Diagenesis of late Cenozoic diatomaceous deposits and formation of the bottom simulating reflector in the southern Bering Sea*

Diatom ooze and diatomaceous mudstone overlie terrigenous mudstone beds at Leg 19 Deep Sea Drilling Project sites. The diatomaceous units are 300-725 m thick but most commonly are about 600 m. Diagenesis of diatom frustules follows a predictable series of physical and chemical changes that are related primarily to temperature (depth of burial and local geothermal gradient). During the first 300-400 m of burial frustules are fragmented and undergo mild dissolution. By 600 m dissolution of opal-A (biogenic silica) is widespread. Silica reprecipitates abundantly as inorganic opal-A between 600 and 700 m sub-bottom depth. Inorganic opal-A is rapidly transformed by crystal growth to opal-CT. The result is formation of silica cemented mudstone and porcelanite beds. A regional acoustic reflector (called the bottom-simulating reflector, or BSR) occurs near 600 m depth in the sections. This acoustic event marks the upper surface where silicification (cementation) is active. In Bering Sea deposits, opal-A is transformed to opal-CT at temperatures between 35° and 50°C. This temperature range corresponds to a sub-bottom depth of about 600 m and is the area where silicification is most active. Thus, the BSR represents an isothermal surface; the temperature it records is that required to transform opal-A to opal-CT. Deposition of at least 500 m of diatomaceous sediment was required before the temperature at the base of the diatomaceous section was appropriate (35°-50°C) for silica diagenesis to occur. Accordingly, silica diagenesis did not begin until Pleistocene time. Once silicification began, in response to sediment accumulation during the Quaternary, the diagenetic front (the BSR) moved upsection in pace with the upward migrating thermal boundary. X-ray diffractograms and SEM photographs show three silica phases, biogenic opal-A, inorganic opal-A’, and opal-CT. These have crystallite sizes of 11-16 A, 20-27 A, and 40-81 A, respectively, normal to 101. The d(101) reflection of opal-CT decreases with depth of burial at DSDP Site 192. This occurs by solid-state ordering and requires at least 700 m of burial. Most clinoptilolite in Leg 19 cores forms from the diagenesis of siliceous debris rather than from the alteration of volcanic debris as is commonly reported.     

The Late-Devensian proglacial Lake Humber: new evidence from littoral deposits at Ferrybridge, Yorkshire, England

Proglacial Lake Humber is of UK national significance in terms of landscape drainage and development of the British Ice Sheet (BIS) during Marine Isotope Stage 2 (MIS 2), yet it is poorly understood in terms of its dynamics and timing. Sands and gravels exposed at Ferrybridge, West Yorkshire, UK, are interpreted as part of the Upper Littoral sands and gravels related to a high-level Lake Humber, which inundated the Humber Basin to ∼30 m OD during MIS 2. Excavations exposed well-rounded gravels of local origin extending downslope from the 27.5 m OD contour and interbedded sands and fine gravels, which are interpreted as the coarse littoral deposits and nearshore associated deposits. A sample from the distal sands returned an Optically Stimulated Luminescence age of 16.6±1.2 kyr, providing the first direct age for the high-level lake and for when North Sea Basin ice must have blocked the Humber Gap. An underlying sequence included a diamicton dated to after 23.3 ±1.5 kyr and before 20.5±1.2 kyr, indicating that the Late Devensian ice reached at least 15 km south of the Escrick Moraine prior to the high-level lake. Previous to both the high-level lake and this ice advance, loess found at the two sites investigated indicates a long period of loess deposition earlier in MIS 2. These new data for the history of Lake Humber are discussed in the context of ice-marginal oscillations in both the Vale of York and the North Sea Basin.     

Paucity of sulfide in a large slab of Esquel: New perspectives on pallasite formation

Abstract— The 0.7 ton Esquel meteorite, found in Patagonia before 1951, is a typical main-group pallasite in most respects. We examined petrographically a slab ～1 m long having an area of 3000 cm² that shows the typical pallasitic texture with fragmental olivine. Phase abundances (in vol%) are olivine (66%), metal (32%), schreibersite (0.76%), troilite (0.46%) and chromite (0.31%). Esquel can be divided into four lithologies: (1) “pallasitic” matrix consisting of olivine fragments embedded in metal (81%); (2) large (>5 cm) olivine nodules having low metal contents (18%); (3) massive metal (0.3%); and (4) zones dominated by FeS and fine olivine (0.7%). Main-group pallasites appear to have formed by the intrusion of a highly evolved (low Ir, high Ni, Au and S) metallic magma into fragmented olivine. This model implies that FeS should be abundant in main-group pallasites, and we had speculated that examination of an exceptionally large slab might reveal a high troilite content. We found instead an exceptionally low FeS content. New compositional data confirm that Esquel has a lower Au content than other main-group pallasites having similar Ir contents. Literature data (based, however, on relatively small sections) suggest that high-Au pallasites have higher S contents than Esquel but have lower S contents than expected from a trapped-melt model. We conclude that a relatively complex model is required to explain the origin of main-group pallasites. After intrusion, the degree of crystallization of the metallic magma varied from location to location but, in almost all cases, an FeS-rich liquid either escaped or formed FeS-rich pallasitic rocks that are underrepresented in the meteorite inventory.     

THEIR SPACE: SECURITY AND SERVICE WORKERS IN A BRAZILIAN GATED COMMUNITY*

ABSTRACT. This study examines the role of service workers in creating a secure landscape in a zone of gated communities near Belo Horizonte, Brazil. Most research on gated communities emphasizes their segregation and formal security apparatuses. In fact, gated communities interact with surrounding rural settlements because they draw their service employees from them. Security emerges from informal relationships of trust that property owners establish with service workers. Gardeners, especially, enable homeowners to project their property investment to others through landscaping. Equally of importance, a manicured garden conveys the message that a home is receiving daily attention—and is secure—even if the owner is not present. The study probes this interdependence from the point of view of gardeners in the context of one gated community in an area south of Belo Horizonte and the attempts by members of its homeowners association to minimize the sense of fear they associate with the Brazilian city.