Stop making sense: the trials and tribulations of qualitative data analysis

An account is given of a research project with particular attention to the place of data analysis and interpretation. It shines some light into what often remains the black box of qualitative research practice, the mysterious process of generating a research narrative based on the data. The paper provides other apprentice researchers with an insight into what the data analytical experience can be like, warts and all. It raises issues to do with qualitative data analysis, the use of CAQDAS, grounded theory, the relationship between the narratives of the researcher and the researched, and about the training of qualitative researchers.     

Tree Coring as a Complement to Soil Gas Screening to Locate PCE and TCE Source Zones and Hot Spots

Preliminary risk assessment for prioritisation of site investigations requires efficient screening to reveal type and level of contamination. The screening methods, tree coring and soil gas sampling were applied and compared at two forested sites contaminated with tetrachloroethylene (PCE) or trichloroethylene (TCE) to evaluate their ability to locate source zones and contaminant hot spots. One test site represented a relatively homogeneous sandy soil and aquifer, and the second a more heterogeneous geology with both sandy and less permeable clay till layers overlying a chalk aquifer. Tree cores from different tree species were sampled and analysed, and compared to soil gas measurements and existing soil gas data. Both methods were found useful as screening tools to locate hot spots of PCE and TCE in the shallow subsurface. Tree coring was found to be particularly beneficial as a complement to soil gas sampling at sites with low permeable soils, and where contamination was located in the capillary rise or shallow groundwater. The shorter time required for tree coring reduced the costs compared to soil gas sampling, but the sensitivity and precision of tree coring were lower. However, this did not affect the feasibility of using tree coring to locate the hot spots. Moreover, a combination of the two methods can help to focus any subsequent investigations like soil or groundwater sampling. The use of tree coring to complement soil gas sampling for pre‐screening is expected to result in higher certainty for revealing hot spots and source zones at contaminated sites.     

Refinement of Phosphorus Determination in Quartz by LA‐ICP‐MS through Defining New Reference Material Values

The aim of this study was to improve the quality of laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) determination of phosphorus in crystalline quartz. Over the last decade, the Geological Survey of Norway has routinely performed trace element determinations on quartz from both operating and potential quartz deposits by LA‐ICP‐MS. The determined phosphorus concentrations were, with but few exceptions, consistently within the range of 10 to 30 μg g^?1, results that seemed to be both too high and too consistent. The multi‐material calibration curve obtained from a suite of reference materials (NIST SRM 610, 612, 614, 1830, BAM No. 1 amorphous SiO₂ glass) did not define a precise regression line. Published phosphorus concentrations for the reference materials are poorly constrained and the observed dispersions along the multi‐material calibration curve suggest that some of the reference values may be inaccurate. Furthermore, the calibration curve did not pass through the origin of the [(cps ³¹P/cps ³⁰Si) · cone. Si] vs. P concentration diagram; thus, in addition to the uncertainties of the literature values of phosphorus, it is difficult to define the calibration curve. Three reference materials (NIST SRM 614, 1830, synthetic quartz KORTH) were sent for phosphorus accelerator implantation, providing an independent and accurate (± 3%) approach for determining phosphorus concentrations in crystalline quartz. The intrinsic phosphorus concentrations of the three implanted samples plus those for NIST SRM 610 and 612 were determined by secondary ion mass spectrometry (SIMS), yielding new phosphorus values for NIST SRM 610, 612, 614 and 1830. Using these new values resulted in a better defined LA‐ICP‐MS calibration curve. However, the source of the ICP‐MS related background could not be defined, such that it must still be empirically corrected for.     

Preparation of a Synthetic Titanite Glass Calibration Material for In Situ Microanalysis by Direct Fusion in Graphite Electrodes: A Preliminary Characterisation by EPMA and LA-ICP-MS

This paper describes a technique for the preparation of a titanite (CaTiSiO₅) glass calibration material for use in in situ microanalysis of major, minor, and trace elements in geological materials. The starting composition was a titanite matrix doped with minor and trace elements at ∼ 200 μg g^-1. The elements Sc, Y, REEs, Th and U were added in the form of nitrates in solution, and the elements V, Cr, Mn, Fe, Co, Ni, Zr, Nb, Hf and W were added as solid oxides. The synthetic titanite glass was produced by direct fusion by resistance heating in graphite electrodes at 1600-1700 °C, and quenched in air. Backscattered electron images indicate good homogeneity, with no signs of separate phases or vesicles, and analysis of the major elements Ca, Ti and Si by electron microprobe showed relative standard deviations between 0.5 and 0.7%, based on six independent measurements. Deviations from nominal concentrations for Ca, Si and Ti were measured to -1.2, -3.3 and -0.8%, respectively. The homogeneity of the trace elements in the glass was assessed by LA-ICP-MS analyses, using NIST SRM 610, 612 and 616 as external calibrators, and Ca as the internal standard element. Determinations were made both with a quadrupole mass spectrometer and a sector field instrument, and both raster and spot modes of analysis were used. For the majority of doped elements, precision was better than 10%, and relative deviations from nominal values were, with few exceptions, between 5 and 10%.     

