Temperature–salinity modeling for Ruwais coastal area in United Arab Emirates

A three dimensional rectangular grid model is applied to resolve the temperature–salinity dynamics of Ruwais, a segment of the UAE coast which is well known as dense water formation zone. The model employs a heat flux module and a turbulence closure scheme that facilitate realistic calculation of temperature–salinity dynamics. A field survey campaign is carried out to support the modeling study, involving measurements of tide, currents, temperature, and salinity. Investigation is done for two meteorologically extreme conditions, i.e. summer and winter. The model study showed that the western flux develops an anticlockwise circulation in the study area. The water industrial discharges elevated the temperature and salinity of the water near the southeastern shoreline. This water mass propagated towards north under the influence of gravity.     

Polybrominated diphenyl ethers and their methoxylated analogs in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) from Bizerte Lagoon, Tunisia

Concentrations of ten polybrominated diphenyl ethers (PBDEs) and eight methoxylated polybrominated diphenyl ethers (MeO-PBDEs) in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) collected from the Bizerte Lagoon and the Mediterranean Sea were investigated. To the best of our knowledge, this is the first report of these compounds in marine fishes from Tunisia. The PBDE mean concentrations in fish from Bizerte Lagoon were 45.3 and 96.2 ng g(-1) lw respectively in mullet and sea bass, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea were 7.80 and 27.9 ng g(-1) lw respectively. MeO-PBDE concentrations in mullet and sea bass from Bizerte Lagoon ranged from 6.46 to 286 ng g(-1) lw and from 49.4 to 798 ng g(-1) lw respectively, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea ranged from 190 to 401 ng g(-1) lw and from 353 to 578 ng g(-1) lw respectively. The total PBDEs and total MeO-PBDEs concentration in fish from Bizerte Lagoon were similar or slightly lower than those reported for other species from other locations around the world.     

CLoE,a new rate-type constitutive model for geomaterials theoretical basis and implementation

The paper describes the basic ideas and the main features of a new class of constitutive laws, in the framework of incrementally non-linear constitutive equations. CLoE is a generic name for that new class of laws, with reference to consistency at the limit surface, and explicit localization analysis. A top–down analysis of the model is presented, and illustrated by examples.     

Automatic interpretation of pumping tests data using metaheuristics

Pumping tests data interpretation is of major importance in groundwater engineering. It is traditionally performed in a subjective manner by means of standard type curves. In this paper, an automatic interpretation of time-drawdown data has been proposed based on two algorithms, the real-coded genetic algorithm and differential evolution. The proposed approaches combine metaheuristic algorithms with an appropriate analytical drawdown solution depending upon the nature of the considered aquifer system, leaky or naturally fractured rock aquifers. The standard error of estimate (SEE) was used as a performance criterion to evaluate the discrepancies between predicted and observed drawdown data in different pumping time periods. Both of the proposed metaheuristic algorithms provide accurate aquifer parameters. For all analyzed pumping tests data, the differential evolution yielded the most accurate results with an improvement in SEE values ranged from 0.2 to 50% compared to previously published results, and exhibits speed and robustness. Furthermore, a new full range numerical evaluation of the Hantush well function based on a tanh-sinh quadrature scheme has been proposed. Our results indicate that our method is accurate, since the maximum relative error was found to be equal to 0.00036%, and practical, since it is free from special functions and could be easily incorporated within an optimization technique to analyze transient time-drawdown data.     

Paleoenvironmental significance of aluminum phosphate-sulfate minerals in the upper Cretaceous ooidal ironstones,E-NE Aswan area,southern Egypt

Aluminum phosphate-sulfate (APS) minerals are present as small, disseminated crystals in the upper Cretaceous shallow marine ooidal ironstones, E-NE Aswan area, southern Egypt. Their association with the ironstones is considered as a proxy of subaerial weathering and post-diagenetic meteoric water alteration. The mineralogical composition of the ooidal ironstones was investigated by optical and scanning electron microscopes, X-ray diffraction, Fourier transform infrared and Raman spectroscopy. The ooidal ironstones are composed mainly of ooids and groundmass, both of which consist of a mixture of detrital (quartz) and diagenetic (fluorapatite, chamosite and pyrite) mineral assemblages. These mineral assemblages are destabilized under acidic and oxidizing, continental conditions. These conditions resulted from the oxidation of pyrite and probably organic matter under warm and humid, tropical climate followed the Santonian Sea regression and subaerial exposure. These pedogenic conditions promoted corrosion of quartz, dissolution of chamosite and apatite and hydrolysis of feldspars of the nearby exposed granitoids. The released Si, Al and Sr from quartz, chamosite and feldspars; Fe and S from pyrite and P, Ca and light rare earth elements (LREE) from apatite are reprecipitated as hematite, kaolinite, apatite and APS minerals from the pore fluids or along fractures. The paragenetic sequence and textural relationships of this post-diagenetic mineral assemblage indicate that hematite was formed by replacement of chamosite followed by formation of a secondary generation of pore filling chlorapatite and APS minerals and finally the precipitation of kaolinite in the remaining pore spaces. The formation of APS minerals and chlorapatite is simultaneous, but APS minerals are stable at shallow depths under acidic to neutral pH conditions, whereas chlorapatite is stable under alkaline pH conditions. Alkaline conditions were maintained at greater depths when the infiltrated acidic fluids reacted with chamosite. The APS minerals display a homogeneous chemical composition in all ironstone locations in Aswan area, corresponding to a solid solution between crandallite (CaAl₃(PO₄)₂(OH)₅·H₂O), goyazite (SrAl₃(PO₄)₂(OH)₅·H₂O), svanbergite (SrAl₃(PO₄)(SO₄)(OH)₆) and woodhouseite (CaAl₃(PO₄)(SO₄)(OH)₆) end-members. The variations in the APS mineral chemistry (AB₃(XO₄)₂(OH)₆) are essentially due to variable substitutions of Sr and LREE for Ca at the A site and limited S for P at the X site. The spatial distribution of APS minerals and their composition in the ooidal ironstones of Aswan area permitted to consider them as good tracers of physicochemical and paleoenvironmental changes, in particular those associated with subaerial exposure and pedogenesis. The post-diagenetic phosphatization and kaolinization of the Aswan ironstones decrease their economic potentiality; thus, understanding paragenetic sequence and textural relationships is essential for the iron ore beneficiation.     

