The lost world of the olenid trilobites

Trilobites of the Family Olenidae (Upper Cambrian to Upper Ordovidan) were closely tied to an oxygen-poor environment. They show a remarkable range of adaptations, testifying to a singular evolutionary plasticity.     

SOME ASPECTS OF THE INTERACTION OF BLOWING SNOW WITH THE ATMOSPHERIC BOUNDARY LAYER

Several possible effects of blowing snow on the atmospheric boundary layer are investigated, mostly within the general framework of the Prairie Blowing Snow Model (PBSM). The processes of snow saltation and suspension are first described. Variations to the drift density profile are tested and the effects of stratification and density variation calculations are evaluated. Despite high density gradients of blowing snow, stratification effects on turbulence and the velocity profiles can generally be neglected. However, with saltating or suspended snow in a constant shear stress layer, part of the shear stress is carried by the particles. A highly simplified, single-phase approach, based on the density variation of the air–snow mixture coupled to a simple turbulent stress–strain relationship, is used to illustrate this. Sublimation rates in a column of blowing snow are calculated using the PBSM and results are compared with those obtained with a modified formulation which incorporates a spectrum of sublimating particles of varying sizes at each height in a steady-state surface boundary layer and different specifications of the ventilation velocity.     

Comparisons of the four Miller Range nakhlites,MIL 03346, 090030, 090032 and 090136: Textural and compositional observations of primary and secondary mineral assemblages

Abstract– Petrological and geochemical analyses of Miller Range (MIL) 03346 indicate that this meteorite originated from the same augitic cumulate layer(s) as the nakhlite Martian meteorites, but underwent rapid cooling prior to complete crystallization. As with the other nakhlites, MIL 03346 contains a secondary alteration assemblage, in this case consisting of iddingsite‐like alteration veins in olivine phenocrysts, Fe‐oxide alteration veins associated with the mesostasis, and Ca‐ and K,Fe‐sulfate veins. We compared the textural and mineralogical compositions of MIL 090030, 090032, and 090136 with MIL 03346, focusing on the composition and Raman spectra of the alteration assemblages. These observations indicate that the meteorites are paired, and that the preterrestrial olivine‐bound alteration assemblages were produced by weakly acidic brine. Although these alteration assemblages resemble similar assemblages in Nakhla, the absence of siderite and halite in the Miller Range nakhlites indicates that the parental alteration brine was comparatively HCO₃^? depleted, and less concentrated, than that which altered Nakhla. This indicates that the Miller Range nakhlite alteration brine experienced a separate evolutionary pathway to that which altered Nakhla, and therefore represents a separate branch of the Lafayette‐Nakhla evaporation sequence. Thin‐sections cut from the internal portions of these meteorites (away from any fusion crust or terrestrially exposed edge), contain little Ca‐sulfate (identified as gypsum), and no jarosite, whereas thin‐sections with terrestrially exposed edges have much higher sulfate abundances. These observations suggest that at least the majority of sulfate within the Miller Range nakhlites is terrestrially derived.     

The application of cathodoluminescence to interpreting the diagenesis of an ancient calcrete profile

A laterally extensive calcrete profile has been identified in the Late Asbian (Lower Carboniferous) shallow marine shelf limestones of the Llangollen area, North Wales. The upper surface of the profile is defined by a laterally discontinuous palaeokarstic surface and by laminated calcareous crusts which developed within the underlying limestone. The profile contains a unique series of early pore-filling vadose cements which only occur down to 1 m below the palaeokarstic surface. Cathodoluminescence reveals that these cements pre-date the late pore-filling meteoric phreatic cements which occur throughout local Asbian lithologies. A spar cement stratigraphy has been established for the calcrete profile. Subaerial vadose cements comprise two generations of non-luminescent cement, followed by a brightly luminescent generation which occasionally shows an acicular habit. This needle-fibre calcite represents the final stage of vadose cementation. Precipitation of vadose cements was contemporary with subaerial alteration and micritization of the limestone. Textures, visible only with cathodoluminescence, provide evidence of recurrent periods of fabric dissolution. The most extensive phase of dissolution occurred immediately after the precipitation of the non-luminescent subaerial vadose cements. Several different textures have been recorded, each reflecting the morphology of a partially dissolved substrate. Dissolution textures are generally confined to the walls of the larger pores and to early brecciation fractures. These probably acted as fluid pathways in the calcrete during early subaerial diagenesis. Much of the non-marine micrite in the calcrete profile appears as needle-fibre calcite under cathodoluminescence. This acicular calcite was probably formed in response to localized supersaturation of meteoric pore fluids caused by periods of near-surface evaporation. Since needle-fibre luminescence is strongly variable, these ambient conditions are not believed to have directly controlled the activator ion concentrations of cementing pore waters. Needle-fibre calcite is considered to be a cement precipitate which has almost completely recrystallized to micrite, probably during the late stages of subaerial diagenesis. Two generations of subaerial micrite which define a ‘micrite stratigraphy’, have been distinguished under cathodoluminescence. Reconstructing the diagenetic history of this ancient calcrete profile has revealed that subaerial alteration was multistaged, with many diagenetic processes acting simultaneously during a single phase of emergence.     

