Biosorption of Cd(II), Ni(II) and Pb(II) from Aqueous Solution by Dried Biomass of Aspergillus niger: Application of Response Surface Methodology to the Optimization of Process Parameters

In this study, the biosorption of Cd(II), Ni(II) and Pb(II) on Aspergillus niger in a batch system was investigated, and optimal condition determined by means of central composite design (CCD) under response surface methodology (RSM). Biomass inactivated by heat and pretreated by alkali solution was used in the determination of optimal conditions. The effect of initial solution pH, biomass dose and initial ion concentration on the removal efficiency of metal ions by A. niger was optimized using a design of experiment (DOE) method. Experimental results indicated that the optimal conditions for biosorption were 5.22 g/L, 89.93 mg/L and 6.01 for biomass dose, initial ion concentration and solution pH, respectively. Enhancement of metal biosorption capacity of the dried biomass by pretreatment with sodium hydroxide was observed. Maximal removal efficiencies for Cd(II), Ni(III) and Pb(II) ions of 98, 80 and 99% were achieved, respectively. The biosorption capacity of A. niger biomass obtained for Cd(II), Ni(II) and Pb(II) ions was 2.2, 1.6 and 4.7 mg/g, respectively. According to these observations the fungal biomass of A. niger is a suitable biosorbent for the removal of heavy metals from aqueous solutions. Multiple response optimization was applied to the experimental data to discover the optimal conditions for a set of responses, simultaneously, by using a desirability function.     

Optimization of a Photo‐assisted Fenton Oxidation Process: A Statistical Model for MDF Effluent Treatment

In the present study, the effects of initial COD (chemical oxygen demand), initial pH, Fe²⁺/H₂O₂ molar ratio and UV contact time on COD removal from medium density fiberboard (MDF) wastewater using photo‐assisted Fenton oxidation treatment were investigated. In order to optimize the removal efficiency, batch operations were carried out. The influence of the aforementioned parameters on COD removal efficiency was studied using response surface methodology (RSM). The optimal conditions for maximum COD removal efficiency from MDF wastewater under experimental conditions were obtained at initial COD of 4000 mg/L, Fe²⁺/H₂O₂ molar ratio of 0.11, initial solution pH of 6.5 and UV contact time of 70 min. The obtained results for maximum COD removal efficiency of 96% revealed that photo‐assisted Fenton oxidation is very effective for treating MDF wastewater.     

Spectral-spatial classification of hyperspectral images using wavelet transform and hidden Markov random fields

This paper proposes a spectral–spatial method for classification of hyperspectral images. The proposed method, called SSC, consists of two steps. In the first step, to overcome the computation complexity, a wavelet-based classifier is designed. In the second step, to enhance the classification accuracy, a novel hidden Markov random field called NHMRF technique in spatial domain is suggested. In NHMRF, we convert two-dimensional energies of traditional hidden Markov random field to three-dimensional energies and then we apply edge preserving regularization terms on each two-dimensional energy of this cube. The class label of each test pixel is fixed based on minimum three-dimensional energy achieved by edge preserving regularization terms. Experimental results show that the classification accuracy of the proposed approach based on three-dimensional energies and edge preserving regularization terms is effectively improved in comparison with the state-of-the-art methods.     

Co‐composting of Municipal Solid Waste with Sawdust: Improving Compost Quality

The aim of present study was to improve compost quality as well as to achieve an optimum C/N ratio in compost, reduction in heavy metal content and increased water‐holding capacity of composting piles in arid areas. Four windrow compost piles were prepared by mixing sawdust at various dosages with municipal solid waste (MSW). The sawdust was mixed with MSW at 0% (MSW0), 16% (MSW16), 32% (MSW32), and 70% (MSW70) on dry weight basis. The compost piles were monitored daily by recording the temperature, while, weekly measurement was done on C/N ratio, moisture, pH, and electrical conductivity (EC). The addition of 16% sawdust increased the initial C/N to the optimum level and decreased N loss during the composting process. The MSW16 and MSW32 exhibited better temperature dynamics and their composting period seemed to be shorter than that of MSW0 and MSW70. Moreover, addition of sawdust caused lowering of moisture loss from the composting piles. Sawdust admixtures also produced lowering of pH and EC values and led to lower heavy metal content in final products. The quality of the final compost makes it possible to propose the use of this experimental procedure for building up a novel mass reduction of the initial composted waste mixtures.     

The mafic–ultramafic complex of Sikhoran (central Iran): a polygenetic ophiolite complexLe massif basique-ultrabasique de Sikhoran (Iran central) : un complexe ophiolitique polygénétique

The mafic–ultramafic complex of Sikhoran presents a long geological history, marked out by various magmatic, metamorphic and tectonic events. This history is much more complex than a simple ophiolite obduction over a continental margin. As early as the Upper Permian, following a mantle uprise in a Tethysian supra-subduction zone, the opening of a (back-arc?) basin in extensional/transtensional conditions provoked the intrusion of multiple gabbroic dykes, veins and plutons charged with fluids, through a mafic/ultramafic complex and its metamorphic cover. Several basins, characterised by abundant submarine basaltic volcanism developed during Jurassic, whose feeding dykes may be represented by the diabase dyke swarms intruding the whole Sikhoran complex and its metamorphic cover. To cite this article: H. Ghasemi et al., C. R. Geoscience 334 (2002) 431–438.