Total content and chemical speciation of arsenic in the polychaete Sabella spallanzanii

An unusual feature has been observed in polychaetes regarding their capacity to accumulate high levels of relatively toxic forms of arsenic in specific tissues. Basal levels of arsenic and distribution of its compounds were investigated in tissues of the Mediterranean polychaete Sabella spallanzanii. Particularly high concentrations were measured in the branchial crown (1036+/-136 microg/g d.w.) and chemical speciation revealed that the predominant form was the relatively toxic dimethylarsinate (DMA). These data suggest a potential role of As as anti-predatory strategy in polychaetes.     

Seismic risk assessments and GIS technology: applications to infrastructures in the Friuli–Venezia Giulia region (NE Italy)

This paper illustrates the seismic risk preliminary estimates of two different groups of structures located on the territory of the Friuli–Venezia Giulia region (NE Italy) : the first group includes some special industrial plants, and the second group includes bridges and tunnels belonging to the regional highway network. The part of the study on special industrial plants tries to evaluate the degree of expected damage, taking into account their structural typology and ground shaking expressed in terms of macroseismic intensity. The second part of the study is an application of the HAZUS methodology to the tunnels and bridges of a highway network: the combination of expected ground shaking and the construction characteristics lead to very different risk levels, especially when considering the bridges. The resulting damage levels to bridges and tunnels are still only indicative because of the fragility curves used in the evaluations: they were developed for existing bridge and tunnel structural typologies in the U.S.A. Moreover, both examples show the power of GIS technology in storing, elaborating, and mapping spatial data. Copyright © 2003 John Wiley & Sons, Ltd.     

On the Final Gravitational Wave Burst from Binary Black Holes Mergers

We use perturbation theory in the strong-field regime to study the inspiral-to-plunge transition of a test particle into a Kerr black hole. We found a smooth transition, without burst, and with lower energy and angular momentum radiated in gravitational waves with respect to previous treatments in the literature. Besides their theoretical interest, our results are relevant for the waveform templates of binary black hole mergers used for gravitational waves detection which are constructed on the basis of a inspiral-to-plunge transition with a high energetic burst.     

Discovery of the Moment of Formation of the Black Hole in GRB 190114C

Astronomy Reports - Almost 50 years after “Introducing the Black Hole” [1], we are witnessing the clear evidence on the discovery of the moment of formation of the Black Hole in GRB...     

Low reproductive success for copepods during a bloom of the non‐aldehyde‐producing diatom Cerataulina pelagica in the North Adriatic Sea

Egg production rates and/or hatching success in the copepods Acartia clausi, Calanus helgolandicus and Temora longicornis were negatively affected by a late spring (May–June 2003) phytoplankton bloom in the North Adriatic Sea, dominated mainly by the large diatom Cerataulina pelagica. Highest total concentrations of 3.3·10⁴ cells·ml^?1 were located in the vicinity of the Po River, which also corresponded to the area where the highest numbers of phaeophorbides were measured (0.779, 0.528 and 0.419 μg·l^?1, respectively, compared to an average of the remaining stations of 0.183 ± 0.049 SD), suggesting some grazing on the bloom. Phytoplankton biomass in terms of carbon was dominated by diatoms, representing on average 42% of total phytoplankton carbon and more than 80% at several stations. Cerataulina pelagica, Cyclotella spp., Chaetoceros spp. and small unidentified centric diatoms dominated the diatom community numerically but C. pelagica was by far the dominant diatom in terms of carbon due to its large cell size. This species represented more than 60% of the diatom biomass at nine of the 14 stations sampled, and was absent only at one station, which was the most offshore station sampled during the cruise. Although polyunsaturated aldehydes (PUAs) were not detected, other oxylipins which are hydroxy and keto derivatives of eicosapentaenoic and docosahexaenoic acids that affect copepod reproduction were found in these samples. Hence, we can attribute the negative impact of diatoms not only to PUAs, as previously believed, but also to these compounds. This is the first direct evidence of the presence of oxylipins other than PUAs in marine blooms dominated by diatoms.     