THE INFLUENCE OF PERMEABILITY ON COMPRESSIONAL WAVE VELOCITY IN MARINE SEDIMENTS*

To investigate the effect of permeability on the propagation of seismo-acoustic waves through marine sediments, a theoretical model based on Biot's equations is established which relates the compressional wave velocity measured at a fixed frequency to computed velocities at zero and infinite frequencies in terms of sediment porosity and permeability. The model is examined experimentally in a standard soil mechanics consolidation test (itself dependent, among other things, on sediment porosity and permeability) which has been modified to include measurements of compressional wave velocity at 1 MHz and shear-wave velocity at 5 kHz. This test allows the elastic modulus of the sediment frame to be assessed under different load conditions simultaneous with the velocity determinations. From a number of tests on different samples, five samples are chosen to typify the range of sediment sizes. The results show that the difference between the measured velocity at 1 MHz and the model-derived velocity at zero frequency increases with increasing particle size (from clays to fine sand), with decreasing porosity, and with increasing permeability. For sediments coarser than fine sand the simple model breaks down, possibly because of the dominance of scattering/diffraction effects at the high frequency of the experiment. Within this limitation the model seems satisfactory to offer a capability of predicting the permeability of a sea floor sediment to an order of magnitude by the in situ measurement of seismic velocities over a wide range of frequencies; the prediction process requires a good in situ determination of sediment porosity such as that offered by electrical formation factor measurements.     

Diagenetic density inversions and the deformation of shallow marine chert beds in Israel

ABSTRACT Chert folds and 'dyke'-like boudinage in the Senonian Mishash Formation of Israel have orientations consistent with contemporaneous tectonic patterns whereas their amplitudes are anomalously high relative to strains calculated for adjacent layers. We suggest several means by which density inversions associated with chert diagenesis might amplify gentle structures whose wavelengths and orientations were determined by regional stresses.     

Effect of Silica Activity on OH- IR Spectra of Olivine: Implications for Low-aSiO2 Mantle Metasomatism

Hydrogen solubility and hydroxyl substitution mechanism in olivineat upper-mantle conditions are not only a function of pressure,temperature, water fugacity and hydrogen fugacity, but are alsoinfluenced by silica activity. Olivine synthesized in equilibriumwith magnesiowüstite displays hydroxyl stretching bandsin the wavenumber range from 3640 to 3430 cm^–1. In contrast,olivine in equilibrium with orthopyroxene shows absorption bandsin a narrower wavenumber range from 3380 to 3285 cm^–1.The two fundamentally different spectra are assigned to hydroxylin tetrahedral and octahedral sublattices, respectively. Olivinein equilibrium with orthopyroxene is also less capable of incorporatinghydroxyl, relative to olivines in equilibrium with magnesiowüstite,by about a factor of ten. A comparison of spectra obtained aspart of this study with hydroxyl spectra of natural mantle olivinesshows that the latter display hydroxyl stretching patterns reminiscentof equilibrium with magnesiowüstite, although undoubtedlyolivine in the Earth’s mantle coexists with orthopyroxene.This may be attributed to a metasomatic overprint by a low-silicafluid and/or melt that was in reaction relationship with orthopyroxene.A likely metasomatic agent is a carbonatitic melt. When carbonatiticmelts decompose to oxides and CO₂, they may temporarily imposea low-aSiO₂ environment inherited by the olivine structure.If this suggestion proves true, Fourier transform IR spectroscopymay be used to fingerprint metasomatic episodes in the lithosphericmantle. KEY WORDS: FTIR spectrometry; olivine; mantle; metasomatism; water     

FORMATION OF LARGE-SCALE CROSS-BEDDING IN A CARBONATE UNIT

The type Lindsey Bridge Member of the Moorefield Formation of northeastern Oklahoma consists of 24 ft. of massively cross-bedded limestone. Cross-bed shape, lithologic variation, grain size and sorting, distribution of insolubles, and distribution of fossils and fossil burrows can be explained with reference to a hydrodynamic model developed in recent flume studies. Three facies can be distinguished in this unit: (1 Thei) foresets, thick-bedded, well-sorted, fine to medium crinoidal grainstones, dipping at angles up to 1° (2) toesets, which are thin-bedded, poorly sorted, skeletal packstones notably more fossiliferous than the foresets, with which they are laterally gradational; toesets dip at approximately 5°-8° (3) bottomsets, composed of argillaceous, fine-grained (mainly silt-size), skeletal limestones. Foresets overlie previously deposited bottomsets; this geometry is typical of regressive sedimentation. The exposure is adjacent to a pre-Moorefield topographic high. As currents crossing this high entered a basin on the downcurrent side, flow separation occurred. Bed material load was deposited mainly on the foreset slope, suspension material mainly in toeset and bottomset areas. The poor sorting of the toesets is in part due to reverse circulation, formed by the flow separation, which transported bottomset sediment back toward the foreset. Jopling (1965b) has shown that this depositional geometry produces tangential cross-beds similar to those seen in this outcrop. Differential settling velocity, substrate stability, and abundance of organic detritus influenced other sedimentologic properties of the deposit.     

AN UNUSUAL CARBONATE BAND IN THE EAST PENNINE COALFIELD (ENGLAND)

A combined petrographical and geochemical study has been made on a per- sistent carbonate horizon from the Mansfield Marine Band, an important marker horizon in the Westphalian Coal Measures of the east Pennines. The composition of this carbonate is unusual for it normally consists of ankerite, but in some localities the carbonate is siderite and not ankerite. The position of the carbonate in the sedimentary cycle is discussed and the conclusion drawn that physicochemical conditions were suitable for the precipitation of CaC03 to occur. Furthermore the detrital material in the carbonate band continued to accumulate at a similar rate to the shales above and below the carbonate. The alteration of the CaC03 is thought to have been a diagenetic effect and the result of a change in the physicochemical environment. Variations in the concentration of dissolved sulphur species and their effect on the solubilities of iron and manganese provide an adequate mechanism to explain how CaC03 may alter to siderite on the one hand or ankerite on the other.