Compositional variations (major and trace elements) of clinopyroxene and Ti-andradite from pyroxenite, ijolite and nepheline syenite, Alnö Island, Sweden

Clinopyroxenes from pyroxenite, ijolite and nepheline syenite from the main intrusion of the Alnö complex define two sub-parallel compositional trends with respect to Na, Ca and Fe_TOT plotted against alkali-pyroxene fractionation index (Na–Mg). Both trends define a smooth fractionation of increasing Na and Fe_TOT and decreasing Ca with increasing Na–Mg, but one set of samples contain clinopyroxenes that constantly plot at higher Na and lower Fe_TOT and Ca (at similar Na–Mg) than the rest of the samples. Clinopyroxenes with higher Ca and Fe_TOT and lower Na (trend 1) co-exist with substantial amounts of Ti-andradite (up to 70 vol.%), while the sample set defining the more Na-rich trend (trend 2) lack co-existing Ti-andradite. Clinopyroxenes from both trends show fractionated REE patterns with a distinct difference in HREE content, reflecting the content of co-existing Ti-andradite. The rocks of the first Ti-andradite-bearing trend crystallized slightly prior to the rocks of the second trend, probably from a primitive, Ca- and Ti-rich nephelinitic magma. Crystallisation of pyroxenite and melteigite occurred under low aSiO₂ and high aCaO and aTiO₂ as evidenced by the presence of perovskite and sometimes substantial amounts of magnetite. Subsequent increase in aSiO₂ is evidenced in the overgrowth of perovskite by titanite, which in turn is overgrown by Ti-andradite. Nepheline syenitic residuals crystallized under higher aSiO₂ and aNa₂O and lower aCaO and aTiO₂, which reduced Ti-andradite into an accessory phase and produced more Si- and Na-rich clinopyroxenes. Some of these residuals probably also mixed with new primitive magma producing a hybrid magma that crystallised the more Na-rich and Ca- and Fe_TOT-poor clinopyroxenes of trend 2. The complete lack of Ti-andradite in these rocks indicates different crystallisation conditions and also a different magma composition.     

An Eocene/Oligocene blueschist‐/greenschist facies P–T loop from the Cycladic Blueschist Unit on Naxos Island,Greece: Deformation‐related re‐equilibration vs. thermal relaxation

Geothermobarometric and geochronological work indicates a complete Eocene/early Oligocene blueschist/greenschist facies metamorphic cycle of the Cycladic Blueschist Unit on Naxos Island in the Aegean Sea region. Using the average pressure–temperature (P–T) method of thermocalc coupled with detailed textural work, we separate an early blueschist facies event at 576 ± 16 to 619 ± 32°C and 15.5 ± 0.5 to 16.3 ± 0.9 kbar from a subsequent greenschist facies overprint at 384 ± 30°C and 3.8 ± 1.1 kbar. Multi‐mineral Rb–Sr isochron dating yields crystallization ages for near peak‐pressure blueschist facies assemblages between 40.5 ± 1.0 and 38.3 ± 0.5 Ma. The greenschist facies overprint commonly did not result in complete resetting of age signatures. Maximum ages for the end of greenschist facies reworking, obtained from disequilibrium patterns, cluster near c. 32 Ma, with one sample showing rejuvenation at c. 27 Ma. We conclude that the high‐P rocks from south Naxos were exhumed to upper mid‐crustal levels in the late Eocene and early Oligocene at rates of 7.4 ± 4.6 km/Ma, completing a full blueschist‐/greenschist facies metamorphic cycle soon after subduction within c. 8 Ma. The greenschist facies overprint of the blueschist facies rocks from south Naxos resulted from rapid exhumation and associated deformation/fluid‐controlled metamorphic re‐equilibration, and is unrelated to the strong high‐T metamorphism associated with the Miocene formation of the Naxos migmatite dome. It follows that the Miocene thermal overprint had no impact on rock textures or Sr isotopic signatures, and that the rocks of south Naxos underwent three metamorphic events, one more than hitherto envisaged.     

Sediment supply and climate change: implications for basin stratigraphy

The rate of sediment supply from erosional catchment to depositional basin depends primarily upon climate, relief, catchment slope and lithology. It varies in both time and space. Spatial changes in erosion rates due to variations in lithology are illustrated by contrasting rates of drainage divide migration away from faults of known ages. Time variations in relative sediment supply are extremely complex and vary widely according to the direction and magnitude of climate change. In many parts of the Great Basin and south-western USA, glacial maximum climates were characterized by higher effective moisture and the altitudinal downward spread of woods and forests. Sparse data from alluvial fans indicate reduced sediment supply, despite the increased runoff evident from higher lake levels. The situation in Mediterranean areas is less clear, with rival climatic scenarios for vegetation ecotypes predicting contrasting runoff. In order to test these latter we run Cumulative Seasonal Erosion Potential [CSEP] experiments for present-day and a variety of full-glacial Mediterranean candidate climates. The results indicate the likelihood of enhanced sediment supply and runoff compared to the present day during full-glacial times for a cool wet winter climate and a reduction in sediment supply and runoff for a full-glacial cool dry winter climate. We then explore the consequences of such phase differences in sediment supply, and sea and lake levels for the stratigraphy of sedimentary basins. Highstands and lowstands of sea or lake may be accompanied by greater or lesser sediment and water supply, as determined by the regional climate and the direction of climatic change. Thus marine lowstands are not necessarily periods of great transfer of coarse clastic sediments to shelves and deep water basinal environments. Unsteady sediment supply has greatest implications for alluvial systems, in particular the effect that changing relative supplies of water and sediment have upon river and fan channel incision.     

Visual characterization technique for gravel‐cobble river bed surface sediments; validation and environmental applications Contribution to the programme of CIRSA (Centre Interuniversitaire de Recherche sur le Saumon Atlantique)

This paper presents an evaluation of the feasibility and the reliability of a visual characterization technique for gravel–cobble river bed surface substrate. Based on principal axis regressions, using phi scale (ϕ), comparisons of visual estimation and grid sampling techniques show that useful predictive relations (R² = 0·78–0·88) exist between visual estimates of the surface d₁₆, d₅₀ and d₈₄ and estimates obtained for the same percentiles with the grid sampling technique. Comparisons of visual estimation and the surface‐bulk sampling technique also indicate a predictive relation (R² = 0·70) between the d₅₀ of the two methods. Trained operators can visually estimate gravel–cobble bed surface d₁₆ to uncertainties of 41 per cent, d₅₀ to 15 per cent and d₈₄ to 11 per cent (for example, there is a 5·5 mm error on a d₈₄ size of 50 mm). Furthermore, evidence shows that if operators are properly trained, a calibration relation for each percentile can be applied independently of operators. This visual characterization allows effective detailed mapping of spatial patterns in substrate size distribution along extensive reaches of gravel‐bed rivers. The technique can be very useful in creating terrain models for various geomorphological, hydrological and biological applications such as the determination of entrainment thresholds, hydraulic roughness and substrate suitability for benthic insects or salmonid habitat. Copyright © 2001 John Wiley & Sons, Ltd.