Alkylation of polycyclic aromatic hydrocarbons in carbonaceous chondrites

Using microprobe laser-desorption, laser-ionization mass spectrometry (μL²MS), we measured the distributions of alkylated and unalkylated polycyclic aromatic hydrocarbons (PAHs) in the free organic material of 20 carbonaceous chondrites. These meteorites represent a variety of meteorite classes and alteration histories, including CI, CK, CM, CO, CR, CV, and Tagish Lake. This work provides information on free organic compounds that is complementary to studies of the structure and composition of meteoritic macromolecular content.For the nine CM2 meteorites analyzed, we observe that higher relative abundances of alkylated PAHs correlate with more intense aqueous activity. We attribute this correlation to the differences in solubility and volatility between unalkylated and alkylated PAHs. Naphthalene and its alkylation series are more susceptible to the effects of aqueous exposure than the less-soluble PAH phenanthrene and its alkylated derivatives. These observations are consistent with the possibility of chromatographic separations on the meteorite parent bodies. We identify six CM2 meteorites with similar PAH distributions that may represent the original, unaltered organic composition of the parent body.Increased metamorphic intensity reduces the abundance of all PAHs. The thermally metamorphosed CK chondrites had no detectable levels of typical meteoritic PAHs. This observation might be explained either by a loss of PAHs caused by volatilization or by a significantly different organic content of the CK parent body.     

Porites corals as recorders of mining and environmental impacts: Misima Island, Papua New Guinea

In 1989 open-cut gold mining commenced on Misima Island in Papua New Guinea (PNG). Open-cut mining by its nature causes a significant increase in sedimentation via the exposure of soils to the erosive forces of rain and runoff. This increased sedimentation affected the nearby fringing coral reef to varying degrees, ranging from coral mortality (smothering) to relatively minor short-term impacts. The sediment associated with the mining operation consists of weathered quartz feldspar, greenstone, and schist. These rocks have distinct chemical characteristics (rare earth element patterns and high abundances of manganese, zinc, and lead) and are entering the near-shore environment in considerably higher than normal concentrations. Using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), we analyzed eight colonies (two from high sedimentation, two transitional, two minor, and two unaffected control sites) for Y, La, Ce, Mn, Zn, and Pb. All sites show low steady background levels prior to the commencement of mining in 1988. Subsequently, all sites apart from the control show dramatic increases of Y, La, and Ce associated with the increased sedimentation as well as rapid decreases following the cessation of mining. The elements Zn and Pb exhibit a different behavior, increasing in concentration after 1989 when ore processing began and one year after initial mining operations. Elevated levels of Zn and Pb in corals has continued well after the cessation of mining, indicating ongoing transport into the reef of these metals via sulfate-rich waters. Rare earth element (REE) abundance patterns measured in two corals show significant differences compared to Coral Sea seawater. The corals display enrichments in the light and middle REEs while the heavy REEs are depleted relative to the seawater pattern. This suggests that the nearshore seawater REE pattern is dominated by island sedimentation. Trace element abundances of Misima Island corals clearly record the dramatic changes in the environmental conditions at this site and provide a basis for identifying anthropogenic influences on corals reefs.     

Assessment of boundary-element method for modelling a free-floating sloped wave energy device. Part 1: Numerical modelling

The boundary-element method has been widely used as a design tool in the offshore and ship building industry for more than 30 years. Its application to wave energy conversion is, however, more recent. This paper deals with the numerical modelling of a free-floating sloped wave energy device. The power take-off mechanism of the device consists of an immersed tube with a piston sliding inside. The modelling is done using the boundary-element method package WAMIT. The model is first worked out for the case where the axis of the tube is vertical. It is then derived for the tube inclined and successfully verified against numerical benchmark data. A companion paper presents results of a detailed comparison with a physical model study.     

