Low‐energy helium ion irradiation‐induced amorphization and chemical changes in olivine: Insights for silicate dust evolution in the interstellar medium

Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)₂SiO₄, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.     

Discriminating between pore‐filling load and bed‐structure load: a new porosity‐based method,exemplified for the river Rhine

Sediments contained in the river bed do not necessarily contribute to morphological change. The finest part of the sediment mixture often fills the pores between the larger grains and can be removed without causing a drop in bed level. The discrimination between pore‐filling load and bed‐structure load, therefore, is of practical importance for morphological predictions. In this study, a new method is proposed to estimate the cut‐off grain size that forms the boundary between pore‐filling load and bed‐structure load. The method evaluates the pore structure of the river bed geometrically. Only detailed grain‐size distributions of the river bed are required as input to the method. A preliminary validation shows that the calculated porosity and cut‐off size values agree well with experimental data. Application of the new cut‐off size method to the river Rhine demonstrates that the estimated cut‐off size decreases in a downstream direction from about 2 to 0·05 mm, covariant with the downstream fining of bed sediments. Grain size fractions that are pore‐filling load in the upstream part of the river thus gradually become bed‐structure load in the downstream part. The estimated (mass) percentage of pore‐filling load in the river bed ranges from 0% in areas with a unimodal river bed, to about 22% in reaches with a bimodal sand‐gravel bed. The estimated bed porosity varies between 0·15 and 0·35, which is considerably less than the often‐used standard value of 0·40. The predicted cut‐off size between pore‐filling load and bed‐structure load (D_c,p) is fundamentally different from the cut‐off size between wash‐load and bed‐material load (D_c,w), irrespective of the method used to determine D_c,p or D_c,w. D_c,w values are in the order of 10^?1 mm and mainly dependent on the flow characteristics, whereas D_c,p values are generally much larger (about 10⁰ mm in gravel‐bed rivers) and dependent on the bed composition. Knowledge of D_c,w is important for the prediction of the total sediment transport in a river (including suspended fines that do not interact with the bed), whereas knowledge of D_c,p helps to improve morphological predictions, especially if spatial variations in D_c,p are taken into account. An alternative to using a spatially variable value of D_c,p in morphological models is to use a spatially variable bed porosity, which can also be predicted with the new method. In addition to the morphological benefits, the new method also has sedimentological applications. The possibility to determine quickly whether a sediment mixture is clast‐supported or matrix‐supported may help to better understand downstream fining trends, sediment entrainment thresholds and variations in hydraulic conductivity.     

Petrography and textural development of inorganic and biogenic lithotypes in a relict barite tufa deposit at Flybye Springs, NT, Canada

A relict mound of Holocene barite (BaSO₄) tufa underlies the Flybye Springs, a small, barium‐rich, cold sulphur spring system in the Northwest Territories of Canada. The tufa is composed of relatively pure barite with ≤0·34 wt% Ca²⁺ and ≤0·77 wt% Sr²⁺. The mound is made up of coated bubble, raft, undulatory sheet, stromatolitic, coated grain and detrital conglomerate barite tufa. Although previously unreported in barite, these lithotypes are akin to facies found in many carbonate spring deposits. Raft and ooid‐coated grain tufa was formed via ‘inorganic’ barite precipitation in spring water ponds and tributaries where rapid oxidation of sulphide to sulphate established barite supersaturation. Undulatory sheet tufa may have formed by the reaction of dissolved barium with sulphate derived from the oxidation of extracellular polysaccharide‐rich colloidal sulphur films floating in oxygenated, barite‐saturated spring water ponds. Coated bubble, oncoid‐coated grain and stromatolitic tufa with filamentous microfossils was formed in close association with sulphur‐tolerant microbes inhabiting dysoxic and oxygenated spring water tributaries and ponds. Adsorption of dissolved barium to microbial extracellular polysaccharide probably facilitated the development of these ‘biogenic’ lithotypes. Detrital conglomerate tufa was formed by barite cementation of microdetrital tufa, allochthonous lithoclasts and organic detritus, including caribou hair. Biogenic textures, organic artefacts and microfossils in the Flybye barite tufa have survived diagenetic aggradational recrystallization and precipitation of secondary cements, indicating the potential for palaeoecological information to be preserved in barite in the geological record. Similarities between the Flybye barite tufa and carbonate spring deposits demonstrate that analogous textures can develop in chemical sedimentary systems with distinct mineralogy, biology and physiochemistry.     

