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Nenad Grba Aleksandra Šajnović Ksenija Stojanović Vladimir Simić Branimir Jovančićević Goran Roglić Vladisav Erić 《Chemie der Erde / Geochemistry》2014
Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined. 相似文献
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Magnetic properties of the profiles of polluted and non-polluted soils. A case study from Ukraine 总被引:7,自引:0,他引:7
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Aleksandra Šajnović Ksenija Stojanović Branimir Jovančićević Olga Cvetković 《Chemie der Erde / Geochemistry》2008,68(4):395-411
In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0–400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals of 15–75 m (A), 75–200 m (B) and 360–400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators.The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C25 are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C25 content.Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C17 content compared to n-C27, and phytane compared to n-C18. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C26 (hypersaline depositional environment), or isoprenoid C25 and n-alkane C22 for high alkalinity environment.This study showed that Sq/n-C26 ratio can be used to assess the quality of organic substance in immature lacustrine sediments. 相似文献
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Aleksandra ?AJNOVI? Nenad GRBA Franz NEUBAUER Milica KA?ANIN-GRUBIN Ksenija STOJANOVI? Nenad PETKOVI? Branimir JOVAN?I?EVI? 《《地质学报》英文版》2020,94(5):1591-1618
A combined inorganic and organic geochemical study was carried out on marls and mudstones collected from the Lower Miocene Lopare Basin, Bosnia and Herzegovina. A total of 46 samples collected from two boreholes, Pot 1 (depth of 193 m) and Pot 3 (depth of 344 m), showed that element abundances like boron (B), lithium (Li), strontium (Sr), uranium (U), chromium (Cr), nickel (Ni), magnesium (Mg), sodium (Na) and calcium (Ca) are much higher than average than in the upper continental crust (UCC). Chemical composition indicates at least two sources: (i) Mesozoic ophiolites occurring in the north of the investigated area, and (ii) dacito-andesitic pyroclastics (Mesozoic to Cenozoic). Lopare Basin sedimentation was influenced by strong evaporation resulting in a partly hypersaline lake, which formed during a warm climatic period, probably during the Miocene Climatic Optimum. A brief episode of humid climate conditions resulted in the basin filling-up and deposition of felsic sediments enriched in thorium (Th). Organic geochemistry shows that the majority of studied sediments contains predominantly immature to marginally mature algal organic matter (OM). The biomarker patterns are generally in agreement with the geological history of the Lopare Basin and inorganic and mineralogical data. Conversely, the molecular distribution of n-alkanes as reliable climatic and δ-MTTC as paleosalinity indicators do not support this conclusion. 相似文献
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Sanja Mrki?Ksenija Stojanovi? Aleksandar Kosti?Hans Peter Nytoft Aleksandra Šajnovi? 《Organic Geochemistry》2011,42(6):655-677
The origin, depositional environment and maturity of petroleum source rocks were determined via conventional whole rock and biomarker analysis of samples from wells in the Banat Depression, where the most important Serbian oil and gas fields are located. The organic matter (OM) in organic-rich upper Tertiary siltstones and marls consists predominantly of Type II kerogen. Numerous biomarker parameters indicated mixed algal-terrestrial OM, related to a brackish or freshwater environment, whose salinity decreased from Middle to Upper Miocene. The OM was deposited under variable redox conditions, reducing to sub-oxic.The wells in the Banat Depression experienced variable high rates of rapid heating, providing an opportunity for examining the applicability of different thermal indicators in a hyperthermal basin. Rock-Eval and numerous biomarker parameters indicate that the main stage of oil generation begins at ca.130 °C and vitrinite reflectance (Rc) ca. 0.63% and reaches a maximum at ca.145-150 °C and Rc ca. 0.72-0.75%, while the late stage of oil generation starts at ca.155 °C and ca. Rc 0.78%, which corresponds, depending on geothermal gradient, to relative depths of 2100-2300 m, 2600-2900 m and 3050-3100 m, respectively. The naphthalene and phenanthrene maturity parameters proved to be less applicable than the biomarker ratios, particularly in the early to moderate maturation range. The newly proposed parameter C(14a)-homo-26-nor-17α(H)-hopane/C30hopane (C30HH/C30H) proved applicable to a wide range of maturity. 相似文献
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Aleksandra Šajnović Ksenija Stojanović Branimir Jovančićević Anatoly Golovko 《Environmental Geology》2009,56(8):1629-1641
Sediments from the Valjevo-Mionica Basin of Neogene age were investigated in this study using different geochemical methods.
The results of the inorganic part analyses suggest that during genesis of the sediments, the contents of Na2O, B and As changed the most, which indicates that genesis of the investigated sediments was followed by climate changes and
volcanic activity. The quantity of other macro- and microelements did not vary significantly. Investigations of the organic
substance showed that it is native organic matter, which has been preserved to a significant extent, formed predominantly
of algal precursor organisms, which provided good quality, deposited under reducing conditions and that it is at a low maturity
level. As it has been established that genesis of the investigated sediments was mostly affected by an arid climate with more
intensive salinity, the aim of this study, was also to identify the processes which were the most affected by the change in
salinity, as well as biomarkers which are the most sensitive to this change. The results led to the conclusion that the salinity
increase in the depositional environment had a primary effect on the preservation of the organic substance and the formation
of the mineral searlesite. In addition, it was noticed that besides the Sq/nC26 ratio, the parameters nC17/nC27, CPI and Ph/nC18, are also significantly sensitive to salinity change in a depositional environment in case of immature organic substance
deposited under reducing conditions. 相似文献
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Maria Jeleńska Agata Hasso-Agopsowicz Magdalena Kądziałko-Hofmokl Barbara Kopcewicz Anatoliy Sukhorada Ksenija Bondar Zhanna Matviishina 《Acta Geophysica》2008,56(4):1043-1064
Our study concerned magnetic properties of soil profiles taken from polluted regions of Eastern Ukraine around the industrial centres Krivyj Rig, Mariupol and Komsomolsk. Soils represent chernozem and podzoluvisol. The low-field magnetic susceptibility shows enhancement in the topsoil caused by contamination by coarse-grain magnetite connected with industrial pollution. Magnetic mineralogy was determined by means of thermal demagnetisation of SIRM, monitoring of susceptibility changes during warming from ?196°C to room temperature and heating to 700°C, and Mössbauer analysis. Granulometry of magnetic particles was investigated by determination of hysteresis parameters, susceptibility, M s , SIRM and ARM ratios and frequency dependence of susceptibility. The chemical parameters, namely pH, organic carbon and iron content in different pedogenic and lithogenic minerals, measured for particular horizons determined pedogenic characteristic of soil profiles. Our study showed that differences in magnetic parameters of non-polluted and polluted soil profiles are not limited to the topsoil, but reach deep layers of the parent material. Industrial pollution promotes formation of the so-called “pedogenic” SP and SD particles in these layers. 相似文献
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