Trace metals in suspended particulate matter and in sediment trap material from a permanently anoxic fjord — Framvaren, South Norway

Geochemical studies of the trace metal concentrations in suspended particulate matter (SPM) and sediment trap material from a permanently anoxic fjord, Framvaren, South Norway in 1989 and 1993 indicate that extremely high concentrations of zinc (max = 183920 mg/kg), copper (max = 4130 mg/kg), lead (max = 2752 mg/kg), and cadmium (max= 8.1 mg/kg) sometimes (1993) occur in the SPM collected in the anoxic water layer. The highest concentrations of Zn occur just below the redoxcline at 22 m water depth (in 1993), and copper, lead and cadmium have maximum concentrations between 30 and 80 m depth, where the amount of total SPM is at a minimum (about 0.3 mg/L). On a mass per volume (g/L) basis, the maximum concentrations of Cd, Cu and Fe occur at the interface (21m) and those of Zn occur just below the redoxcline (22 m depth). The SPM and sediment trap data suggest that the metals are precipitated as sulfide minerals in the anoxic water. The presence of particulate sulfides was confirmed by SEM studies that show the occurrence of discrete metal (Cu, Fe, Pb, and Zn) sulfide particles in size from 10–20 m as well as framboidal pyrites (1–5 m in size). Higher levels of metal sulfides at intermediate depths rather than in the deep water of Framvaren (> 100 m), may be due to input of trace metals by water exchange over the sill in the upper part of the water column. In the deep water, less metal sulfide precipitation takes place due to depletion of trace metals, and the dilution of particulate metal concentrations by organic matter and by the chemogenic formation of calcite.     

Ultraviolet radiation exposure of a high arctic lake in Svalbard during the Holocene

Long‐term fluctuations in lake‐water optical properties were examined using a Holocene sediment sequence and multi‐proxy palaeolimnological approach in Lake Einstaken, Nordaustlandet, Svalbard. UV‐absorbance of sedimentary cladoceran remains provided information on underwater UV exposure and changes in lake‐catchment coupling processes were inferred from sediment geochemistry. In addition, aquatic community succession was used as an indicator for lake‐water bio‐optical properties and a Holocene record of sun activity (sunspots) was utilized to evaluate long‐term solar forcing. The results indicated that the UV‐absorbance of cladoceran remains was highest (i.e. maximum UV‐induced pigmentation) for a short period during the early Holocene and for several millennia during the mid‐Holocene. Sun activity was high during these time intervals, probably impacting the UV intensities, but it is probable that the amount of UV‐attenuating compounds (e.g. dissolved organic carbon (DOC)) also significantly affected the underwater UV environment and were low during high UV exposure. Benthic autotrophic communities also responded to the millennial changes in lake‐water optical properties. UV‐resistant Nostoc cyanobacterial colonies were established during the mid‐Holocene, indicative of high underwater UV intensities, and Fontinalis mosses thrived during the early Holocene, indicating a highly transparent water column. The results further suggested that underwater UV exposure decreased during the late Holocene, which is probably attributable to increased DOC and decreased solar forcing. Owing to the location of Lake Einstaken and its catchment in the periglacial barren landscape of the polar desert, the fluctuations of bio‐optical lake‐water properties were apparently forced by postglacial environmental processes and Holocene climate development. These factors controlled sea shoreline proximity, water discharge, ice‐cover duration and littoral‐benthic primary production and further affected the underwater UV environment. Although the role of solar forcing cannot be underestimated, the current record emphasizes the role of climate‐mediated lake‐catchment interactions in impacting bio‐optical properties and UV exposure of high arctic aquatic systems.     

Controls of the chemical composition of particle populations in a macrotidal estuary (Tamar Estuary, U.K.)

The chemical composition of suspended particulate material (SPM) in the Tamar Estuary and its response to tidal sediment resuspension at the turbidity maximum have been investigated. The results discriminate four regions: (1) the outer estuary where spatial changes in the composition of SPM reflect the dispersal of estuarine particles modified by in situ generation of organic particles, (2) the middle estuary where the composition of SPM is mainly determined by hydrodynamic mixing although there is some evidence of in situ chemical reactivity, (3) the upper estuary where sharply distinct and temporally variable SPM compositions are centred at the turbidity maximum; these are largely the result of particle-selective accumulation, sedimentation and resuspension processes rather than of local particle-water chemical exchanges, and (4) the fluvial estuary where the SPM composition reflects the influx of riverine particles.     

