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1.
Daniel P. Glavin Jason P. Dworkin Andrew Aubrey Oliver Botta James H. Doty Zita Martins Jeffrey L. Bada 《Meteoritics & planetary science》2006,41(6):889-902
Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection. 相似文献
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Ronald Amundson Stephanie Ewing Brad Sutter Oliver Chadwick Michelle Walvoord 《Geochimica et cosmochimica acta》2008,72(15):3845-3864
Early (>3 Gy) wetter climate conditions on Mars have been proposed, and it is thus likely that pedogenic processes have occurred there at some point in the past. Soil and rock chemistry of the Martian landing sites were evaluated to test the hypothesis that in situ aqueous alteration and downward movement of solutes have been among the processes that have transformed these portions of the Mars regolith. A geochemical mass balance shows that Martian soils at three landing sites have lost significant quantities of major rock-forming elements and have gained elements that are likely present as soluble ions. The loss of elements is interpreted to have occurred during an earlier stage(s) of weathering that may have been accompanied by the downward transport of weathering products, and the salts are interpreted to be emplaced later in a drier Mars history. Chemical differences exist among the sites, indicating regional differences in soil composition. Shallow soil profile excavations at Gusev crater are consistent with late stage downward migration of salts, implying the presence of small amounts of liquid water even in relatively recent Martian history. While the mechanisms for chemical weathering and salt additions on Mars remain unclear, the soil chemistry appears to record a decline in leaching efficiency. A deep sedimentary exposure at Endurance crater contains complex depth profiles of SO4, Cl, and Br, trends generally consistent with downward aqueous transport accompanied by drying. While no model for the origin of Martian soils can be fully constrained with the currently available data, a pedogenic origin is consistent with observed Martian geology and geochemistry, and provides a testable hypothesis that can be evaluated with present and future data from the Mars surface. 相似文献
5.
Although its use is widespread in several other scientific disciplines, the theory of tensor invariants is only marginally
adopted in gravity field modeling. We aim to close this gap by developing and applying the invariants approach for geopotential
recovery. Gravitational tensor invariants are deduced from products of second-order derivatives of the gravitational potential.
The benefit of the method presented arises from its independence of the gradiometer instrument’s orientation in space. Thus,
we refrain from the classical methods for satellite gravity gradiometry analysis, i.e., in terms of individual gravity gradients,
in favor of the alternative invariants approach. The invariants approach requires a tailored processing strategy. Firstly,
the non-linear functionals with regard to the potential series expansion in spherical harmonics necessitates the linearization
and iterative solution of the resulting least-squares problem. From the computational point of view, efficient linearization
by means of perturbation theory has been adopted. It only requires the computation of reference gravity gradients. Secondly,
the deduced pseudo-observations are composed of all the gravitational tensor elements, all of which require a comparable level
of accuracy. Additionally, implementation of the invariants method for large data sets is a challenging task. We show the
fundamentals of tensor invariants theory adapted to satellite gradiometry. With regard to the GOCE (Gravity field and steady-state
Ocean Circulation Explorer) satellite gradiometry mission, we demonstrate that the iterative parameter estimation process
converges within only two iterations. Additionally, for the GOCE configuration, we show the invariants approach to be insensitive
to the synthesis of unobserved gravity gradients. 相似文献
6.
Efficient GOCE satellite gravity field recovery based on least-squares using QR decomposition 总被引:3,自引:0,他引:3
We develop and apply an efficient strategy for Earth gravity field recovery from satellite gravity gradiometry data. Our approach
is based upon the Paige-Saunders iterative least-squares method using QR decomposition (LSQR). We modify the original algorithm
for space-geodetic applications: firstly, we investigate how convergence can be accelerated by means of both subspace and
block-diagonal preconditioning. The efficiency of the latter dominates if the design matrix exhibits block-dominant structure.
Secondly, we address Tikhonov-Phillips regularization in general. Thirdly, we demonstrate an effective implementation of the
algorithm in a high-performance computing environment. In this context, an important issue is to avoid the twofold computation
of the design matrix in each iteration. The computational platform is a 64-processor shared-memory supercomputer. The runtime
results prove the successful parallelization of the LSQR solver. The numerical examples are chosen in view of the forthcoming
satellite mission GOCE (Gravity field and steady-state Ocean Circulation Explorer). The closed-loop scenario covers 1 month
of simulated data with 5 s sampling. We focus exclusively on the analysis of radial components of satellite accelerations
and gravity gradients. Our extensions to the basic algorithm enable the method to be competitive with well-established inversion
strategies in satellite geodesy, such as conjugate gradient methods or the brute-force approach. In its current development
stage, the LSQR method appears ready to deal with real-data applications. 相似文献
7.
Oliver K. Manuel 《Icarus》1980,41(2):312-315
Isotopically anomalous xenon in chondrites is closely associated with low-Z noble gases, but there is no helium (or neon) in the noble gas component with normal xenon. The correlation of elemental and isotopic heterogeneities in meteoritic noble gases places stringent limits on the origin of isotopically anomalous elements in meteorites and on the formation of the solar system. 相似文献
8.
Frederick W. Oliver 《Planetary and Space Science》1978,26(3):289-290
The Mossbauer spectra has been measured for the Leoville meteorite. Experimental results identify it as a type III carbonaceous meteorite. The spectrum shows the principle iron components to be olivine, magnetite, metallic iron, troilite and phyllosilicate material. 相似文献
9.
B.M. Oliver 《Icarus》1975,25(2):360-367
Approximate expressions are derived for the number of civilizations within a few tens of light years of each other since intelligent life first evolved in the Galaxy. The number is proportional to the square of the usual selectivity factors and to the first power of the longevity. Arguments are presented for expecting intelligent life in certain multiple star systems, and the number of coexistent civilizations in such systems is estimated. 相似文献
10.