Hydrous pyrolysis of a Type III source: fractionation effects during primary migration in natural and artificially matured samples

A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores.     

Analysis of Blast Vibration Characteristics Across a Trench and a Pre-Split Plane

This paper presents the influence of various discontinuities, natural or artificial, on magnitude and frequencies of blast induced ground vibrations. These discontinuities were geological faults, a pond, a shaft incline, a trench and a pre-split plane interposed in the path of vibration propagation. In the post-trench region, ground vibrations in terms of peak particle velocity were significantly reduced and dominant frequencies in higher bands were consequently observed. Depth of trench with respect to blastholes were varied and consequent vibration characteristics were analyzed. The techniques of creating a trench and pre-split plane were successfully implemented in controlling vibration and in increasing the explosives charge to meet the scheduled production target of an opencast mine. Comparisons of ground vibration characteristics affected by a trench and a pre-split plane of the same depth are described in the text. The findings lead to the conclusion that such experimental data are necessary for production blasting in open cast mines under constrained conditions.     

Way forward to achieve sustainable and cost-effective biofuel production from microalgae: a review

Driven by policies aimed at enhancing energy security and mitigating greenhouse gas emissions, the production and use of biofuels have significantly increased in recent years. Microalgae owing to its multiple advantages which include high lipid content, sustainable biomass production, effective land and water utilization are the most potential biofuel feedstock that can provide drop-in fossil fuel replacements without stimulating competition for agricultural resources and are considered to be more environmentally benign than the first- and second-generation biofuel feedstocks. However, there are many existing technical and scientific impediments that are yet to be resolved. Keeping this in view, the present review provides a concise account of the microalgal species known to accumulate high levels of lipid and describes the main factors that should be taken into consideration while selecting suitable algal strains for mass cultivation. The underlining advantages and limitations of raceway pond and photobioreactor cultivation systems are also examined. The recent advances in genetic engineering of microalgae to improve biomass and lipid productivity are then highlighted, which include the ongoing debate over the biosafety issues pertinent to the use of genetically modified algae. Furthermore, a wide range of high-value products that can be co-produced from microalgae have been discussed. The review concludes with a comprehensive summary of the major techno-economic constraints to commercialization of algal-derived biofuels along with promising methods for overcoming these challenges in order to produce cost-competitive and environmentally sustainable biofuel.     

Spatio-temporal variations of respirable particles at residential areas located in the vicinity of opencast coal projects,India: a case study

The objective of the study is to investigate spatio-temporal variations of PM₁₀, PM_2.5, and PM₁ concentrations at seven residential sites, located in the vicinity of opencast coal projects, Basundhara Garjanbahal Area (BGA), India. Meteorological parameters such as wind speed, wind direction, relative humidity, and temperature were collected simultaneously with PM concentrations. Mean concentrations of PM₁₀ in the range 215 ± 169–526 ± 412 μg m^?3, PM_2.5 in the range of 91 ± 79–297 ± 107 μg m^?3, PM₁ in the range of 68 ± 60–247 ± 84 μg m^?3 were obtained. Coarse fractions (PM_2.5–10) varied from 27 to 58% whereas fine fractions (PM_1–2.5 and PM₁) varied in the range of 51–73%. PM_2.5 concentration was 41–74% of PM₁₀ concentration, PM₁ concentration was 31–62% of PM₁₀ concentration, and PM₁ concentration was 73–83% of PM_2.5 concentration. Role of meteorology on PM concentrations was assessed using correlation analysis. Linear relationships were established among PM concentrations using least square regression analysis. With the aid of principal component analysis, two components were drawn out of eight variables, which represent more than 75% of variance. The results indicated that major sources of air pollutants (PM₁₀, PM_2.5, PM₁, CO, CO₂) at the residential sites are road dust raised by vehicular movement, spillage of coal generated during transportation, spontaneous combustion of coal, and biomass burning in village area.     

New insights on petrography and geochemistry of impactites from the Lonar crater,India

The Lonar impact crater, India, is one of the few known terrestrial impact craters excavated in continental basaltic target rocks (Deccan Traps, ~65 Ma). The impactites reported from the crater to date mainly include centimeter‐ to decimeter‐sized impact‐melt bombs, and aerodynamically shaped millimeter‐ and submillimeter‐sized impact spherules. They occur in situ within the ejecta around the crater rim and show schlieren structure. In contrast, non–in situ glassy objects, loosely strewn around the crater lake and in the ejecta around the crater rim do not show any schlieren structure. These non–in situ fragments appear to be similar to ancient bricks from the Daityasudan temple in the Lonar village. Synthesis of existing and new major and trace element data on the Lonar impact spherules show that (1) the target Lonar basalts incorporated into the spherules had undergone minimal preimpact alteration. Also, the paleosol layer as preserved between the top‐most target basalt flow and the ejecta blanket, even after the impact, was not a source component for the Lonar impactites, (2) the Archean basement below the Deccan traps were unlikely to have contributed material to the impactite parental melts, and (3) the impactor asteroid components (Cr, Co, Ni) were concentrated only within the submillimeter‐sized spherules. Two component mixing calculations using major oxides and Cr, Co, and Ni suggest that the Lonar impactor was a EH‐type chondrite with the submillimeter‐sized spherules containing ~6 wt% impactor components.     

Geological remote sensing in parts of subarnarekha — baitarani basin,Eastern India

Landsat imagery have been interpreted visually and under Additive Colour Viewer to interpret the regional geology and geomorphology in parts of Subarnarekha-Baitarani basin. The area lies south of Singhbhum shear zone and represents Precamrain shield. Important Simlipal ultrabasic volcanic complex of Orissa is included in the area. Although detailed map of the area is available, yet an attempt has been made to interpret the imagery for evaluating the results provided in comparison to the existing maps. Delineation of main lithological groups is possible. Having some data from the existing maps, lithoiogical boundary delineation of Mica Schist-Phyllite-Quartzite, Granites and Gneisses, Dhanjori Lava, Anorthosite-Gabbro Complex and Dolerite dykes, all of Precambrian age, has been done. Laterite and Quaternary sediments are also picked up. Lineament mapping has been carried out from imagery, which is difficult to map in the field. N--S and NNW-SSE lineament system is very prominent in Simlipal complex whereas in other parts NNW-SSE and NNE-SSW trends are common. The major fault plane running NNE-SSW in the area is responsible for the present-day configuration of Subarnarekha river. Identification of different geomorphological units is perhaps best done on imagery. Several geomorphic units like structural Hill, Denudational Hill, Pediment, Buried Pediment, Lateritic Clay Plain, Laterite upland, Terrace Plain etc have been mapped. Valley fills are wellpicked up from imagery. Hydrogeological potentiality of the different geologic and geomorphic units have been evaluated qualitatively. Ground water occurrence, movement and potentiality are mainly controlled by structural, geological and geomorphological set-up of the area. Buried Pediment, Laterite upland, Laterite clay plain and alluvial fills are the potential zones from the view point of ground water occurrences. Comparative study of the different Landsat bands and band-filter combinations under Additive Colour Viewer has been undertaken to find out the enhancement capability in delineating features. It is found that small scale geological and geomorphological maps can be prepared from Landsat imagery.