Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.     

极地冰钻关键技术研究进展

极地冰钻技术是获取冰芯,研究冰盖-冰架-海洋相互作用,以及获取极地冰下基岩与冰下水环境样品,开展冰下环境探测的重要手段。目前极地冰钻技术的难点与前沿主要包括深冰芯钻探、冰架热水钻、冰下基岩钻和冰下水环境采样与观测技术。本文针对以上4个极地冰钻关键技术,对国内外相关技术的研究进展与项目开展情况进行了总结与梳理。综合来看,虽然我国开展极地钻探技术研究起步较晚,但随着我国极地战略不断推进,我国的极地冰钻关键技术与装备的研究正持续向着赶超极地钻探强国方向迈进,这必将为我国的极地科学研究提供强有力的技术支撑。     

The dynamics of the northwestern border of the Carpathians

The border area between the Bohemian Massif and the Carpathians arc is covered by dense networks of repeated levellings as well as horizontal (triangulation, trilateration) measurements. The results were adjusted in separate vertical or horizontal networks respectively. Derived rates of vertical and horizontal movements are presented. The properties of these movements are discussed as a background to the tectonic development of the area under study.     

Gravimetric monitoring of the first field‐wide steam injection in a fractured carbonate field in Oman – a feasibility study

Gas‐Oil Gravity Drainage is to be enhanced by steam injection in a highly fractured, low permeability carbonate field in Oman. Following a successful pilot, field‐wide steam injection is being implemented, first of this type in the world. A dedicated monitoring program has been designed to track changes in the reservoir. Various observations are to be acquired, including, surface deformation, temperature measurements, microseismic, well logs, pressure and saturation measurements to monitor the reservoir. Because significant changes in the reservoir density are expected, time‐lapse gravimetry is also being considered. In this paper we investigate the feasibility of gravimetric monitoring of the thermally enhanced gravity drainage process at the carbonate field in Oman. For this purpose, forward gravity modelling is performed. Based on field groundwater measurements, the estimates of the hydrological signal are considered and it is investigated under what conditions the groundwater influences can be minimized. Using regularized inversion of synthetic gravity data, we analyse the achievable accuracy of heat‐front position estimates. In case of large groundwater variations at the field, the gravity observations can be significantly affected and, consequently, the accuracy of heat‐front monitoring can be deteriorated. We show that, by applying gravity corrections based on local observations of groundwater, the hydrological influences can to a large extent be reduced and the accuracy of estimates can be improved. We conclude that gravimetric monitoring of the heat‐front evolution has a great potential.     

High‐temperature gold‐copper extraction with chloride flux in lava tubes of Tolbachik volcano (Kamchatka)

Subvolcanic environments in supra‐subduction zones are renowned for hosting epithermal deposits that often contain electrum and native gold, including bonanza examples. This study examined mineral assemblages and processes occurring in shallow‐crust volcanic settings using recent eruption (2012–2013) of the basaltic Tolbachik volcano in the Kamchatka arc. The Tolbachik eruptive system is characterized by an extensive system of lava tubes. After cessation of magma input, the tubes maintained the flow of hot oxidized gases that episodically interacted with the lava surfaces and sulphate‐chloride precipitates from volcanic gases on these surfaces. The gas‐rock interaction had strong pyrometamorphic effects that resulted in the formation of molten salt, oxidized (tenorite, hematite, Cu‐rich magnesioferrite) and skarn‐like silicate mineral assemblages. By analogy with experimental studies, we propose that a combination of these processes was responsible for extraction of metals from the basaltic wall rocks and deposition of Cu‐, Fe‐ and Cu‐Fe‐oxides and native gold.     

Induction Sounding of the Earth’s Mantle at a New Russian Geophysical Observatory

Deep magnetotelluric (MT) sounding data were collected and processed in the western part of the East European Craton (EEC). The MT sounding results correspond well with impedances obtained by magnetovariation (MV) sounding on the new geophysical observatory situated not far from the western border of Russia. Inversion based on combined data of both induction soundings let us evaluate geoelectrical structure of the Earth’s crust and upper and mid-mantle at depths up to 2000 km, taking into account the harmonics of 11-year variations. Results obtained by different authors and methods are compared with similar investigations on the EEC such as international projects CEMES in Central Europe and BEAR in Fennoscandia.     

Problems connected with the tangential metric coefficient in the Schwarzschild metric: A possible solution

Four situations are shown where the Schwarzschild metric cannot be used or is subject to unsurmountable problems. The first is the question of a metric useful for PPN-formalism checking different gravitational theories. The second problem occurs in connection with Mach's principle, when the flatness of the spacetime inside a massive hollow sphere is a generally accepted solution. The metrical discontinuity on the same spherical shell is a third problem. The fourth one is the anisotropy of the mass-energy of a test particle in the gravitational field. Three principles for solution are proposed:

1. The space is not dilated, but rather contracted, in the gravitational field; then the measurement-rods are shorter and measured distances have greater magnitudes.
2. The potential energy is to be related to a potential level where a stationary observer is placed and the general relativistic potential must be used.
3. A new metric must be introduced which is distinct from the Schwarzschild metric, so that the space in the gravitational field is warped isotropically.

Then the problems stated are shown to be easily solvable.     

Methane fluxes in the southeastern Baltic Sea

New data from surveys of gas-bearing mud areas in the Gdansk Deep (southeastern Baltic Sea) were collected during four research cruises in 2009–2011. These revealed the presence of seven large pockmarks apart from the three already known, and enabled significant improvement of the existing digital map of gassy mud distribution. Based on geochemical sediment analyses, calculated diffusive methane fluxes from the upper (0–5?cm) seabed layer into near-bottom waters were highest—3.3?mmol/(m²?day)—in pockmark mud, contrasting strongly with the minimum value of 0.004?mmol/(m²?day) observed in typical, background mud. However, fluxes of less than 0.1?mmol/(m²?day) were observed in all sediment types, including pockmarks. In a newer attempt to roughly estimate budgets at a more regional scale, diffusive methane venting amounts to 280?×?10⁶?mmol/day for southeastern Baltic Sea muddy sediments. Elongated pockforms in the southern Gotland Deep, known since the end of the 1980s as pockmarks, had methane concentrations that were similar to those of gassy mud from the Gdansk Basin, and there was no geo-acoustic evidence of considerably increased gas levels.