Removal of diazinon pesticide from aqueous solutions using MCM-41 type materials: isotherms,kinetics and thermodynamics

In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g^?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L^?1, temperature of 298 K and adsorbent dose of 0.1 g L^?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L^?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups.     

Three‐dimensional nonlinear finite element analysis of pile groups in saturated porous media using a new transmitting boundary

The dynamic behaviour of pile groups subjected to an earthquake base shaking is analysed. An analysis is formulated in the time domain and the effects of material nonlinearity of soil, pile–soil–pile kinematic interaction and the superstructure–foundation inertial interaction on seismic response are investigated. Prediction of response of pile group–soil system during a large earthquake requires consideration of various aspects such as the nonlinear and elasto‐plastic behaviour of soil, pore water pressure generation in soil, radiation of energy away from the pile, etc. A fully explicit dynamic finite element scheme is developed for saturated porous media, based on the extension of the original formulation by Biot having solid displacement (u) and relative fluid displacement (w) as primary variables (u–w formulation). All linear relative fluid acceleration terms are included in this formulation. A new three‐dimensional transmitting boundary that was developed in cartesian co‐ordinate system for dynamic response analysis of fluid‐saturated porous media is implemented to avoid wave reflections towards the structure. In contrast to traditional methods, this boundary is able to absorb surface waves as well as body waves. The pile–soil interaction problem is analysed and it is shown that the results from the fully coupled procedure, using the advanced transmitting boundary, compare reasonably well with centrifuge data. Copyright © 2007 John Wiley & Sons, Ltd.     

Strength behavior and microstructural characteristics of tropical laterite soil treated with sodium silicate-based liquid stabilizer

Although the effects of nontraditional stabilizers on the geotechnical properties of tropical soils has been the issue of investigation in recent years, the micro-structural characteristics of nontraditional soil additives and in particular selected additive (TX-85) have not been fully studied. Nontraditional soil stabilization additives are widely used for stabilizing marginal materials. These additives are low-cost alternatives to traditional construction materials and have different compositions. They also differ from one another while interacting with soil. In line with that, it was the objective of this research to investigate the strength properties and physicochemical mechanisms related to tropical laterite soil mixed with the liquid stabilizer TX-85. Macro-structure study, i.e., compaction, and unconfined compression strength test were used to assess the engineering and shear properties of the stabilized laterite soil. In addition, the possible mechanisms that contributed to the stabilization process were discussed using various spectroscopic and microscopic techniques such as X-ray diffractometry (XRD), energy-dispersive X-ray spectrometry, scanning electron microscopy, and Fourier transform infrared spectroscopy. From engineering point of view, the results indicated that the strength of TX-85 stabilized laterite soil improved significantly. The degree of improvement was approximately four times stronger than natural soil after a 7-day curing period. The XRD showed no crystalline products (gel form). Moreover, weathering effects were obvious in TX-85 treated samples in most of clay minerals’ peak intensities. These effects were reduced especially for kaolinite mineral inside the soil with curing time.     

Physicochemical behavior of tropical laterite soil stabilized with non-traditional additive

Non-traditional soil stabilizers are widely used for treating weak materials. These additives are cost- and time-effective alternatives to more traditional materials such as lime and cement. It has been well established that the treatment of natural soil with chemical additives will gradually affect the size, shape, and arrangement of soil particles. Furthermore, the degree of improvement is dependent on the quantity and the pattern of new products formed on and around the soil particles. In this paper, unconfined compressive strength (UCS) test was performed as an index of soil improvement on mix designs treated with calcium-based powder stabilizer (SH-85). The time-dependent changes in shear strength parameter and compressibility behavior of treated soil were also studied using standard direct shear and one-dimensional consolidation tests. In order to better understand the shape and surface area of treated particles, FESEM, N₂-BET, and particle size distribution analysis were performed on soil-stabilizer matrix. From engineering standpoint, the UCS results showed that the degree of improvement for SH-85-stabilized laterite soil was roughly five times stronger than the untreated soil at the early stages of curing (7-day period). Also, a significant increase in the compressibility resistance of treated samples with curing time was observed. Based on the results, less porous and denser soil fabric was seen on the surface of clay particles. FESEM images of the treated mix designs showed the formation of white lumps in the soil fabric with the cementitious gel filling the pores in the soil structure.     

