A comparative mineralogical study of gas-related sediments of the Gulf of Cádiz

The Gulf of Cádiz area has been extensively surveyed in recent years and several gas-related fluid escape seafloor structures have been identified. In this study, gravity cores, collected during the ANASTASYA/00 and ANASTASYA/01 cruises, on mud volcanoes, hemipelagic sediments and dredged material from diapiric structures, have been studied. A comparative mineralogical analysis by XRD and SEM of samples from different areas has been performed in order to determine whether there is a characteristic mineralogy related to these fluid escape structures, and also to determine the origin of the mud matrix and constrain the depth of the parent units. The mineralogical analysis reflects the different origins of the different units described in the cores: hemipelagic material of the slope, clays that underlie the mud volcanoes and are discharged at the sea bottom surface, and authigenic and diagenetic minerals possibly involved in the anaerobic oxidation of methane in the mud volcano sediments.     

Genetic and chemical relationships between berthierine,chlorite and cordierite in nodules associated to granitic pegmatites of Sierra Albarrana (Iberian Massif,Spain)

Chlorite and berthierine occur through alteration of cordierite within enclaves of metamorphic rocks transformed by the Sierra Albarrana pegmatites. The coexistence of both phyllosilicates allows us to study their stability relationships and to compare their chemical compositions. Samples showing incipient replacement of cordierite by small cryptocrystalline aggregates can be identified by X-ray diffraction (XRD) as berthierine with small quantities of chlorite. Electron Microprobe (EMP) analyses give mixed compositions of berthierine and cordierite. Samples with extensive replacement of cordierite by aggregates show similar characteristics to those with incipient replacement, but some small crystals are present. The last type of sample shows complete replacement of cordierite by crystals showing optical properties of chlorite and EMPA compositions coherent with chlorite or berthierine. Their XRD pattern corresponds to chlorite and their high resolution transmission electron microscopy (HRTEM) images only show perfect sequences of 14 Å lattice fringes. The cryptocrystalline aggregates of the samples with incipient and extensive replacement present coexistent areas of 14 Å and 7 Å lattice fringes that are intergrown at different levels: (1) large areas (> 1 m) of 7 Å layers; (2) packets of 7 Å layers between 14 Å layer areas, with visible 7 Å to 14 Å lateral changes; (3) random mixed-layers 7 Å/14 Å. Chlorite is the final stable product of alteration of cordierite, with berthierine as an intermediate metastable phase. Energy dispersive X-ray spectrometry microanalyses of 14 Å, 7 Å and (14+7) Å areas show lack of systematic differences in chemical compositions between both phyllosilicates which may be considered as true polymorphs.     

On the relationship between kilometer-scale sheath folds, ductile thrusts and minor structures in the basal high-pressure units of the Cabo Ortegal complex (NW Spain)

Large sheath folds in the basal high-pressure nappes of the Cabo Ortegal complex are described and a kinematic interpretation provided. The principal penetrative and map structures relate to regional D2 deformation, which produced foliations (S2) bearing mineral and stretching lineations (L2) and several types of folds (a-type, sheath-like and ‘folded folds’). The latter structures are subparallel to the trend of the orogen. Their attitude suggests that the units involved shared a common tectonic evolution during progressive ductile deformation of an anisotropic medium. Reconstruction of major geological structures was accomplished through projection of map-scale features onto the ductile flow plane and the plane perpendicular to the ductile flow direction. The structures reconstructed illustrate their development in the deeper structural levels of an orogenic channel subjected to high-pressure metamorphism during the early phases of the Hercynian orogeny in NW Iberia. We argue that orogen-normal tectonic displacements (of up to a few hundreds of kilometers) represent the minor components of the transpression with possibly thousands of kilometers along-strike dextral displacement between the intervening plates (during subduction/collision).     

The El Salvador earthquakes of January and February 2001: context, characteristics and implications for seismic risk

The small Central American republic of El Salvador has experienced, on average, one destructive earthquake per decade during the last hundred years. The latest events occurred on 13 January and 13 February 2001, with magnitudes M_w 7.7 and 6.6, respectively. The two events, which were of different tectonic origin, follow the patterns of the seismicity of the region although neither event has a known precedent in the earthquake catalogue in terms of size and location. The earthquakes caused damage to thousands of traditionally built houses and triggered hundreds of landslides, which were the main causes of fatalities. The earthquakes have clearly demonstrated trends of increasing seismic risk in El Salvador due to rapid population expansion in areas of high shaking and landslide hazard, exacerbated by deforestation and uncontrolled urbanisation. The institutional mechanisms required for the control of land use and building practice are very weak and present a major obstacle to risk mitigation.     