The 1631 Vesuvius eruption. A reconstruction based on historical and stratigraphical data

The eruption of 1631 A.D. was the most violent and destructive event in the recent history of Vesuvius. More than fifty primary documents, written in either Italian or Latin, were critically examined, with preference given to the authors who eyewitnessed volcanic phenomena. The eruption started at 7 a.m. on December 16 with the formation of an eruptive column and was followed by block and lapilli fallout east and northeast of the volcano until 6 p.m. of the same day. At 10 a.m. on December 17, several nuées ardentes were observed to issue from the central crater, rapidly descending the flanks of the cone and devastating the villages at the foot of Vesuvius. In the night between the 16th and 17th and on the afternoon of the 17th, extensive lahars and floods, resulting from rainstorms, struck the radial valleys of the volcano as well as the plain north and northeast.Deposits of the eruption were identified in about 70 localities on top of an ubiquitous paleosol formed during a long preeruptive volcanic quiescence. The main tephra unit consists of a plinian fallout composed of moderately vesicular dark green lapilli, crystals and lithics. Isopachs of the fallout are elongated eastwards and permit a conservative volume calculation of 0.07 km³. The peak mass flux deduced from clast dispersal models is estimated in the range 3–6 × 10⁷ kg/s, corresponding to a column height of 17–21 km. East of the volcano the plinian fallout is overlain by ash-rich low-grade ignimbrite, surges, phreatomagmatic ashes and mud flows. Ash flows occur in paleovalleys around the cone of Vesuvius but are lacking on the Somma side, suggesting that pyroclastic flows had not enough energy to overpass the caldera wall of Mt. Somma. Deposits are generally unconsolidated, massive with virtually no ground layer and occasionally bearing sparse rests of charred vegetation. Past interpretations of the products emitted on the morning of December 17 as lava flows are inconsistent with both field observations and historical data. Features of the final phreatomagmatic ashes are suggestive of alternating episodes of wet ash fallout and rainfalls. Lahars interfingered with primary ash fallout confirm episodes of massive remobilization of loose tephra by heavy rainfalls during the final stage of the eruption.Chemical analyses of scoria clasts suggest tapping of magma from a compositionally zoned reservoir. Leucite-bearing, tephritic-phonolite (SiO₂ 51.17%) erupted in the early plinian phase was in fact followed by darker and slightly more mafic magma richer in crystals (SiO₂ 49.36%). During the nuées ardentes phase the composition returned to that of the early phase of the eruption.The reconstruction of the 1631 eruptive scenario supplies new perspectives on the hazards related to plinian eruptions of Vesuvius.     

Natural background levels and threshold values derivation for naturally As, V and F rich groundwater bodies: a methodological case study in Central Italy

Natural background levels (NBL) and threshold values (TV) derivation is an important task for EU Member States to correctly assess the chemical status of groundwater bodies within the context of the recently adopted Groundwater Directive. Attempts are being made both by water authorities and scientific community to test application viability of proposed methods to different real situations and to develop tailored adjustments and refinements. The aim of this paper is to describe a methodological case study of NBL and TV determination in a large area (5,500 km²) located in Central Italy where both natural and anthropogenic contamination occurs, resulting in several substances be detected in ground waters with concentration frequently exceeding drinking water standards. This paper shows the key role played in the determination process by knowledge on the hydrogeological setting and hydrogeochemical features. The adoption of appropriate pre-selection criteria of samples, the establishment of TV at the groundwater body scale for natural origin substances, and the evaluation of TVs exceedances in a multiparameter context are experimentally discussed. Beyond the critical evaluation of NBL and TV determination method, this research aims at increasing consciousness in the water management agencies that groundwater status assessment should be conceived as a scientific evaluation procedure and not as a mere technical/administrative exercise to be performed using any set of available data. As such, it should be supported by adequate knowledge of hydrogeological setting, hydrochemical processes occurring in groundwater bodies, and human activities acting overland to be progressively verified.     

Preface: Workshop on matter,astrophysics, gravitation,ions and cosmology—MAGIC23

We outline our experience in organizing the first edition of the Workshop on Matter, Astrophysics, Gravitation, Ions and Cosmology, held in virtual and in-person format, denominated MAGIC23, held from 6 to 10 March, 2023, in Praia do Rosa, Santa Catarina, Brazil. The event aimed to bring together leading academic scientists, professors, students, and research scholars for exchanging experiences and discuss the most recent innovations, trends, practical challenges, and experimental and theoretical solutions adopted in the investigation fields within the scope of the meeting. The workshop offered to the participants a platform for scientific and academic projects, partnerships, and presentation of high-quality research contributions describing original and unpublished results on topics related to matter, astrophysics, gravitation, ions, and cosmology.