Facies analysis and palaeoclimatic significance of ironstones formed during the Eocene greenhouse

Lower and middle Eocene ironstone sequences of the Naqb and Qazzun formations from the north‐east Bahariya Depression, Western Desert, Egypt, represent a proxy for early Palaeogene climate and sea‐level changes. These sequences represent the only Palaeogene economic ooidal ironstone record of the Southern Tethys. These ironstone sequences rest unconformably on three structurally controlled Cenomanian palaeohighs (for example, the Gedida, Harra and Ghorabi mines) and formed on the inner ramp of a carbonate platform. These palaeohighs were exposed and subjected to subaerial lateritic weathering from the Cenomanian to early Eocene. The lower and middle Eocene ironstone sequences consist of quiet water ironstone facies overlain by higher energy ironstone facies. The distribution of low‐energy ironstone facies is controlled by depositional relief. These deposits consist of lagoonal, burrow‐mottled mud‐ironstone and laterally equivalent tidal flat, stromatolitic ironstones. The agitated water ironstone facies consist of shallow subtidal–intertidal nummulitic–ooidal–oncoidal and back‐barrier storm‐generated fossiliferous ironstones. The formation of these marginal marine sequences was associated with major marine transgressive–regressive megacycles that separated by subaerial exposure and lateritic weathering. The formation of lateritic palaeosols with their characteristic dissolution and reprecipitation features, such as colloform texture and alveolar voids, implies periods of humid and warm climate followed major marine regressions. The formation of the lower to middle Eocene ironstone succession and the associated lateritic palaeosols can be linked to the early Palaeogene global warming and eustatic sea‐level changes. The reworking of the middle Eocene palaeosol and the deposition of the upper Eocene phosphate‐rich glauconitic sandstones of the overlying Hamra Formation may record the initial stages of the palaeoclimatic transition from greenhouse to icehouse conditions.     

Using Vertical Electrical Soundings for Characterizing Hydrogeological and Tectonic Settings in Deir El-Adas Area,Yarmouk Basin,Syria

The present study is aimed at characterizing the subsurface geological and tectonic structure in Deir El-Adas area, by using Vertical Electrical Sounding survey (VES) and hydrogeological investigations, in order to determine the causes of the failure for the majority of the wells drilled in the area. The survey data was treated in three different approaches including direct VES inversion, pseudo-2D method and horizontal profiling, in order to maximize the reliability of the data interpretation. The results revealed the presence of a local faulted anticline structure at the top of the Paleogene formation, underneath the basaltic outcrops where Deir El-Adas village is situated. The appearance of this subsurface anticline structure has complicated the local hydro-geological situation, and most likely led to limitation of the groundwater recharge in the area. Moreover, the performed piezometric and discharge maps indicated the presence of a notable groundwater watershed, in addition to feeble water productivity of the wells drilled adjacent to Deir El-Adas, mostly related to the subsurface geological and tectonic settings in the area.     

The biostratigraphic and paleoecological importance of the subsurface Carboniferous microfossil assemblages from Faghur-1x well,Western Desert of Egypt

The microfossil assemblages of subsurface Carboniferous rocks from Faghur-1x were examined and identified. Their biostratigraphical and paleoenvironmental importance were investigated. The assemblage included well-preserved foraminifera like Omphalotis omphalota, Omphalotis sp. 2, Omphalotis sp. 3, Paraarchaediscus stilus, Paraarchaediscus koktjubensis, Archaediscus krestovnikovi, Archaediscus complanatus, Archaediscus inflatus, Archaediscus karreri, Diplosphearina inequalis, Eotubertina sp., Tetrataxis conica, Cribrostomum lecomptei, Palaeotextularia angulata, and Palaeotextularia longiseptata. This foraminiferal association indicates the late Viséan-early Serpukhovian. The other microfossils are gastropods, brachiopods, ostracods, crinoidal ossicles, frond-like fenestrate bryozoan types and stick-like colonies, echinoderms, microproblematica like Draffania biloba and algal Calcisphaera and the dasyclad Koninckopora. This microfossils assemblage points to the deposition in a restricted to open platform in a lagoonal framework environment. The Tehenu Basin is the eastern segment of northern African Sahara basins that provided refuge for the foraminiferal genera through the mass extinction events during the glacial Viséan-Serpukhovian times. However, its foraminiferal associations have lower diversities than the western basins, which indicate that it was more readily affected by the mass extinction event.