Discrimination of Crust and Mantle Deformation from Differential SKS-Ps Splitting Analysis,Iranian Plateau

Geotectonics - We present a new technique for shear wave splitting analysis in anisotropic mantle by combining the splitting analysis of Ps phases in receiver functions and SKS splitting analysis....     

Multi-scale assessment of invasive plant species diversity using Pléiades 1A,RapidEye and Landsat-8 data

We used a full remote sensing-based approach to assess plant species diversity in large and inaccessible areas affected by Lantana camara L., a common invasive species within the deciduous forests of Western Himalayan region of India, using spectral heterogeneity information extracted from optical data. The spread of L. camara was precisely mapped by Pléiades 1A data, followed by comparing Pléiades 1A, RapidEye and Landsat-8 OLI – assessed plant species diversities in invaded areas. The single plant species analysis was improved by Pléiades 1A-based diversity analysis, and higher species diversity values were observed for mixed vegetation cover. Furthermore, lower Coefficient of Variation and Renyi diversity values were observed where L. camara was the only species, while higher variations were observed in areas with a mixed spectral reflectance. This study was concluded to add a crucial baseline to the previous studies on remote sensing-based solutions for rapid estimation of biodiversity attributes.     

Measuring and Simulating Co(II) Sorption on Waste Calcite,Zeolite and Kaolinite

Sorption of cobalt (CoII) ions from aqueous solution by waste calcite, kaolinite and zeolite was investigated in a series of batch experiments. The sorption capacity of the sorbents was a function of the initial solution pH, contact time and sorbent/sorbate ratio. For these three sorbents, the kinetic and isotherm experimental data were well fitted to pseudo-second-order and Langmuir equations, respectively. The maximum sorption capacity (mg g^?1) of Co(II) was 4.67, 3.76 and 2.23 for waste calcite, zeolite and kaolinite, respectively. Desorption experiments showed that the desorption capacities were in the order of zeolite?>?kaolinite?>?waste calcite. The equilibrium and kinetic results indicated that waste calcite had the best performance for the removal of Co(II) compared to zeolite and kaolinite. To simulate and predict Co(II) sorption mechanisms, the surface complexation and cation exchange models in PHREEQC program were used. The model results suggested that the main mechanisms of Co(II) sorption on waste calcite and zeolite were surface complexation and cation exchange, respectively. In the case of kaolinite, the model predicted that both mechanisms were involved in the sorption of Co(II), but the surface complexation was the predominant mechanism.

     

Synthetic RapidEye data used for the detection of area-based spruce tree mortality induced by bark beetles

Tree mortality caused by outbreaks of the bark beetle Ips typographus (L.) plays an important role in the natural dynamics of Norway spruce (Picea abies L.) stands, which could cause far-reaching changes in the occurrence and duration of vegetation phenology. Field-based early detection of tree disturbances is hampered by logistic, terrain, and technical shortcomings, and by the inability to continuously monitor disturbances over large areas. Despite achievements in remote mapping of bark-beetle-induced tree mortalities, early warning has been mostly unsuccessful mainly because of the lack of spectral sensitivity and discrepancies in definitions of field- and image-based disturbance classes. Here we applied a method based on inter-annual phenology of Norway spruce stands derived from synthetic multispectral data to part of the Bavarian Forest National Park in Germany. We fused temporally continuous Moderate Resolution Imaging Spectroradiometer and discrete RapidEye data using a flexible spatiotemporal data fusion method to achieve validated 8-day RapidEye-like composites of normalized difference vegetation index for 2011. We assumed that the dead trees delineated on 2012 aerial photographs were those in which bark beetle infestations were initiated in 2011. Samples were drawn with variable-sized buffering to represent the areas prone to infestations and their surroundings. We applied a conditional inference random forest to select the best image date among the entire 46 synthetic datasets to best discriminate between the core infestation patches and their surroundings from the subsequent year. Of the discrete time points identified, day 281 of the year represented the highest discrepancy between aerial image-based dead trees and their surroundings. Classification results were significantly correlated with beetle count data obtained using pheromone traps. Our method provided valuable information for management purposes and enabled wall-to-wall mapping of stands prone to infestation and its uncertainty. The results offer potential implications for rapid and cost-effective monitoring of bark beetle outbreaks using satellite data, which would be of great benefit for both management and research tasks.