The origin of selected lunar geochemical anomalies: Implications for early volcanism and the formation of light plains

The Apollo orbital geochemistry, photogeologic, and other remote sensing data sets were used to identify and characterize geochemical anomalies on the eastern limb and farside of the Moon and to investigate the processes responsible for their formation. The anomalies are located in the following regions: (1) Balmer basin, (2) terrain northeast of Mare Smythii, (3) near Langemak crater, (4) Pasteur crater, (5) terrain northwest of Milne basin, (6) northeast of Mendeleev basin, (7) north and northeast of Korolev basin, (8) terrain north of Taruntius crater, and (9) terrain north of Orientale basin. The anomalies are commonly associated with Imbrian- or Nectarian-aged light plains units which exhibit dark-haloed impact craters. The results of recent spectral reflectance studies of dark-haloed impact craters plus consideration of the surface chemistry of the anomalies strongly indicate that those geochemical anomalies associated with light plains deposits which display dark-haloed impact craters result from the presence of basaltic units that are either covered by varying thickness of highland debris or have a surface contaminated with significant amounts of highlands material. The burial or contamination of ancient volcanic surfaces by varying amounts of highland material appears to have been an important (though not the dominant) process in the formation of lunar light plains. Basaltic volcanism on the eastern limb and farside of the Moon was more extensive in both space and time than has been accepted.     

Screening of polymers on selected Hawaii soils for erosion reduction and particle settling

In recent years, high‐molecular‐weight anionic polyacrylamides (PAMs) have been tested on a variety of soils, primarily in temperate climates. However, little information is available regarding the effectiveness of PAM for preventing soil loss through runoff in tropical settings. Screening tests were performed using three negatively charged PAMs and one positively charged PAM on five Hawaii soils (two Oxisols, one Vertisol, and two Aridisols) to determine erosion loss, sediment settling, and aggregate stability. A laboratory‐scale rainfall simulator was used to apply erosive rainfall at intensities from 5 to 8·5 cm h^?1 at various PAM doses applied in both dry and solution forms. Soil detachment due to splash and runoff, as well as the runoff and percolate water volumes, were measured for initial and successive storms. The impact of PAM on particle settling and aggregate stability was also evaluated for selected soil‐treatment combinations. Among the PAMs, Superfloc A‐836 was most effective, and significantly reduced runoff and splash sediment loss for the Wahiawa Oxisol and Pakini Andisol at rates varying between 10 and 50 kg ha^?1. Reduced runoff and splash sediment loss were also noted for PAM Aerotil‐D when applied in solution form to the Wahiawa Oxisol. Significant reductions in soil loss were not noted for either the Lualualei Vertisol or the Holomua Oxisol. It is believed that the high montmorillonite content of the Lualualei Vertisol and the low cation‐exchange capacity of the Holomua Oxisol diminished the effectiveness of the various PAMs tested. The polymers were also found to enhance sediment settling of all soils and helped improve their aggregate stability. This screening study shows the potential use of PAM for tropical soils for applications such as infiltration enhancement, runoff reduction, and enhanced sedimentation of detention ponds. Copyright © 2005 John Wiley & Sons, Ltd.     

Subaqueous pyroclastic flows and ignimbrites: an assessment

An assessment of the literature on subaqueous pyroclastic flows and their deposits shows that the term pyroclastic flow is frequently used loosely to describe primary, hot gas-rich pyroclastic flows, mass-flows which resulted from the transformation of gassupported flows into water-supported ones, and secondary mass-flows carrying redeposited pyroclastic debris. Based on subaerial pyroclastic flows, the term pyroclastic flow should be restricted to demonstrably hot, gas-rich mass-flows of pyroclastic debris. Using this definition, very few examples of subaqueous pyroclastic deposits with evidence for hot emplacement and of having been wholly submerged have been described. In the majority of these cases, the evidence for a hot state of emplacement and for the subaqueous nature of the host depositional environment is inadequate. The only unequivocal cases of hot pyroclastic flow deposits with adequate supporting evidence are the Ordovician nearshore, shallow marine ignimbrites of Ireland and Wales, and Miocene ignimbrites of southwest Japan, resulting from the passage of subaerially erupted pyroclastic flows into shallow water. Other possible examples are near-vent dense clast deposits in the Donzurobo Formation of Japan, possible submarine intra-caldera ponded ignimbrite successions in California and Wales, and near-vent pumiceous deposits of Ramsay Island, Wales. All other purported cases are either clearly the result of water-supported mass-flow transportation and deposition (debris avalanches, debris flows, turbidity currents), or lack adequate supporting evidence regarding the heat state or the palaeoenvironment. Only the shallow marine ignimbrites of Ireland and Wales show adequate evidence of welding, but even these could have been nearly wholly exposed above sea-level when welding occurred. We conclude that when pyroclastic flows enter water they are generally disrupted explosively and/or ingest water and transform into water-supported mass-flows, and we suggest the various scenarios in which this occurs. There is no evidence to suggest that welding in wholly subaqueous environments is common.     

