The use of principle component analyses in characterising trace and major elemental distribution in a 55 kyr peat deposit in tropical Australia: Implications to paleoclimate

The Lynch’s Crater peat deposit in NE-Australia is a sensitive environmental archive located in the tropical Southern Hemisphere. This unique deposit illustrates that local and regional changes had a profound effect on the local Australian ecosystem over the past 55 kyr. To obtain a proxy of past climate changes, trace and major element geochemistry analyses were applied to a 13 m peat core from the crater. Principle component analysis (PCA) was used to identify the main factors that control elemental distribution in the peat and to add interpretative strength to the geochemical behavior of selected major and trace elements. For example, Sc, Al, Cu, and Pb were found to be related to increased erosion of the basin soils, and from this, several periods of significant flux from atmospheric input and/or terrigenous run-off were identified. Geochemically mobile elements during rock weathering and pedogenesis, such as Mg, Ca, and Sr helped to identify the peat ombrotrophic-minerotrophic boundary at ∼1.5 m depth and offered important information about fluxes of these nutrients to the mire and their dynamics within the deposit. Arsenic and V comparisons between the peat record (high concentrations in some peat sections) and in local basin rocks (very low concentrations), suggested the presence of a long range, atmospheric dust source early in the formation of the mire. The Lynch’s Crater peat record presents a continuous record of environmental change in tropical Australia and contributes new understanding to geochemical processes in peatlands.     

White-light enhancements and small-scale chromospheric activities in an active region

A microflare or a group of Ellerman bombs was found to be associated with several points of white-light enhancements. These points had similar sizes as facular points (d 0.3 arc sec). Temporal evolution of these activities is described. Origins of these activities are discussed to be deeply seated excess heating in chromospheric and photospheric levels.     

Small-scale clusters of photospheric network bright points and their dependence on the solar cycle phase

The tendency of network bright points (NBPs) to form in their surface distribution non-random, small-scale clusters is studied by a 2-D nearest-neighbours test, based on observational data for the distance between separate NBPs. High-resolution photographs taken from long time series obtained at4308 with the 50-cm refractor of Pic du Midi Observatory are used. Three different epochs of the solar cycle were chosen. The results obtained suggest that the degree of clustering depends on the solar cycle phase. Supposing that the NBPs are good tracers of the kilogauss small-scale magnetic field, we use them to obtain information about the subphotospheric small-scale magnetic field organisation and its dependence on the solar cycle phase.     

Distribution of isomorphous cations within octahedral sheets in montmorillonite from Camp-Bertaux

 Ni-saturated montmorillonite from Camp-Bertaux heated at different temperatures has been studied by X-ray powder diffraction, X-ray absorption (EXAFS) and vibration IR spectroscopy. Analysis of the experimental data has shown that heating of samples at temperatures higher than 150° C was accompanied by migration of Ni cations into vacant cis-octahedra of 2:1 layers. In the octahedral sheet the Ni cation has two “heavy” (Fe) and four “light” (Al and Mg) nearest octahedral cations. A model for the octahedral cation distribution in Camp-Bertaux montmorillonite was proposed in which Fe and Mg octahedral cations are segregated in small clusters. Received July 7, 1996 / Revised, accepted August 23, 1996     

THE NEW DECADE: DIGITS AND DIVERSITY

The President of the Photogrammetric Society, Mr. I Newton, chaired a panel discussion concerned with those developments in photogrammetry which may take place during the 1990s.     

Stratospheric methane and nitrogen dioxide from infrared spectra

Values of the mixing ratio by volume of stratospheric NO₂ and CH₄ deduced from infrared spectra taken by means of balloon-borne spectrometers are presented. Possible evidence for the presence of formaldehyde in the stratosphere is also given.