Sequence stratigraphy of a Late Devonian ramp-situated reef system in the Western Canada Sedimentary Basin: dynamic responses to sea-level change and regressive reef development

The Alexandra Formation, located in the Northwest Territories of Canada, is formed of a Late Devonian (Frasnian) reef system that developed on a gently sloping, epicontinental ramp in the Western Canada Sedimentary Basin. High‐resolution sequence stratigraphic analysis of its deposits delineates two reef complexes that are separated by a Type I sequence boundary. The second reef complex developed on the outer ramp, basinward of the first, after sea‐level fell ≈17 m. Stratigraphic complexity of the second reef complex was a result of its initiation during forced regression, and its development through an entire cycle of sea‐level rise followed by sea‐level fall. Its highstand systems tract was not characterized by high rates of carbonate production or sediment shedding. Rather, these features took place as sea‐level fell, after its highstand systems tract. The sequence stratigraphic framework of this regressive reef system highlights a number of depositional parameters that differ from high‐relief, shelf‐situated reef systems with steep, narrow margins. These have implications for understanding the controls on the development of ramp‐situated reef systems, and the nature of reef systems with gently sloping profiles. This study demonstrates that the development of stromatoporoid reef systems may be far more complex than generally realized, and that high‐resolution sequence stratigraphy may provide the tools for better understanding of complex, often enigmatic, aspects of these systems.     

Transition and Diversity in Rural Housing Provision: The case of Narrogin,Western Australia

The purpose of this paper is to examine the changing dynamics of housing markets in an Australian rural community. With reference to the case of Narrogin, Western Australia, it argues that there is an increasing disjuncture between the social and demographic characteristics of rural residents and the modal form of housing in country towns, namely the detached family house. Factors contributing to this disjuncture include the ageing of the population, the loss of traditional blue-collar employment, sub-regional restructuring of service provision, retirement migration patterns, and growing acceptance of the particular housing needs of groups such as the aged, the disabled, young and indigenous people. While it is clear that there is currently something of a mismatch between the characteristics of the population and the housing stock in Narrogin, it is also evident that a combination of political, cultural and economic factors form a significant barrier to adjustment in the local housing market.     

Growth patterns and implications of complex dendrites in calcite travertines from Lýsuhóll, Snæfellsnes, Iceland

Calcite dendrite crystals are important but poorly understood components of calcite travertine that forms around many hot springs. The Lýsuhóll hot-spring deposits, located in western Iceland, are formed primarily of siliceous sinters that were precipitated around numerous springs that are now inactive. Calcite travertine formed around the vent and on the discharge apron of one of the springs at the northern edge of the area. The travertine is formed largely of two types (I and II) of complex calcite dendrite crystals, up to 1 cm high, that grew through the gradual addition of trilete sub-crystals. The morphology of the dendrite crystals was controlled by flow direction and the competition for growth space with neighbouring crystals. Densely crowded dendrites with limited branching characterize the rimstone dams whereas widely spaced dendrites with open branching are found in the pools. Many dendrite bushes in the pools nucleated around plant stems. Growth of the dendrite crystals was seasonal and incremental. Calcite precipitation was driven by rapid CO₂ degassing of CO₂-rich spring waters during the spring and summer. During winter, when snow covered the ground and temperatures were low, opal-A precipitated on the exposed surfaces of the dendrites. Segmentation of dendrite branches by discontinuities coated with opal-A and overgrowth development around sub-crystals resulted from this seasonal growth cycle. The calcite dendrite crystals in the Lýsuhóll travertine differ in morphology from those at other hot springs, such as those at Lake Bogoria, Kenya, and Waikite in New Zealand. Comparison with the calcite dendrite crystals found at those sites shows that dendrite morphology is site-specific and probably controlled by carbonate saturation levels that, in turn, are controlled by the rate of CO₂ degassing and location in the spring outflow system.     

An analysis of regional climate model performance over the tropical Americas. Part I: simulating seasonal variability of precipitation associated with ENSO forcing

Sea surface temperature (SST) anomalies associated with El Niño/Southern Oscillation (ENSO) constitute a major source of predictability in the tropics. We evaluate the ability of a regional climate model (the Rossby Centre Atmospheric Model; RCA) to downscale SST and large-scale atmospheric anomalies associated with ENSO. RCA is configured over the tropical east Pacific and tropical Americas and runs for the period 1979–2005, using European Centre for Medium-Range Weather Forecasts (ECMWF) lateral and surface boundary conditions. We study the ability of RCA to represent regional patterns of precipitation, with respect to both the climatology and interannual variability associated with ENSO. The latter is achieved by grouping the simulations into El Niño and La Niña composites and studying the delayed response of precipitation to SST forcing in four regions of Central and South America.
In this paper, we concentrate on seasonal mean timescales. We find that RCA accurately simulates the main features of the precipitation climatology over the four regions and also reproduces the majority of the documented regional responses to ENSO forcing. Furthermore, the model captures the variability in precipitation anomalies between different ENSO events. The model exhibits a wet bias over the northern Amazon and slightly overestimates the magnitude of ENSO anomalies over Central America.     

1988 Compilation of Elemental Concentration Data for USGS Basalt BCR-1

Concentration data on up to 82 individual constituents in USGS Basalt BCR-1 have been collected from 1395 journal articles and technical reports. These data are summarized in consensus (mean) values with uncertainties expressed as ± one standard deviation. Mean values are also calculated as a function of analytical procedure and all raw data are given in the tables. Recommended values are proposed based upon data criteria used by NIST (National Institute of Standards and Technology, formerly the National Bureau of Standards or NBS).