Ghaleh-khargushi rhyodacite and Gorid andesite from Iran: characterization,uses, and durability

Durability of building stones is an important issue in sustainable development. Crystallization of soluble salts is recognized as one of the most destructive weathering agents of building stones. For this reason, durability of Ghaleh-khargushi rhyodacite and Gorid andesite from Iran was investigated against sodium sulfate crystallization aging test. Petrographic and physico-mechanical properties and pore size distribution of these stones were examined before and after the aging test. The characteristics of the microcracks were quantified with fluorescence-impregnated thin sections. Durability and physico-mechanical characteristics of Ghaleh-khargushi rhyodacite are mainly influenced by preferentially oriented preexisting microcracks. Stress induced by salt crystallization led to the widening of preexisting microcracks in Ghaleh-khargushi rhyodacite, as confirmed by the pore size distributions before and after the aging test. The preexisting microcracks of Gorid andesite were attributed to the mechanical stress induced by contraction of lava during cooling. The number of transcrystalline microcracks was significantly increased after the aging test. The degree of plagioclase microcracking was proportional to its size. Durability of the studied stones depends on initial physico-mechanical properties, pore size distribution, and orientation of microcracks. Initial effective porosity is found to be a good indicator of the stones’ durability. Salt crystallization resulted in an increase in the effective porosity with a parallel decrease in the wave velocities. Surface microroughness parameters increased with the development of salt crystallization-induced microcracking. Gorid andesite showed higher quality and durability than Ghaleh-khargushi rhyodacite.     

Spatially-Weighted Factor Analysis for Extraction of Source-Oriented Mineralization Feature in 3D Coordinates of Surface Geochemical Signal

Natural Resources Research - This contribution proposes a spatially weighted factor analysis (SWFA) to recognize effectively the underlying mineralization-related feature(s) in geochemical signals....     

Sensitive Ion‐Flotation Separation of Ag(I) Traces Using 2‐(2‐Methoxyphenyl)benzimidazole before Flame Atomic Absorption Spectrometric Determination in Water

A sensitive, reliable, and environmentally friendly method for simple separation and preconcentration of Ag(I) traces in aqueous samples is presented prior to their flame atomic absorption spectrometric determinations. At pH 7.0, Ag(I) was separated with 2‐(2‐methoxyphenyl)benzimidazole (MPBI) as a new complexing agent and floated after adding sodium dodecyl sulfate (SDS) as a foaming reagent. The floated layer was then dissolved in proper amount of concentrated nitric acid in methanol and introduced to the flame atomic absorption spectrometer (FAAS). The effects of pH, concentration of MPBI, type and amount of surfactant as the floating agent, type and amount of eluting agent, and influence of foreign ions on the recovery of the analyte ion were investigated. Also, using a nonlinear curve fitting method, the formation constant of 1.62 × 10⁶ was obtained for Ag(I)–MPBI complex. The analytical curve was linear in the range of 1.8 × 10^?7–1.7 × 10^?6 mol/L for determination of Ag(I). The relative standard deviation (RSD; N = 10) corresponding to 0.7 × 10^?6 mol/L of Ag(I), the limit of detection (10 blanks), and the enrichment factor were obtained as 1.7%, 2.9 × 10^?8 mol/L, and 43.0, respectively. The proposed procedure was then applied successfully for determination of silver ions in different water samples.     

Multiple linear regression,multi-layer perceptron network and adaptive neuro-fuzzy inference system for forecasting precipitation based on large-scale climate signals

ABSTRACT

Nowadays, mathematical models are widely used to predict climate processes, but little has been done to compare the models. In this study, multiple linear regression (MLR), multi-layer perceptron (MLP) network and adaptive neuro-fuzzy inference system (ANFIS) models were compared for precipitation forecasting. The large-scale climate signals were considered as inputs to the applied models. After selecting the most effective climate indices, the effects of large-scale climate signals on the seasonal standardized precipitation index (SPI) of the Maharlu-Bakhtaran catchment, Iran, simultaneously and with a delay, was analysed using a cross-correlation function. Hence, the SPI time series was forecasted up to four time intervals using MLR, MLP and ANFIS. The results showed that most of the indices were significant with SPI of different lag times. Comparison of the SPI forecast results by MLR, MLP and ANFIS models showed better performance for the MLP network than the other two models (RMSE = 0.86, MAE = 0.74 for the first step ahead of SPI forecasting).

Editor D. Koutsoyiannis; Associate editor F. Pappenberger     

Intercontinental response to variations in the Arabia-Eurasia Plate convergence,calcite e-twin evidence of the Kuhbanan Fault system,Central Iran

Variations in the plate convergence direction have generally reflected on the kinematics of the major fault zones developed in the intercontinental parts of the collision zones. The Kuhbanan Fault system is one of the most important intercontinental faults in the Arabia-Eurasia collision zone with a dextral strike slip mechanism. This fault system is composed of three fault strands including Kuhbanan, Bazargan, and Kerman Faults. Here we used calcite e-twin analysis of the vein samples developed in these fault zones to reconstruct deformation condition and the paleodifferential stress direction and magnitude at the Kuhbanan Fault system. Our results represent 190°C-200°C of the deformation temperature and related 5–6 ± 1 km of deformation depth at the Kuhbanan Fault system. Calculated paleodifferential stress magnitude in the Kuhbanan Fault system using e-twin parameters ranges from 169-196 MPa similar to the inner parts of the orogenic systems. Comparing the data set of the Kuhbanan Fault system with previous studies at the Zagros orogen represents an increase of deformation depth and paleodifferential stress magnitudes from the foreland of the Zagros orogen to its hinterland and finally northward around the Kuhbanan Fault system in the central Iranian blocks. We have also proposed a shift of the stress direction from paleo NE to recent N directed by comparing paleostress direction deduced from the calcite e-twin and recent stress direction calculated from GPS and earthquake data analysis around the Kuhbanan Fault system. This kinematics change due to plate reorganization is in agreement with the observed regional variation in convergence direction all in the Arabia-Eurasia collision zone.     

Neural network prediction of solar cycle 24

The ability to predict the future behavior of solar activity has become extremely import due to its effect on the environment near the Earth.Predictions of both the amplitude and timing of the next solar cycle will assist in estimating the various consequences of space weather.The level of solar activity is usually expressed by international sunspot number (Rz).Several prediction techniques have been applied and have achieved varying degrees of success in the domain of solar activity prediction.We predict a...