Age estimates of coastal terraces in the Andaman and Nicobar Islands and their tectonic implications

The great Indian Ocean earthquake of December 26, 2004 caused significant vertical changes in its rupture zone. About 800 km of the rupture is along the Andaman and Nicobar Islands, which forms the outer arc ridge of the subduction zone. Coseismic deformation along the exposed land could be observed as uplift/subsidence. Here we analyze the morphological features along the coast of the Andaman and Nicobar Islands, in an effort to reconstruct the past tectonics, taking cues from the coseismic effects. We obtained radiocarbon dates from coastal terraces of the island belt and used them to compute uplift rates, which vary from 1.33 mm yr^− 1 in the Little Andaman to 2.80 mm yr^− 1 in South Andaman and 2.45 mm yr^− 1 in the North Andaman. Our radiocarbon dates converge on  600 yr and  1000 yr old coastal uplifts, which we attribute to the level changes due to two major previous subduction earthquakes in the region.     

The sea-surface microlayer of puget sound: Part I. Toxic effects on fish eggs and larvae

The sea surface is an important habitat for the developmental stages (eggs and larvae) of many fish and invertebrates; it is also a concentration point for anthropogenic contaminants entering the sea. Studies were conducted to determine the extent to which the sea surface of Puget Sound was toxic to the early life history stages of fish. Three urban bays with suspected contamination, a rural reference bay, and a Central Sound site were compared. Surface-dwelling eggs and organisms (zooneuston) were collected with a surface-skimming neuston net and their densities enumerated. Sand sole (Psettichthys melanostictus) embryos were exposed in the field and laboratory to the sea-surface microlayer. To develop a useful year-round approach to monitoring sea-surface toxicity, larval development of anchovies, kelp bass, and sea urchins was also evaluated as an indication of sea-surface microlayer toxicity.During the spawning season (February and March), urban boys in Puget Sound had lower concentrations of sand sole eggs and neustonic organisms on the sea surface than did the rural bayor Central Sound reference sites. Compared to the reference sites, laboratory exposure to surface microlayer samples collected from urban bay sites generally resulted in more chromsomal aberrations in developing sole embryos, reduced hatching success of sole larvae, and reduced growth in trout cell cultures. In situ hatching success of sole eggs was reduced by half or more in urban bays compared to reference sites.Toxicity was associated with visible surface slicks and, in urban bays, increased with increasing surface pressure (dynes cm⁻¹). Results to be reported separately (Part II) indicate that toxicity is strongly correlated with the presence of high concentrations of polycyclic aromatic hydrocarbons and metals in the sea-surface microlayer. The toxicity of SMIC samples was similar when evaluated by sole, anchovy, kelp bass, or sea urchin tests. A sea-surface monitoring program could use sea urchin embryos to evaluate site-specific sea-surface toxicity throughout the year.     

Mineral assemblages occurring around hydrocarbon vents in the northern Gulf of Mexico

Magnesian calcites are the most abundant authigenic minerals associated with hydrocarbon vents at 25 sites, in water depths ranging from 100 to 600 m in the Green Canyon area and about 2200 m in the Alaminos Canyon area on the Continental Slope of the northern Gulf of Mexico. The most frequently encountered magnesian calcites have 10–15 mol% MgCO₃ and the apparent structural disorder revealed by XRD peak widths increases with Mg substitution. There are no systematic variations in Mg content with respect to water depth or geographic location. The calcite saturation state of the precipitating fluid is primarily determined by the nature of the fluids escaping from the vents, not the ambient seawater.     

