Geochemical characteristics of mineral air particles emitted inside a clay atomisation plant which introduces waste recycling processes

The objective of this work is to assess the concentrations of three factions of air particles (settable particles, TSP and PM10) and the levels of several toxic elements in a clay atomisation industry through aerosol sampling at several points inside an industrial plant. Mechanical activities, which produce diffuse emissions, are the main process of discharge of particles in both indoor and outdoor workplace environments in the atomisation plant. The levels of As, Cd, Pb, Zn, Ba and Ni increase in the zones with higher concentrations of particles and lower ventilation. The concentrations of As and F are not influenced by the recycling processes. The levels of Cd and Pb do not show great enrichment in air particles collected inside the atomisation plant although the content of both elements is associated with ceramic muck recycling. Finally, the content of B in waste water is mainly transferred in gaseous phase to the atmosphere during the process of drying by atomisation.     

Eigenproperties of non-classically damped primary structure and equipment systems by a perturbation approach

Closed-form expressions are obtained to calculate the approximate complex eigenvalues and eigenvectors of a system composed of a non-classically damped primary structure and a single degree of freedom oscillator. The expressions are obtained through a systematic second order perturbation analysis of a transformed eigenvalue problem of the combined system. The possibility of tuning between the structure and equipment is considered. The dynamic properties of the combined system are derived in terms of the complex eigenvalues and eigenvectors of the supporting structure and the frequency, mass and damping ratio of the equipment. Examples demonstrating the accuracy of the expressions for the eigenvalues and eigenvectors are presented. These eigenproperties are used for generation of floor response spectra for non-classically damped structures to incorporate the dynamic interaction effects between the structure and equipment.     

An approach to the ecological characterization of arid and semiarid basins

A morphometric study of 61 sub-basins of the River Segura basin (SE Spain) enables us to attribute ecological processes in streams of these arid and semiarid watersheds to altered patterns of discharge resulting from human activity. Methods used are compared to other, commonly used limnological indexes.     

Selenium and other trace element in phosphorites: A comparison between those of the Bayovar-Sechura and other provenances

Data of trace element composition of phosphorites are scarce and incomplete. Phosphorites of different origins can vary substantially in trace element contents. In this paper 20 trace element concentrations of 35 sample phosphorites are reported. The geographical provenance is: Bayovar-Sechura (Peru), Khouribga, Youssoufia and Boucraa (Morocco), Gafsa (Tunisia), Florida (USA), Idaho and Phosphoria Formation (USA), North Carolina (USA), Algeria, Israel, Senegal, Syria and Togo. Aqua regia extracts were used to estimate the “pseudototal” values, following standard procedures (ISO 11466, 2002) and measured by ICP-AES and ICP-MS.     

Advance and prospectus of seasonal prediction: assessment of the APCC/CliPAS 14-model ensemble retrospective seasonal prediction (1980–2004)