The relative impact of future storminess versus offshore dredging on suspended sediment concentration in a shallow coastal embayment: Rødsand lagoon,western Baltic Sea

Natural and human-induced disturbances challenge the resilience of coastal ecosystems. The relative impact of a projected increase in storm intensity versus a temporary sediment spill from the construction of the planned Fehmarnbelt Fixed Link on the suspended sediment concentrations was estimated in the shallow coastal embayment of Rødsand lagoon. The investigations were performed through a combination of field observations and numerical modeling. The numerical model was calibrated and validated with the field observations. The lagoonal response to a regional increase in wind speed showed temporarily amplified suspended particulate matter concentration (SPMC) levels (26–37%) and amplified exceedance duration above wash load (30–32%) in the entire lagoon, but especially in the shallow regions. The lagoonal response to a sediment spill outside Rødsand lagoon showed temporarily amplified SPMC levels (2–4%) and amplified exceedance duration above wash load (1–2%) in the entire lagoon, but especially in the regions in close proximity to the spill source. The regional response to increasing wind speed was thus 10-fold larger than the sediment spill where only advective sediment transport took place. This highlights the importance of the internal lagoonal processes as opposed to exterior disturbances. The study contributed to an improved understanding of the potential natural and human-induced stressors on the sediment dynamics in lagoonal ecosystems.

     

Domestic Environmental Benefits of China's Energy-Related CDM Potential

We estimate the domestic environmental and health benefits of exploiting China's energy-related CDM potential. Exploiting the CDM potential may save between 3,000 and 40,000 lives annually. Additional gains are estimated to reach upwards from 1 billion RMB annually. The key to these gains is the fact that actions and measures to reduce CO₂ emissions also reduce emissions of TSP and SO₂. In our estimate, exploiting the CDM-potential will cut SO₂-emissions by between one-half and three million tons annually. To arrive at these conclusions we synthesize a significant body of recent research on co-benefits of climate abatement in China.     

Accuracy of asymptotic series for the kinematics of high solitary waves

The accuracy of several asymptotic series expansions for wave speed and particle velocity under the crest of a solitary wave (on a fluid at rest) up to maximum height is investigated. The very accurate numerical results of Williams (1985) are the measure for our comparisons. The results are based on a scaling of calculated properties of long periodic waves to the case of solitary waves.For wave speeds the classical Boussinesq–Rayleigh expression gives good agreement up to a relative wave height of, say, 0.3. An asymptotic fourth-order expression based on Fenton (1990) can be used up to a relative wave height of 0.7, whereas the corresponding fifth-order expression is slightly less accurate.The Eulerian particle velocity profile under the wave crest is examined using a cnoidal wave expression from Fenton (1990) in the limit of the solitary wave. For low waves a `consistent' (i.e. properly truncated) fifth-order expression and an `inconsistent' ditto both coincide with Williams' results. Beginning at medium high waves, the consistent expression surprisingly exhibits oscillations in the velocity profile, and the oscillations become stronger as the wave gets higher. The inconsistent expression, however, yields the same shape as Williams' profile, but is displaced parallel to this, resulting in slightly larger velocities. For high waves also the inconsistent expression begins to differ in shape from Williams' profile, and asymptotic theory fails. Only for low waves `lowest order theory' gives acceptable results. We show analytically that for the highest wave the particle velocity profile has a horizontal tangent at the water surface; this is corroborated by Williams' numerical results.We also study the particle velocity at the wave crest as a function of wave height. It is shown that the variation has a vertical tangent for the highest wave. Two fifth-order asymptotic series for this velocity, based on the wave speed through the Bernoulli equation, show very good agreement with Williams up to a relative wave height of about 0.6.It is finally shown that it is possible to produce very accurate rational-function approximations to Williams' results for the wave speed as well as for the particle velocity at the wave crest.