The distribution of tritium and CFCs in the Weddell Sea during the mid-1980s

Transient tracer data (tritium, CFC11 and CFC12) from the southern, central and northwestern Weddell Sea collected during Polarstern cruises ANT III-3, ANT V-2/3/4 and during Andenes cruise NARE 85 are presented and discussed in the context of hydrographic observations. A kinematic, time-dependent, multi-box model is used to estimate mean residence times and formation rates of several water masses observed in the Weddell Sea.Ice Shelf Water is marked by higher tritium and lower CFC concentrations compared to surface waters. The tracer signature of Ice Shelf Water can only be explained by assuming that its source water mass, Western Shelf Water, has characteristics different from those of surface waters. Using the transient nature of tritium and the CFCs, the mean residence time of Western Shelf Water on the shelf is estimated to be approximately 5 years. Ice Shelf Water is renewed on a time scale of about 14 years from Western Shelf Water by interaction of this water mass with glacial ice underneath the Filchner-Ronne Ice shelf. The Ice Shelf Water signature can be traced across the sill of the Filchner Depression and down the continental slope of the southern Weddell Sea. On the continental slope, new Weddell Sea Bottom Water is formed by entrainment of Weddell Deep Water and Weddell Sea Deep Water into the Ice Shelf Water plume. In the northwestern Weddell Sea, new Weddell Sea Bottom Water is observed in two narrow, deep boundary currents flowing along the base of the continental slope. Classically defined Weddell Sea Bottom Water (θ ≤ −0.7°C) and Weddell Sea Deep Water (−0.7°C ≤ θ ≤ 0°C) are ventilated from the deeper of these boundary currents by lateral spreading and mixing. Model-based estimates yield a total formation rate of 3.5Sv for new Weddell Sea Bottom Water (θ = −1.0°C) and a formation rate of at least 11Sv for Antarctic Bottom Water (θ = −0.5°C).     

Contaminant concentrations and toxicity of sea-surface microlayer near Los Angeles, California

Sea-surface microlayer samples were collected from six nearshore areas receiving different amounts of anthropogenic inputs. The samples were analyzed for selected trace metals, chlorinated hydrocarbons, and polycyclic aromatic hydrocarbons. The relative toxicities of the samples were determined with fish embryo bioassays.Contaminant concentrations generally increased from offshore to the inshore stations. Contaminant concentrations were several orders of magnitude higher in microlayer samples from the highly industrialized Los Angeles and Long Beach harbors compared to samples from a site 15km offshore. Microlayer samples from the inshore stations were significantly more toxic, and induced significantly more developmental abnormalities and chromosome aberrations, than samples from the offshore stations.     

Aquatic surface microlayer contamination in chesapeake bay

The aquatic surface microlayer (SMIC), 50 μm thick, serves as a concentration point for metal and organic contaminants that have low water solubility or are associated with floatable particles. Also, the eggs and larvae of many fish and shellfish species float on, or come in contact with, the water surface throughout their early development. The objectives of this study were (1) to determine the present degree of aquatic surface microlayer pollution at selected sites in Chesapeake Bay, and (2) to provide a preliminary evaluation of sources contributing to any observed contamination.Twelve stations located in urban bays, major rivers, and the north central bay were sampled three times, each at 5-day intervals during May 1986. Samples of 1.4–4.1 each were collected from the upper 30–60-μm water surface (surface microlayer, SMIC) using a Teflon-coated rotating drum microlayer sampler. One sample of subsurface water was collected in the central bay.At all stations, concentrations of metals, alkanes, and aromatic hydrocarbons in the SMIC were high compared with one bulk-water sample and with typical concentrations in water of Chesapeake Bay and elsewhere. SMIC contamination varied greatly among the three sampling times, but high mean contaminant levels (total polycyclic aromatic hydrocarbons, 1.9–6.2 μg 1⁻¹; Pb, 4.9–24 μg 1⁻¹; Cu, 4–16 μg 1⁻¹; and Zn, 34–59 μg 1⁻¹) were found at the upper Potomac and northern bay sites. Three separate areas were identified on the basis of relative concentrations of different aromatic hydrocarbons in SMIC samples - the northern bay, the Potomac River, and the cleaner southern and eastern portions of the sampling area.Suspected sources of surface contamination include gasoline and diesel fuel combustion, coal combustion, and petroleum product releases. Concentrations of metals and hydrocarbons, at approximately half the stations sampled, are sufficient to pose a threat to the reproductive stages of some fish and shellfish. Sampling and analysis of the surface microlayer provides a sensitive tool for source identification and monitoring of potentially harmful aquatic pollution.