Supercritical gas sorption on moist coals

The effect of moisture on the CO₂ and CH₄ sorption capacity of three bituminous coals from Australia and China was investigated at 55 °C and at pressures up to 20 MPa. A gravimetric apparatus was used to measure the gas adsorption isotherms of coal with moisture contents ranging from 0 to about 8%. A modified Dubinin–Radushkevich (DR) adsorption model was found to fit the experimental data under all conditions. Moisture adsorption isotherms of these coals were measured at 21 °C. The Guggenheim–Anderson–de Boer (GAB) model was capable of accurately representing the moisture isotherms over the full range of relative pressures.Moist coal had a significantly lower maximum sorption capacity for both CO₂ and CH₄ than dry coal. However, the extent to which the capacity was reduced was dependent upon the rank of the coal. Higher rank coals were less affected by the presence of moisture than low rank coals. All coals exhibited a certain moisture content beyond which further moisture did not affect the sorption capacity. This limiting moisture content was dependent on the rank of the coal and the sorbate gas and, for these coals, corresponded approximately to the equilibrium moisture content that would be attained by exposing the coal to about 40–80% relative humidity. The experimental results indicate that the loss of sorption capacity by the coal in the presence of water can be simply explained by volumetric displacement of the CO₂ and CH₄ by the water. Below the limiting moisture content, the CO₂ sorption capacity reduced by about 7.3 kg t^− 1 for each 1% increase in moisture. For CH₄, sorption capacity was reduced by about 1.8 kg t^− 1 for each 1% increase in moisture.The heat of sorption calculated from the DR model decreased slightly on addition of moisture. One explanation is that water is preferentially attracted to high energy adsorption sites (that have high energy by virtue of their electrostatic nature), expelling CO₂ and CH₄ molecules.     

Meadow fragmentation and reproductive output of the SE Asian seagrass Enhalus acoroides

Flower and fruit production of the abundant, tall, long-lived, dioecious, surface-pollinating seagrass species Enhalus acoroides (L.) Royle were estimated at seven sites in the reef flats off Bolinao (NW Luzon, The Philippines) featuring different fragmentation of the seagrass meadows. Fragmentation of the seagrass meadow was quantified as cover of E. acoroides and all seagrass species present in 20×20 m plots. E. acoroides and overall seagrass cover were correlated positively. The proportion of female flowers of E. acoroides that developed a fruit increased sharply as overall seagrass cover was around 50%. Apparent sex ratio bore no relationship with overall seagrass cover. This threshold-type of relationship suggests that fragmentation of seagrass meadows can have a major effect on the reproductive output of this species. A possible mechanism underlying these results would be a non-linear increase of the efficiency of trapping the surface-dispersed pollen with increasing seagrass canopy density. This provides the first evidence based on real data that fragmentation can affect the population dynamics of seagrass species.     

Factors affecting spatial and temporal variability in material exchange between the Southern Everglades wetlands and Florida Bay (USA)

