Experimental study on the hydrological performance of green roofs in the application of novel biochar

Biochar has the potential to be a soil amendment in green roofs owing to its water retention, nutrient supply, and carbon sequestration application. The combined effects of biochar and vegetated soil on hydraulic performance (e.g., saturated hydraulic conductivity, retention and detention, and runoff delay) are the crucial factor for the application of the novel biochar in green roofs. Recent studies investigated soil water potential (i.e., suction) either on vegetated soil or on biochar-amended soil but rarely focused on their integrated application. With the purpose of investigating the hydraulic performance of green roofs in the application of biochar, the combined effect of biochar and vegetated soil on hydrological processes was explored. Artificial rainfall experiments were conducted on the four types of experimental soil columns, including natural soil, biochar-amended soil, vegetated natural soil, and vegetated biochar-amended soil. The surface ponding, bottom drainage and the volumetric water content were measured during the rainfall test. Simulation method by using HYDRUS-1D was adopted for estimating hydraulic parameters and developing modelling analysis. The results indicated that the saturated hydraulic conductivity of vegetated soil columns were higher than bare soil columns. The addition of biochar decreased the saturated hydraulic conductivity, and the magnitude of decrease was much significant in the case of vegetated soil. The influence of vegetation on permeability is more prominent than biochar. The vegetated biochar-amended soil has the highest retention and detention capacity, and shows a preferable runoff delay effect under heavy rain among the four soil columns. The results from the present study help to understand the hydrological processes in the green roof in the application of biochar, and imply that biochar can be an alternative soil amendment to improve the hydraulic performance.     

Comparative performance evaluation of physicochemical treatment processes for simulated dairy wastewater

In the present study, the effectiveness of physicochemical treatment processes (coagulation and Fenton’s oxidation) was investigated for simulated dairy wastewater (pH = 7.3, chemical oxygen demand (COD) = 3600 mg/l, 5-day biochemical oxygen demand (BOD₅) = 1950 mg/l, total Kjeldahl nitrogen (TKN) = 87 mg/l, and total phosphorous (TP) = 14 mg/l). Plain and ballasted coagulation runs were carried out in a jar apparatus, while Fenton’s oxidation was performed in a three-neck glass reactor. Ballasted coagulation caused an enhancement in the settling rate of sludge though no significant enhancement in the removal of organics was observed. Individually, coagulation and Fenton’s oxidation processes resulted in ~67 and 80 % COD removals, respectively, from the wastewater. The sequential treatment exploring coagulation followed by Fenton’s oxidation showed overall COD, BOD₅, TKN, and TP reductions of ~93, 97, 84, and 70 %, respectively, from the wastewater. However, a biological post-treatment would be required to achieve the effluent discharge standards. The removal of proteins, fats, and amino acids from wastewater was confirmed from Fourier transform infrared analysis of the settled sludge (obtained after coagulation process). Preliminary cost analysis suggested coagulation and the sequential treatment (i.e. coagulation followed by Fenton’s oxidation) as the preferred options.     

A hierarchical model for estimating methane emission from wetlands using MODIS data and ARIMA modeling

A three-step hierarchical Semi Automated Empirical Methane Emission Model (SEMEM) has been used to estimate methane emission from wetlands and waterlogged areas in India using Moderate Resolution Imagine Spectroradiometer (MODIS) sensor data onboard Terra satellite. Wetland Surface Temperature (WST), methane emission fluxes and wetland extent have been incorporated as parameters in order to model the methane emission. Analysis of monthly MODIS data covering the whole of India from November 2004 to April 2006 was carried out and monthly methane emissions have been estimated. Interpolation techniques were adopted to fill the data gaps due to cloudy conditions during the monsoon period. AutoRegressive Integrated Moving Average (ARIMA) model has been fitted to estimate the emitted methane for the months of May 2006 to August 2006 using SPSS software.     

Static deformation of two welded half-spaces due to very long strike-slip dislocations

Closed form analytic expressions for displacement and stresses at any point of either of the two homogeneous, isotropic, perfectly elastic half-spaces in welded contact due to very long strike-slip dislocations are obtained. Both cases of vertical and horizontal strike-slip dislocations are discussed in detail. Variation of the displacement with horizontal distance from the fault and with vertical distance from the interface for a vertical strike-slip fault is studied numerically.     

