面向21世纪的煤化工

煤炭是中国的主要能源和资源，但同时也是主要的污染源。从保护环境、合理利用有限的化石资源的角度和中国的具体国情考虑，应该大力开发温和化高效煤的新工艺，使煤炭资源逐步由能源型利用转化为材料型利用，近年来，我们在煤的溶剂萃取，脱硫降灰机理，煤相关模型化合物反应，煤焦油中稠环芳香族化合物的分离精制，功能性高分子单体合成及一氧化碳高效吸附剂的制备等方面做了大量的研究工作，结合这些研究工作，本文介绍了煤化工的     

基于MICAPS系统的数字化天气图及常规气象资料检索分析系统

介绍了基于“9210工程”和MICAPS系统的资料自动存储、整理、检索和历史天气图分析业务系统——基于MICAPS系统的数字化天气图及常规气象资料检索分析系统，较全面地介绍了该系统高度自动化、设计友好的功能和在业务中的应用。     

陕西略阳铧厂沟金矿床地质与矿床类型

铧厂沟金矿床位于勉略缝合带中泥盆系三河口群郭镇岩组中。含矿与容矿岩系为泥盆系三河口群郭镇岩组中的细碧岩和结晶灰岩。主控矿构造为寨子湾韧-脆性剪切构造带。围岩蚀变包括退化蚀变和矿化蚀变。在矿区内产出南北两条矿化带，矿石类型为蚀变细碧岩型、黄铁绢英片岩型和石英脉型。主要的金属矿物为黄铁矿和黄铜矿，金矿物是自然金。韧脆性剪切构造叠加和岩石强烈变形、彻底退化蚀变以及后期含矿热液交代与充填是主要的成矿作用，属于火山-沉积岩系中的类卡林型金矿床。     

Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and ²⁹Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 μm, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2 s ). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2 s ). Other examples for older zircons are also given.     

采用弯曲进行道路化简冲突避免的方法

针对道路化简后可能导致要素间空间关系前后不一致的问题,提出了一种采用弯曲进行道路化简冲突避免的方法。首先,以弯曲为单元分析道路化简前后弯曲的形态变化规律,对化简过程产生的要素间空间冲突类型进行了归纳和总结;其次,基于道路弯曲与要素之间的空间关系,提出了相应的冲突判别规则;最后,利用弯曲化简的可控性和弯曲组的间接化简策略实现对化简冲突的避免。试验表明,该方法能有效地识别和避免道路化简产生的空间冲突,确保化简前后道路与其他要素空间关系的一致性。     

顾及邻域居民地群组相似性的道路网匹配方法

现有多源同比例尺道路网匹配方法中,大多只利用道路自身特征进行匹配,而较少顾及道路周边要素对匹配过程的影响和约束,从而影响了道路网匹配效果的进一步提高,特别是对系统误差改正后仍存在一定位置或旋转偏差的道路数据进行匹配时,这种影响尤为明显。本文借鉴人类对陌生环境的空间认知特点,提出了一种顾及邻域居民地群组相似性的道路网匹配方法。该方法通过构建城市骨架线网确定与道路相邻的居民地群组,进而计算居民地群组空间关系和几何特征相似度来获得对应道路的匹配结果。其特点在于:对存在位置或旋转偏差的道路数据匹配,以其邻域空间内居民地群组的整体相似性指标来带动道路自身匹配,实际上是增加了周边居民地群组对道路匹配过程的约束,更具鲁棒性。试验及对比分析表明,本方法能够较好地解决系统误差改正后仍存在较大位置和旋转偏差的道路数据间的匹配问题,提高匹配的正确率。     

渤海湾曹妃甸深槽海区地形地貌特征及控制因素

通过研究浅层地震剖面、侧扫声纳和水深地形等数据资料,得出,曹妃甸沙岛的岬角地貌引起深槽海域局部潮流流速增大,甸头前沿深槽区以冲刷为主,最大水深达42 m,刷新了渤海湾最大水深记录,深槽部位的侵蚀量最大,深槽南坡冲刷幅度大于北坡,工程建设后期深槽区侵蚀冲刷程度有变小变缓趋势。早期深槽的形成是由于浅部断层受深部构造影响发生阶梯状错断沉陷,海底地层形成古凹槽,但深槽海底地层沉陷速率略大于沉积速率,使得深槽海域长期保持了渤海湾最大的水深环境。初步得出在历史时期曹妃甸深槽经过2万a以上长期存在,深槽的走向经历了南北向-北东向-北西向的转化过程。认为地质构造、古滦河三角洲演变、海洋水动力作用和人类活动等内外营力作用共同控制了曹妃甸海区地貌体系的发育与演化。达到了研究渤海湾曹妃甸深槽海区地形地貌控制因素和深槽的地质演化的目的,为曹妃甸港的规划、运营期维护和未来发展提供科学依据具有重要意义。     

湖南汝城盆地原定中侏罗世地层发现早白垩世孢粉组合

通过对湖南汝城盆地原定为中侏罗统的李家洞水库剖面28个孢粉样品的分析处理,发现24个样品有孢粉化石,化石呈现早白垩世孢粉化石组合特征。发现的早白垩世特征分子有高含量的无突肋纹孢Cicatricosisporites,徐氏孢Hsuisporites,刺毛孢Pilosisporites,膜环弱缝孢Aequitriradites,二连粉Erlianpollis,有突肋纹孢Appendicisporites,微囊粉Parvisaccites,以及少量被子植物花粉。依据孢粉化石组合特征,建议将本剖面时代重新厘定为早白垩世。     

Theoretical calculation of equilibrium Mg isotope fractionation between silicate melt and its vapor

Isotope fractionation during the evaporation of silicate melt and condensation of vapor has been widely used to explain various isotope signals observed in lunar soils, cosmic spherules, calcium–aluminum-rich inclusions, and bulk compositions of planetary materials. During evaporation and condensation, the equilibrium isotope fractionation factor (α) between high-temperature silicate melt and vapor is a fundamental parameter that can constrain the melt’s isotopic compositions. However, equilibrium α is difficult to calibrate experimentally. Here we used Mg as an example and calculated equilibrium Mg isotope fractionation in MgSiO₃ and Mg₂SiO₄ melt–vapor systems based on first-principles molecular dynamics and the high-temperature approximation of the Bigeleisen–Mayer equation. We found that, at 2500 K, δ²⁵Mg values in the MgSiO₃ and Mg₂SiO₄ melts were 0.141?±?0.004 and 0.143?±?0.003‰ more positive than in their respective vapors. The corresponding δ²⁶Mg values were 0.270?±?0.008 and 0.274?±?0.006‰ more positive than in vapors, respectively. The general \(\alpha - T\) equations describing the equilibrium Mg α in MgSiO₃ and Mg₂SiO₄ melt–vapor systems were: \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.264 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\) and \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.340 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\), respectively, where m is the mass of light isotope ²⁴Mg and m′ is the mass of the heavier isotope, ²⁵Mg or ²⁶Mg. These results offer a necessary parameter for mechanistic understanding of Mg isotope fractionation during evaporation and condensation that commonly occurs during the early stages of planetary formation and evolution.