心力,使流场在超深井的流动中极其复杂,同时,由于流体介质泥浆属于液固两相流,更致使内部流场测试困难,而且超深井中的工况在使用常规方法已很难得到较准确的数据。为此,将计算流体力学软件Fluent应用于超深井下流场的模拟,基于Navier-Stokes方程和Reynolds应力方程模型,建立多种仿真模型,在相同条件下,使用CFD仿真软件Fluent模拟仿真的不同结果,优化与旋转轴套叶片设计相关的几何参数,提高