Sedimentary aspects and paleoenvironmental evolution of a rift basin: Salta Group (Cretaceous–Paleogene), northwestern Argentina

The rift history of the Salta basin is related to the evolution of the Central Andes and to the activity of the Pacific margin, owing to its geographic location. Sedimentation occurred from the Neocomian to the Paleogene, with deposits reaching up to 5,000 m in thickness. Paleoenvironmental analysis reveals an evolutionary history controlled by tectonic and climatic changes. Isolated grabens characterized the early synrift stage; differential subsidence provoked distinct environments in the southern and northern subbasins. In the southern subbasins, alluvial-fan, fluvial-fan and lacustrine deposits prevail, whilst in the northern subbasins eolian and fluvial environments dominate. During the Maastrichtian, two major factors controlled the basin fill: the decrease in tectonic subsidence and a relative sea-level rise as recorded in South America. An extensive and shallow Atlantic marine ingression installed a carbonate system coincident with mainly humid conditions until the Danian. Until the Middle Eocene, the fluvial and lacustrine environmental evolution of the sag basin was controlled especially by the alternation of temperate with dry and humid periods. Paleontological records reflect these climatic changes and show their relationship to the sedimentation regime.     

Contrasting hydrological response of coastal and desert biocrusts

Biocrusts abound in southern Israel, covering the Hallamish dune field near Nizzana (NIZ) in the Negev (mean annual precipitation of 95 mm) and the coast of Nizzanim (NIM) near Ashdod (mean annual precipitation of 500 mm). While the hydrological response of the NIZ crust to natural rain events was thoroughly investigated, no data is available on the hydrological response of the NIM crust. Runoff was monitored in runoff plots during the years 2005–2008, and in addition, sprinkling experiments were carried out on NIM and NIZ crusts. For the evaluation of the possible factors that may control runoff initiation, fine content of the parent material, crust thickness, compressional strength, hydrophobicity, surface microrelief, organic matter, biomass (chlorophyll a and total carbohydrates) and the crust's species composition of NIM were studied and compared to that of NIZ. The data showed that in comparison to the NIZ crust that readily generated runoff, no runoff was produced by the NIM crust. This was so despite the fact that (1) Microculeus vaginatus predominated in both crusts, (2) the substantially higher rain intensities in NIM, (3) the greater thickness and higher chlorophyll content and (4) the lower microrelief at NIM in comparison to NIZ. The lack of runoff in NIM was explained by its low amounts of exopolysaccharides that did not suffice to affectively clog the surface and in turn to facilitate runoff initiation. The absence of runoff and its consequences on the NIM ecosystem are discussed. Copyright © 2012 John Wiley & Sons, Ltd.     

A multi-tracer approach to delineate groundwater dynamics in the Rio Actopan Basin,Veracruz State,Mexico

Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (¹⁴C, ³H/³He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.     

Mid and late Holocene forest fires and deforestation in the subalpine belt of the Iberian range,northern Spain

The conversion of subalpine forests into grasslands for pastoral use is a well-knownphenomenon, although for most mountain areas the timing of deforestation has not been determined. The presence of charcoal fragments in soil profiles affected by shallow landsliding enabled us to date the occurrence of fires and the periods of conversion ofsubalpine forest into grasslands in the Urbión Mountains, Iberian Range, Spain. We found that the treeline in the highest parts of the northwestern massifs of the Iberian Range(the Urbión, Demanda, Neila, and Cebollera massifs) is currently between 1500 and 1600 m a.s.l., probably because of pastoral use of the subalpine belt, whereas in the past it would have reached almost the highest divides(at approximately 2100–2200 m a.s.l.). The radiocarbon dates obtained indicate that the transformation of the subalpine belt occurred during the Late Neolithic, Chalcolithic, Bronze Age, Iron Age, and Middle Ages. Forest clearing was probably moderate during fires prior to the Middle Ages, as the small size of the sheep herds and the local character of the markets only required small clearings, and therefore more limited fires. Thus, it is likely that the forest recovered burnt areas in a few decades; this suggests the management of the forest and grasslands following a slash-andburn system. During the Middle and Modern Ages deforestation and grassland expansion affected most of the subalpine belt and coincided with the increasing prevalence of transhumance, as occurred in other mountains in the Iberian Peninsula(particularly the Pyrenees). Although the occurrence of shallow landslides following deforestation between the Neolithic and the Roman Period cannot be ruled out, the most extensive shallow landsliding processes would have occurred from the Middle Ages until recent times.