Comparison of marine gas hydrates in sediments of an active and passive continental margin

Two sites of the Deep Sea Drilling Project in contrasting geologic settings provide a basis for comparison of the geochemical conditions associated with marine gas hydrates in continental margin sediments. Site 533 is located at 3191 m water depth on a spit-like extension of the continental rise on a passive margin in the Atlantic Ocean. Site 568, at 2031 m water depth, is in upper slope sediment of an active accretionary margin in the Pacific Ocean. Both sites are characterized by high rates of sedimentation, and the organic carbon contents of these sediments generally exceed 0.5%. Anomalous seismic reflections that transgress sedimentary structures and parallel the seafloor, suggested the presence of gas hydrates at both sites, and, during coring, small samples of gas hydrate were recovered at subbottom depths of 238m (Site 533) and 404 m (Site 568). The principal gaseous components of the gas hydrates wer methane, ethane, and CO₂. Residual methane in sediments at both sites usually exceeded 10 mll^?1 of wet sediment. Carbon isotopic compositions of methane, CO₂, and ΣCO₂ followed parallel trends with depth, suggesting that methane formed mainly as a result of biological reduction of oxidized carbon. Salinity of pore waters decreased with depth, a likely result of gas hydrate formation. These geochemical characteristics define some of the conditions associated with the occurrence of gas hydrates formed by in situ processes in continental margin sediments.     

Transneptunian Binaries

The discovery of binaries among the population of transneptunian objects isa landmark advance in the study of this remote region of the solar system.Determination of binary orbits will enable direct determination of systemmasses, fundamental for determination of density, internal structure, and bulkcomposition. The mere existence of binaries with the observed separations andapparent masses constrains models of planetary formation.     

Physical effects of hurricane bere upon Funafuti atoll,Tuvalu

Detailed aerial photograph analysis of the effects of hurricane Bebe (21 October 1972) on Funafuti atoll using ‘before and after’ photos plus ground truthing give a detailed picture of wind and water motions during passage of the cyclone. Interpretation of damage to coconut palms, motu (cay) and reef‐flat structures together with other directional indicators show that hurricane Bebe passed to the east of the atoll. Average wind and water‐flow directions were substantially different; wind directions changed during the cyclone's movement while wave and surge generated water flows remained more constant. A model showing wind and water motion associated with the storm is presented.     

A high‐resolution pollen and geochemical analysis of late Holocene human impact and vegetation history in southern Cumbria,England

The historic era, which in Cumbria begins with the Roman invasion of AD 71, is a frequently neglected period in palaeoecological research, but its study can bring benefits in improving knowledge of landscape history and in understanding the significance and limitations of palaeoecological records. Pollen and geochemical data are presented for late Holocene records from Deer Dyke and Hulleter Mosses in southern Cumbria. The records show initially low levels of anthropogenic impact, followed by a phase of forest clearance and mixed agriculture from the 7th to 11th centuries AD. The timing of these clearances suggests that they were initially Anglo‐Saxon in origin, rather than Norse. Further clearances in the 16th century AD are interpreted as a response to monastic dissolution and late Tudor population pressures; the landscapes reached their contemporary form following extensive clearances in the 17th century AD. Silicon and titanium concentrations at Deer Dyke Moss were used to reconstruct past levels of atmospheric dust loading, which is broadly related to soil erosion. Geochemical influx was found to peak during periods of landscape transition rather than from established land use. This relationship with pollen data is thought to reflect the predominantly low levels of anthropogenic impact in the region, which changes as substantial woodland clearances during the 16th century AD and continuous land use pressure since then have greatly increased the supply of airborne dust. Copyright © 2008 John Wiley & Sons, Ltd.     

Petrology and mineral chemistry of sedimentary rocks from the Western Solomon Sea

Multichannel seismic reflection profiles recorded in the northern Red Sea show structures that we interpret to be a result of the intrusion of uppermost Miocene salt. We believe that the evaporites are underlaid by attenuated continental crust and the flow of salt is due to renewed faulting of basement in the Pliocene when sea floor spreading began between latitudes 21°N and 15°30°N.     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

The observed limb effect in Fraunhofer lines,I

The absolute limb effect is presented for Fei lines 3767 and 3969; for five Tii lines of multiplet 42 near 4535 and one Tiii line at 4534; two lines of Mgi, 4571 and 5172; two lines of Baii at 5854 and 6497. The scattered light of the McMath solar telescope is illustrated by several figures but not applied to the limb-effect observations. It is suggested that the supergravity shift at the limb is the result of scattering of the atoms in anisotropic velocity field.Operated by the Association of Universities for Research in Astronomy, Inc. (AURA) under cooperative agreement with the National Science Foundation.