We assessed current status of multi-model ensemble (MME) deterministic and probabilistic seasonal prediction based on 25-year (1980–2004) retrospective forecasts performed by 14 climate model systems (7 one-tier and 7 two-tier systems) that participate in the Climate Prediction and its Application to Society (CliPAS) project sponsored by the Asian-Pacific Economic Cooperation Climate Center (APCC). We also evaluated seven DEMETER models’ MME for the period of 1981–2001 for comparison. Based on the assessment, future direction for improvement of seasonal prediction is discussed. We found that two measures of probabilistic forecast skill, the Brier Skill Score (BSS) and Area under the Relative Operating Characteristic curve (AROC), display similar spatial patterns as those represented by temporal correlation coefficient (TCC) score of deterministic MME forecast. A TCC score of 0.6 corresponds approximately to a BSS of 0.1 and an AROC of 0.7 and beyond these critical threshold values, they are almost linearly correlated. The MME method is demonstrated to be a valuable approach for reducing errors and quantifying forecast uncertainty due to model formulation. The MME prediction skill is substantially better than the averaged skill of all individual models. For instance, the TCC score of CliPAS one-tier MME forecast of Niño 3.4 index at a 6-month lead initiated from 1 May is 0.77, which is significantly higher than the corresponding averaged skill of seven individual coupled models (0.63). The MME made by using 14 coupled models from both DEMETER and CliPAS shows an even higher TCC score of 0.87. Effectiveness of MME depends on the averaged skill of individual models and their mutual independency. For probabilistic forecast the CliPAS MME gains considerable skill from increased forecast reliability as the number of model being used increases; the forecast resolution also increases for 2 m temperature but slightly decreases for precipitation. Equatorial Sea Surface Temperature (SST) anomalies are primary sources of atmospheric climate variability worldwide. The MME 1-month lead hindcast can predict, with high fidelity, the spatial–temporal structures of the first two leading empirical orthogonal modes of the equatorial SST anomalies for both boreal summer (JJA) and winter (DJF), which account for about 80–90% of the total variance. The major bias is a westward shift of SST anomaly between the dateline and 120°E, which may potentially degrade global teleconnection associated with it. The TCC score for SST predictions over the equatorial eastern Indian Ocean reaches about 0.68 with a 6-month lead forecast. However, the TCC score for Indian Ocean Dipole (IOD) index drops below 0.40 at a 3-month lead for both the May and November initial conditions due to the prediction barriers across July, and January, respectively. The MME prediction skills are well correlated with the amplitude of Niño 3.4 SST variation. The forecasts for 2 m air temperature are better in El Niño years than in La Niña years. The precipitation and circulation are predicted better in ENSO-decaying JJA than in ENSO-developing JJA. There is virtually no skill in ENSO-neutral years. Continuing improvement of the one-tier climate model’s slow coupled dynamics in reproducing realistic amplitude, spatial patterns, and temporal evolution of ENSO cycle is a key for long-lead seasonal forecast. Forecast of monsoon precipitation remains a major challenge. The seasonal rainfall predictions over land and during local summer have little skill, especially over tropical Africa. The differences in forecast skills over land areas between the CliPAS and DEMETER MMEs indicate potentials for further improvement of prediction over land. There is an urgent need to assess impacts of land surface initialization on the skill of seasonal and monthly forecast using a multi-model framework.     

Characterisation and multifaceted anisotropy assessment of Corvio sandstone for geological CO2 storage studies

We present a comprehensive characterisation of the physical, mineralogical, geomechanical, geophysical, and hydrodynamic properties of Corvio sandstone. This information, together with a detailed assessment of anisotropy, is needed to establish Corvio sandstone as a useful laboratory rock‐testing standard for well‐constrained studies of thermo–hydro–mechanical–chemical coupled phenomena associated with CO₂ storage practices and for geological reservoir studies in general. More than 200 core plugs of Corvio sandstone (38.1 and 50 mm diameters, 2:1 length‐to‐diameter ratio) were used in this characterisation study, with a rock porosity of 21.7 ± 1.2%, dry density 2036 ± 32 kg m^?3, and unconfined compressive and tensile strengths of 41 ± 3.28 and 2.3 ± 0.14 MPa, respectively. Geomechanical tests show that the rock behaves elastically between ～10 and ～18 MPa under unconfined conditions with associated Young's modulus and Poisson's ratio of 11.8 ± 2.8 GPa and 0.34 ± 0.01 GPa, respectively. Permeability abruptly decreases with confining pressure up to ～10 MPa and then stabilises at ～1 mD. Ultrasonic P‐ and S‐wave velocities vary from about 2.8–3.8 km s^?1 and 1.5–2.4 km s^?1, respectively, over confining and differential pressures between 0.1 and 35 MPa, allowing derivation of associated dynamic elastic moduli. Anisotropy was investigated using oriented core plugs for electrical resistivity, elastic wave velocity and attenuation, permeability, and tracer injection tests. Corvio sandstone shows weak transverse isotropy (symmetry axis normal to bedding) of <10% for velocity and <20% for attenuation.     

土地利用/土地覆被变化遥感监测研究

根据1990年和1999年两期TM/ETM 遥感数据,运用遥感分类中的监督分类方法,全面分析乌鲁木齐市的土地利用的数量变化特征和空间变化特征,阐明了区域土地利用变化的区域特点。     

Late Triassic fluvial and marine shelf succession, Quebrada Doña Inés Chica, Atacama region, northern Chile

A 400-meter-thick volcanic and fine-grained clastic sedimentary succession in Quebrada Doña Ines Chica (26°07′S latitude; 69°20'W longitude) provides a record of Late Triassic deposition in the Atacama region of northern Chile. The strata are conformably overlain by fossiliferous marine limestones and sandstones of Late Triassic to Early Jurassic (Sinemurian) age which contain the oldest ichthyosaur remains known from Central and South America. The clastic succession is interpreted as coastal fluvial deposits, with the overlying limestones representing shelf deposits.