Effect of some additives on synthesis of zeolite from coal fly ash

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.     

Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.     

煤中黄铁矿的成因研究

本文在系统地研究四川晚二叠世高硫煤中黄铁矿矿物学的基础上，运用微区电子探针、中子活化、Ｘ光电子能谱和硫同位素等多 种方法综合地研究煤中黄铁矿的结构、成分、价态及同位素等成因标型特征，对黄铁矿标型特征进行了成因探讨，有效地判别了成岩期形成的Ｉ型脉状黄铁矿及后生热液Ⅱ型脉状黄铁矿。同时提出直接沉淀系列（自形晶→集合→聚晶）和复杂成因（微粒、莓粒→圆球→结核→团块）等两大类成因演化模式。它不仅对不同类型     

煤中微量元素分布特征初步研究

采自我国不同聚煤区的不同时代的89件煤样品,用中子活化分析法(INAA)分别测定了29种微量元素。据统计分析结果表明:(1)绝大多数微量元素的平均值高于世界的平均值,含量范围也较美国宽。我国各聚煤区不同时代间相比较,煤中大多数元素的平均含量和富集因数,从华南二叠纪至华北石炭—二叠纪到全国中-新生代逐渐降低。(2)中-新生代的煤中,元素间的相关性较好,华南二叠纪次之,而华北石炭—二叠纪的煤最差。(3)REE分布模式类型以中-新生代的煤最复杂;而华北石炭—二叠纪的煤较简单。     

Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids

This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, R_r=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids.     

湖南瑶岗仙钨矿中石英的标型特征

以湖南宜章县瑶岗钨矿床为例，较系统地研究了石英的标型特征，如稀土元素，微量元素，铝及碱质含量，热发光性，包体化学成分和温度，红外光谱等，总结了这类矿床的石英标型特征以及含矿石英与无矿石英的区别。     

火山地震的理论地震图计算方法

本文首先分析了不同类型火山地震的波形,提出了相应的震源模型.然后发展了计算层状介质理论地震图的部分分离变量—有限差分方法,其最重要的环节是引用了吸收边界条件,使计算工作得以简化.这种方法特别适用于火山地震的理论地震图计算.最后,本文给出了计算实例.     

大震前地磁场时空间线性度变化的初步研究

把用来分析地震波波形的时间线性度和空间线性度两种方法，应用到地磁资料分析当中，具体分析处理了１９７６年７月２８日唐山Ｍｓ７．８地震和１９８９年１０月１９日大同Ｍｓ６．１地震前后地磁场资料，并对这两次地震前后地磁时空线性度变化情况进行了研究。所得结果表明：①较大地震前地磁场的时空线性度均可能呈现出较明显的下降异常变化，有些在震前回升，②各分量的时空线性度呈现异常的时间基本上同步，并与波速异常发展趋势基本相符。     

地震波动力学特征变化指标在短期地震预报中的应用

本文研究了地震前地震波动力学特征的变化，主要是波形和频谱的变化，并从中提取出可望在短期（半年以内）地震预报中应用的一些预报指标。这些指标包括：Ｐ波初始部分波形的时间线性度和空间线性度，初始段平均半周期，Ｓ，Ｐ波频谱的峰值频率，拐角频率，相对带宽度，相对频谱峰值，高频段的谱线斜率绝对值等。同时还研究了短周期地脉动的波形线性度及频谱特征量（峰值频率等）在大震前出现的短期（半年以内）和临震（９天以内）的     

神经网络方法在地震预报研究中的初步应用

本文把神经网络方法引进地震预报研究当中。使用地震频次，最大震级，平均震级，等价地震次数等多项地震活动性指标作为神经网络的输入，未来时段内的最大地震震级作为其输出，可以对某一固定地区的最大地震震级作出中近期预报。选用的神经网络模型为含两个中间层的前向模型，并采用ＢＰ算法。所得结果表明，用神经网络方法可以在一定精度范围内使震级预报的内检符合率达到１００％，在本文的例子中，外推预报准确率达到６０％以上。