Physical and biological processes controlling spatial and temporal variations in material concentration and exchange between the Southern Everglades wetlands and Florida Bay were studied for 2.5 years in three of the five major creek systems draining the watershed. Daily total nitrogen (TN), and total phosphorus (TP) fluxes were measured for 2 years in Taylor River, and ten 10-day intensive studies were conducted in this creek to estimate the seasonal flux of dissolved inorganic nitrogen (N), phosphorus (P), total organic carbon (TOC), and suspended matter. Four 10-day studies were conducted simultaneously in Taylor, McCormick, and Trout Creeks to study the spatial variation in concentration and flux. The annual fluxes of TOC, TN, and TP from the Southern Everglades were estimated from regression equations. The Southern Everglades watershed, a 460-km² area that includes Taylor Slough and the area south of the C-111 canal, exported 7.1 g C m⁻², 0.46 g N m⁻², and 0.007 g P m⁻², annually. Everglades P flux is three to four orders of magnitude lower than published flux estimates from wetlands influenced by terrigenous sedimentary inputs. These low P flux values reflect both the inherently low P content of Everglades surface water and the efficiency of Everglades carbonate sediments and biota in conserving and recycling this limiting nutrient. The seasonal variation of freshwater input to the watershed was responsible for major temporal variations in N, P, and C export to Florida Bay; approximately 99% of the export occurred during the rainy season. Wind-driven forcing was most important during the later stages of the dry season when low freshwater head coincided with southerly winds, resulting in a net import of water and materials into the wetlands. We also observed an east to west decrease in TN:TP ratio from 212:1 to 127:1. Major spatial gradients in N:P ratios and nutrient concentration and flux among the creek were consistent with the westward decrease in surface water runoff from the P-limited Everglades and increased advection of relatively P-rich Gulf of Mexico (GOM) waters into Florida Bay. Comparison of measured nutrient flux from Everglades surface water inputs from this study with published estimates of other sources of nutrients to Florida Bay (i.e. atmospheric deposition, anthropogenic inputs from the Florida Keys, advection from the GOM) show that Everglades runoff represents only 2% of N inputs and 0.5% of P input to Florida Bay.     

Springs of Great Britain

Predictably, in a country such as Britain, with its preponderance of consolidated, sedimentary, mainly fissure-flow aquifers, there is a very large number of springs, many of which are, or have been, used for public supply. Migratory springs are a feature of the British (Ur. Cretaceous) Chalk, the most important British aquifer. The Chalk's low specific yield and high capillary moisture retention together give rise to very considerable fluctuations (more than 33 m in some areas) of the unconfined water table. Along the gentle dip slopes of the Chalk (North and South Downs of southern and southeastern England) springs may migrate laterally for several miles, giving rise to seasonal streams locally known as bournes or lavants. However, springs such as at Duncton, West Sussex, at the base of the much steeper scarp slopes of the Chalk, form point sources, the flows from which tend to be relatively steady; such springs commonly supply and are the original reason for the existence of many of the small towns and villages which nestle along the bases of the chalk scarps of Sussex and Kent.Where the Chalk forms coastal cliffs, a number of springs break out at the base of the cliff between high and low tide levels; there are major chalk coastal springs, for instance, at St. Margaret's Bay (Kent) and at Arish Mells, east of Lulworth Cove, Dorset. Such springs are not used for direct supply (their salinity is usually too high) but are indicators of the presence of local reserves of groundwater for possible future development.     

A comparison of mud- and sand-dominated meanders in a downstream coarsening reach of the mixed bedrock-alluvial Klip River, eastern Free State, South Africa

Along a 28 km reach of the Klip River, eastern Free State, South Africa, mud- and sand-dominated meanders have developed in close proximity within a floodplain wetland up to 1.5 km wide, providing an unusual opportunity to compare their characteristics under similar hydrological conditions. Throughout the reach, the channel bed is grounded on sandstone/shale bedrock although the banks are alluvial, and most river activity occurs during summer high flows. The reach can be divided into three geomorphological zones: Zone 1 (0–11 km), a muddy proximal part with a single meandering channel (w/d < 10) and near-permanent standing water in oxbows and backswamps; Zone 2 (11–17.5 km), a transitional mud-to-sand part with one main channel (w/d  20–30), a number of sinuous palaeochannels and oxbows, and only limited standing water; and Zone 3 (17.5–28 km), a sandy distal part with a single meandering channel (w/d  15–30), scroll bars and oxbows, and little standing water. Each zone also has a distinctive sedimentology: Zone 1 is characterised by an  3–4 m thick succession of basal sand and minor granules overlain by dominantly muddy sediment deposited primarily by oblique accretion in meander bends; Zone 2 is characterised by < 4 m of interbedded sand and mud deposited primarily by lateral point-bar accretion, although a history of avulsions also attests to the importance of abandoned-channel accretion; and Zone 3 is characterised by < 3 m of dominantly sand deposited primarily by lateral point-bar accretion. This unusual downstream sediment coarsening trend, and the associated changes in channel and floodplain character, are independent of sediment inputs from tributaries, and result from a downstream increase in bankfull unit stream power from < 3.5 W m^− 2 (Zone 1) to  4–10 W m^− 2 (Zone 3). Mud is deposited primarily in low-energy Zone 1 but is conveyed in suspension more effectively through higher energy Zones 2 and 3, only forming drapes over sandy lateral accretion deposits during waning flood stages. The downstream increase in unit stream power is controlled in part by a slight downstream increase in floodplain gradient that may be related to a subtle variation in the erosional resistance of the bedrock underlying the channel bed. These findings add to previous work on meandering rivers by demonstrating that mud-dominated meanders can occur in long-term erosional settings where the channel bed is grounded on bedrock, and that downstream fining trends may be reversed locally.     