COOLING RATES, SKY VIEW FACTORS AND THE DEVELOPMENT OF INTRA-URBAN AIR TEMPERATURE DIFFERENCES

Intra‐urban cooling rates were monitored for a year in the centre of Göteborg on the Swedish west coast. Five sites with different building geometry ‐ from dense canyon to open space ‐ within a radius of 300 m were analysed. Results showed two modes of cooling during the night. In the first mode, the cooling was site‐dependent ‐the open space cooled the most and the dense canyon the least. In the second mode, which began about 3–4 hours after sunset, all sites cooled at the same rate. Our hypothesis is that in the early part of the evening both radiative divergence and sensible heat dominate the cooling. However, as the evening progresses, a spatially homogeneous inversion is established which controls the radiative cooling, making the cooling independent of both surface geometry and surface type. From April to November the sites cooled rapidly around sunset and the cooling slowly decreased during the rest of the night. However, between December and March, the cooling was less intense, with an almost constant rate during the entire night. It has been suggested that this might be the result of the draining of stored solar heat during the summer and a continuous flux of anthropogenic heating during the winter.     

Mapping and monitoring of Rann (tidal) ingress in Banni Plains,Kachchh, Gujarat using multi-temporal satellite data

The Rann ingress into the ‘Banni Plains’ of Kachchh district, Gujarat which is famous for the sprawling grasslands supporting significant cattle population is taking place at an alarming rate. This has resulted in the desertion of many villages due to intrusion of Rann waters. In the present investigation multi-date satellite data has been analysed to map and monitor the Rann ingress during the period 1975 to 1989. Detailed analysis has brought out that the inundation is quite rapid affecting about 244 sq. km area during 1960–1989 period. Mapping of the creeks has also been done to understand the possible mechanism of ‘Rann ingress’.     

On pressure-work,viscous dissipation and the energy balance relation for geothermal reservoirs

This article examines the conditions under which the pressure-work and viscous dissipation terms should be retained in the energy balance relation for single (liquid water or vapor) and two-phase (liquid water and vapor) fluid flow through porous media. It is shown that if one wishes to retain the pressure-work term, then one must also keep the viscous dissipation term in the energy balance. Consideration of steady non-isothermal radial flow demonstrates that both pressure-work and viscous dissipation are liable to have negligibly small effects in single phase liquid water and in two-phase liquid-vapor systems. This conclusion is, however, not generally valid for pure vapor systems; in this case, pressure-work and viscous dissipation can produce significant variations in the computed reservoir response.     

Estimation and comparison of leaf area index of agricultural crops using irs liss-III and EO-1 hyperion images

Motivated by the increasingly availability and importance of hyperspectral remote sensing data, this study aims to determine whether current generation narrowband hyperspectral remote sensing data could be used to estimate vegetation Leaf Area Index (LAI) accurately than the traditional broadband multispectral data. A comparative study has been carried out to evaluate the performance of the narrowband Normalized Difference Vegetation Index (NDV1) derived from Hyperion hyperspectral sensor with that of derived from IRS LISS-III for the estimation of LAI of some major agricultural crops (e.g. cotton, sugarcane and rice) in part of Guntur district, India. It has been found that the narrowband NDVI derived from Hyperion has shown better results over its counterpart derived from broadband LISS-III. Linear regression models have been used which with selected subsets of individual Hyperion bands performed better to predict LAI than those based on the broadband datasets, although the potential to overfit models using the large number of available Hyperion bands is a concern for further research.     

Superoxide-mediated reduction of organically complexed iron(III): Impact of pH and competing cations (Ca)

The mechanism and kinetics of superoxide-mediated reduction of a variety of organic iron(III) complexes has been investigated over the pH range 7-9. Our experimental results show that the rate of iron(II) formation is a function of pH, ligand type and ligand concentration with the measured rate varying between 0.44 ± 0.07 and 39.25 ± 1.77 pM s⁻¹ in the systems investigated. Additionally, our results show that the presence of competing cations such as Ca²⁺ have a significant impact on iron(II) formation if the organic ligand is strongly complexed by Ca²⁺. Formation of iron(II) occurs by either (or, in some instances, both) reaction of superoxide with inorganic iron(III) after its dissociation from the complex (dissociative reduction) or by direct reaction of superoxide with the complex (non-dissociative reduction). In the presence of weak ligands, dissociative reduction (DR) dominates; however non-dissociative reduction (NDR) becomes important in the presence of either strongly binding ligands or high concentrations of weakly binding ligands. The major factors contributing to the pH dependence of the iron(II) formation rate are the complexation kinetics of inorganic iron(III) (which controls the DR contribution) and the reduction kinetics of the iron(III) complex (which controls the NDR contribution). The relative NDR contribution increases with increasing superoxide and ligand concentration and decreasing pH for all ligands examined. Since iron(II) formation occurring via NDR results in a significantly larger increase in the proportion of iron in free aquated form than does DR, this non-dissociative pathway of superoxide-mediated iron(III) reduction is particularly effective in increasing the lability of iron in aquatic systems.