Revised recommended methods for analyzing crater size-frequency distributions

Impact crater populations help us to understand solar system dynamics, planetary surface histories, and surface modification processes. A single previous effort to standardize how crater data are displayed in graphs, tables, and archives was in a 1978 NASA report by the Crater Analysis Techniques Working Group, published in 1979 in Icarus. The report had a significant lasting effect, but later decades brought major advances in statistical and computer sciences while the crater field has remained fairly stagnant. In this new work, we revisit the fundamental techniques for displaying and analyzing crater population data and demonstrate better statistical methods that can be used. Specifically, we address (1) how crater size-frequency distributions (SFDs) are constructed, (2) how error bars are assigned to SFDs, and (3) how SFDs are fit to power-laws and other models. We show how the new methods yield results similar to those of previous techniques in that the SFDs have familiar shapes but better account for multiple sources of uncertainty. We also recommend graphic, display, and archiving methods that reflect computers’ capabilities and fulfill NASA's current requirements for Data Management Plans.     

Relating groundwater to seasonal wetlands in southeastern Wisconsin, USA

Historically, drier types of wetlands have been difficult to characterize and are not well researched. Nonetheless, they are considered to reflect the precipitation history with little, if any, regard for possible relation to groundwater. Two seasonal coastal wetland types (wet prairie, sedge meadow) were investigated during three growing seasons at three sites in the Lake Michigan Basin, Wisconsin, USA. The six seasonal wetlands were characterized using standard soil and vegetation techniques and groundwater measurements from the shallow and deep systems. They all met wetland hydrology criteria (e.g., water within 30 cm of land surface for 5% of the growing season) during the early portion of the growing season despite the lack of appreciable regional groundwater discharge into the wetland root zones. Although root-zone duration analyses did not fit a lognormal distribution previously noted in groundwater-dominated wetlands, they were able to discriminate between the plant communities and showed that wet prairie communities had shorter durations of continuous soil saturation than sedge meadow communities. These results demonstrate that the relative rates of groundwater outflows can be important for wetland hydrology and resulting wetland type. Thus, regional stresses to the shallow groundwater system such as pumping or low Great Lake levels can be expected to affect even drier wetland types.     

Measuring impact crater depth throughout the solar system

One important, almost ubiquitous, tool for understanding the surfaces of solid bodies throughout the solar system is the study of impact craters. While measuring a distribution of crater diameters and locations is an important tool for a wide variety of studies, so too is measuring a crater's “depth.” Depth can inform numerous studies including the strength of a surface and modification rates in the local environment. There is, however, no standard data set, definition, or technique to perform this data-gathering task, and the abundance of different definitions of “depth” and methods for estimating that quantity can lead to misunderstandings in and of the literature. In this review, we describe a wide variety of data sets and methods to analyze those data sets that have been, are currently, or could be used to derive different types of crater depth measurements. We also recommend certain nomenclature in doing so to help standardize practice in the field. We present a review section of all crater depths that have been published on different solar system bodies which shows how the field has evolved through time and how some common assumptions might not be wholly accurate. We conclude with several recommendations for researchers which could help different data sets to be more easily understood and compared.     

Towards a climate event stratigraphy for New Zealand over the past 30 000 years (NZ‐INTIMATE project)