Photospheric and chromospheric activity on EY Dra

Magnetic activity in the photosphere and chromosphere of the M dwarf EY Dra is studied and possible correlations between the two are investigated using photometric observations in the V and R bands and optical and near infrared spectroscopy. The longitudinal spot configuration in the photosphere is obtained from the V band photometry, and the chromospheric structures are investigated using variations in the Hα line profile and observations of the Paschen β line. The shape of the V band light‐curve indicates two active regions on the stellar surface, about 0.4 in phase apart. The spectroscopic observations show enhanced Hα emission observed close to the phases of the photometrically detected starspots. This could indicate chromospheric plages associated with the photospheric starspots. Some indications of prominence structures are also seen. The chromospheric pressure is limited to log m_TR < –4 based on the non‐detection of emission in the Paschen β wavelength region. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Sedimentary cladoceran assemblages and their functional attributes record late Holocene climate variability in southern Finland

We examined long-term relationships between Cladocera and limnogeological and climate variables in a late Holocene lake sediment sequence to assess cladoceran responses to climate change and reconstruct past climate variations in southern Finland, near the Baltic Sea coast. Elemental composition, organic matter, and inferred water quality variables were used to constrain paleoenvironmental (until 4500 cal BP) conditions and human impact. Fossil Cladocera assemblages, ephippia, and body size trends were utilized to estimate mean July air temperature (T _Jul) variability, open-water season length, and water-temperature regimes. Results revealed stable cladoceran communities, dominated by Eubosmina, until 500 cal BP, followed by major assemblage changes including increases in Chydorus cf. sphaericus, Alonella spp., and Bosmina longirostris. Pb and Cu concentrations were associated temporally with increasing human impact and warming climate during the past few centuries, and were the most significant factors in explaining cladoceran community changes, based on redundancy analysis. A Cladocera-based T _Jul reconstruction estimated elevated temperatures for the end of the Holocene Thermal Maximum, a cooler period during ~3000–2000 cal BP, slightly increased temperatures during 1200–800 cal BP corresponding to the Medieval Climate Anomaly (MCA), and lower temperatures during the Little Ice Age (LIA), 800–200 cal BP. The reconstruction also suggests that significant climate warming took place during the twentieth century. Cladocerans mostly associated with warm periods included B. longirostris and Pleuroxus uncinatus, whereas Alona affinis, A. quadrangularis, and C. cf. sphaericus were associated with colder climate. Compared to a reference Chironomidae-inferred T _Jul reconstruction from the same region, discrepancies were apparent in amplitude of temperature change, as the temperature variability in the cladoceran-based record was muted until ~200 cal BP. During the LIA, increased ephippia and body size agreed with the temperature reconstruction, but suggested a severely shorter open-water season and reduced water temperatures compared to the preceding late Holocene episodes, even though the cladoceran T _Jul showed quite similar temperatures for these periods. Our results suggest that fossil cladoceran assemblages, ephippia, and morphological attributes respond sensitively to long-term climate fluctuations and this record reflects well the major climate events of the late Holocene and provides realistic paleoclimatic estimates for maritime southern Finland.     

How to Earn the Status of Honest Broker? Scientists’ Roles Facilitating the Political Water Supply Decision-Making Process

“Honest broker” refers to scientists facilitating complex political decisions from a neutral position, aiming to expand the scope of choice available instead of advocating a certain policy. This article reflects on the experiences of three scientists acting as honest brokers while carrying out a multicriteria evaluation to help politicians choose the water supply option for the city of Oulu, Finland. The process was considered successful and many politicians said that they have never before been that well informed when making a decision. The case primarily shows that besides the common knowledge brokerage roles targeting knowledge exchange, the honest brokerage approach relates more to managing social relationships and balancing political games and rapidly evolving discussions. Trustful relationships increased the perceived credibility of the brokers and ensured two-way communication. On the other hand, the brokers faced ethical dilemmas and difficulties of staying impartial while finding out confidential information related to political strategies.     

Early presence of Bythotrephes cederströmii (Cladocera: Cercopagidae) in lake sediments in North America: evidence or artifact?

Journal of Paleolimnology - The spiny water flea (Bythotrephes cederströmii), a freshwater crustacean considered to be the world’s best-studied invasive zooplankter, was first recorded...     

A fuzzy multiple-attribute decision-making modelling for vulnerability analysis on the basis of population information for disaster management

Research activity and published literature on the reliability and vulnerability analysis of urban areas for disaster management has grown tremendously in the recent past. Population information has played the most important role during the entire disaster management process. In this article, population information was used as the evaluation criterion, and a fuzzy multiple-attribute decision-making (MADM) approach was used to support a vulnerability analysis of the Helsinki area for disaster management. A kernel density map was produced as a result that showed the vulnerable spatial locations in the event of a disaster. Model results were first validated against the original population information kernel density maps. In the second step, the model was validated by using fuzzy set accuracy assessment and the actual domain knowledge of the rescue experts. This is a novel approach to validation, which makes it possible to see how and if computer decision-making models compare to a real decision-making process in disaster management. The validation results showed that the fuzzy model has produced a reasonably accurate result. By using fuzzy modelling, the number of vulnerable areas was reduced to a reasonable scale and compares to the actual human assessment of these areas, which allows resources to be optimised during the rescue planning and operation.