Diets of mammalian herbivores in Australian arid, hilly shrublands: seasonal effects on overlap between euros (hill kangaroos), sheep and feral goats, and on dietary niche breadths and electivities

The diets of euros or hill kangaroos (Macropus robustus), domestic sheep (Ovis aries) and feral goats (Capra hircus) in hilly, shrub rangeland in southern Australia were examined in a 12-year study. Levels of dietary overlap between these herbivores, their foraging in relation to resource availability, and the potential for competition in different conditions were also examined. The diet of euros was based around grasses. In dry seasons some shrubs were also eaten but in severe drought grass formed more than 80% of their diet. While grass was important to sheep in wetter conditions, they ate much shrub in dry conditions. Feral goats had broad diets but their preference for browse was high. In drought, euros had only a modest dietary overlap with sheep and goats. Data for dietary niche breadths and electivities pointed to only limited competition between the herbivores.     

Petrogenesis of orthopyroxene- and amphibole-bearing andesites, Mustique, Grenadine Islands, Lesser Antilles Arc: Isotope, trace element and physical constraints

Abstract On the island of Mustique, fresh and propylitized olivine–plagioclase–clinopyroxene basalt, plagioclase–clinopyroxene–orthopyroxene and plagioclase–clinopyroxene–amphibole andesite lavas and minor intrusions are interbedded with Oligocene pyroclastic and epiclastic rocks. Chemical data show that two isotopically identical, but chemically different, suites of lava are present: (i) the OPXS (⁸⁷Sr/⁸⁶Sr 0.70403–0.70454; ¹⁴³Nd/¹⁴⁴Nd 0.512952–0.512986; δ¹⁸O_cpx 5.49 and 5.61), comprising basalts and orthopyroxene‐bearing andesites; and (ii) the AMPHS (⁸⁷Sr/⁸⁶Sr 0.70401–0.70457; ¹⁴³Nd/¹⁴⁴Nd 0.512981–0.513037; δ¹⁸O_cpx 5.54), made up of basalts and amphibole‐bearing andesites. The OPXS has higher contents of TiO₂, P₂O₅, light rare earth elements, Sm, Pb, Th, U, Zr, Y and Nb, and higher La/Yb ratios than the AMPHS. The isotopic data suggest that both suites formed from melts derived from the same subduction‐modified depleted mantle source as the volcanic rocks of nearby St Vincent and Bequia, and the northern islands of the Lesser Antilles Arc. The immobile trace element contents, and La/Yb ratios, of the OPXS are indicative of ～10% partial melting of the source, whereas those of the AMPHS are indicative of ～25% partial melting. The within‐suite chemical variation of the OPXS is consistent with ～45% fractional crystallization of its intratelluric mineral assemblages, and that of the AMPHS is consistent with the removal of ～65% of its intratelluric assemblages. Experimental evidence suggests that both suites of basalt crystallized at pressures <8 kbar from melts containing 1–2 wt% water. After extensive fractional crystallization, the andesites crystallized at pressures between approximately 5 and 2 kbar. The OPXS magmas appear to have lost more of their water content than the AMPHS magmas. Thus, the OPXS andesites formed from melts with an estimated water content of 2–3 wt%, whereas the AMPHS andesites formed from melts containing at least 4.5 wt% water.