It is widely recognised that the acquisition of high‐resolution palaeoclimate records from southern mid‐latitude sites is essential for establishing a coherent picture of inter‐hemispheric climate change and for better understanding of the role of Antarctic climate dynamics in the global climate system. New Zealand is considered to be a sensitive monitor of climate change because it is one of a few sizeable landmasses in the Southern Hemisphere westerly circulation zone, a critical transition zone between subtropical and Antarctic influences. New Zealand has mountainous axial ranges that amplify the climate signals and, consequently, the environmental gradients are highly sensitive to subtle changes in atmospheric and oceanic conditions. Since 1995, INTIMATE has, through a series of international workshops, sought ways to improve procedures for establishing the precise ages of climate events, and to correlate them with high precision, for the last 30 000 calendar years. The NZ‐INTIMATE project commenced in late 2003, and has involved virtually the entire New Zealand palaeoclimate community. Its aim is to develop an event stratigraphy for the New Zealand region over the past 30 000 years, and to reconcile these events against the established climatostratigraphy of the last glacial cycle which has largely been developed from Northern Hemisphere records (e.g. Last Glacial Maximum (LGM), Termination I, Younger Dryas). An initial outcome of NZ‐INTIMATE has been the identification of a series of well‐dated, high‐resolution onshore and offshore proxy records from a variety of latitudes and elevations on a common calendar timescale from 30 000 cal. yr BP to the present day. High‐resolution records for the last glacial coldest period (LGCP) (including the LGM sensu stricto) and last glacial–interglacial transition (LGIT) from Auckland maars, Kaipo and Otamangakau wetlands on eastern and central North Island, marine core MD97‐2121 east of southern North Island, speleothems on northwest South Island, Okarito wetland on southwestern South Island, are presented. Discontinuous (fragmentary) records comprising compilations of glacial sequences, fluvial sequences, loess accumulation, and aeolian quartz accumulation in an andesitic terrain are described. Comparisons with ice‐core records from Antarctica (EPICA Dome C) and Greenland (GISP2) are discussed. A major advantage immediately evident from these records apart from the speleothem record, is that they are linked precisely by one or more tephra layers. Based on these New Zealand terrestrial and marine records, a reasonably coherent, regionally applicable, sequence of climatically linked stratigraphic events over the past 30 000 cal. yr is emerging. Three major climate events are recognised: (1) LGCP beginning at ca. 28 000 cal. yr BP, ending at Termination I, ca. 18 000 cal. yr BP, and including a warmer and more variable phase between ca. 27 000 and 21 000 cal. yr BP, (2) LGIT between ca. 18 000 and 11 600 cal. yr BP, including a Lateglacial warm period from ca. 14 800 to 13 500 cal. yr BP and a Lateglacial climate reversal between ca. 13 500 and 11 600 cal. yr BP, and (3) Holocene interglacial conditions, with two phases of greatest warmth between ca. 11 600 and 10 800 cal. yr BP and from ca. 6 800 to 6 500 cal. yr BP. Some key boundaries coincide with volcanic tephras. Copyright © 2007 John Wiley & Sons, Ltd.     

The water impacts of climate change mitigation measures

A variety of proposed activities to mitigate greenhouse gas emissions will impact on scarce water resources, which are coming under increasing pressure in many countries due to population growth and shifting weather patterns. However, the integrated analysis of water and carbon impacts has been given limited attention in greenhouse mitigation planning. In this Australian case study, we analyse a suite of 74 mitigation measures ranked as highest priority by one influential analysis, and we find that they have highly variable consequences for water quantity. We find: (1) The largest impacts result from land-based sequestration, which has the potential to intercept large quantities of water and reduce catchment yields, estimated to exceed 100 Mm³/MtCO₂-e of carbon mitigated (100,000 l per tonne CO₂-e). (2) Moderate impacts result from some renewable power options, including solar thermal power with a water cost estimated at nearly 4 Mm³/MtCO₂-e. However, the water impacts of solar thermal power facilities could be reduced by designing them to use existing power-related water supplies or to use air or salt-water cooling. (3) Wind power, biogas, solar photovoltaics, energy efficiency and operational improvements to existing power sources can reduce water demand through offsetting the water used to cool thermal power generation, with minor savings estimated at 2 Mm³/MtCO₂-e and amounting to nearly 100 Mm³ of water saved in Australia per annum in 2020. This integrated analysis significantly changes the attractiveness of some mitigation options, compared to the case where water impacts are not considered.     

Ecosystem under pressure: ballast water discharge into Galveston Bay, Texas (USA) from 2005 to 2010

Ballast water exchange processes facilitate the dispersal and unnatural geographic expansion of phytoplankton, including harmful algal bloom species. From 2005 to 2010, over 45,000 vessels (≈ 8000 annually) travelled across Galveston Bay (Texas, USA) to the deep-water ports of Houston (10th largest in the world), Texas City and Galveston. These vessels (primarily tankers and bulkers) discharged ≈ 1.2 × 10(8) metrictons of ballast water; equivalent to ≈ 3.4% of the total volume of the Bay. Over half of the ballast water discharged had a coastwise origin, 96% being from US waters. Galveston Bay has fewer non-indigenous species but receives a higher volume of ballast water discharge, relative to the highly invaded Chesapeake and San Francisco Bays. Given the magnitude of shipping traffic, the role of Galveston Bay, both as a recipient and donor region of non-indigenous phytoplankton species is discussed here in terms of the invasibility risk to this system by way of ballast water.