Geochemical and oxygen isotope perspective of a new R chondrite Dhofar 1671: Affinity with ordinary chondrites

Dhofar 1671 is a relatively new meteorite that previous studies suggest belongs to the Rumuruti chondrite class. Major and REE compositions are generally in agreement with average values of the R chondrites (RCs). Moderately volatile elements such as Se and Zn abundances are lower than the R chondrite values that are similar to those in ordinary chondrites (OCs). Porphyritic olivine pyroxene (POP), radial pyroxene (RP), and barred olivine (BO) chondrules are embedded in a proportionately equal volume of matrix, one of the characteristic features of RCs. Microprobe analyses demonstrate compositional zoning in chondrule and matrix olivines showing Fa‐poor interior and Fa‐rich outer zones. Precise oxygen isotope data for chondrules and matrix obtained by laser‐assisted fluorination show a genetic isotopic relationship between OCs and RCs. On the basis of our data, we propose a strong affinity between these groups and suggest that OC chondrule precursors could have interacted with a ¹⁷O‐rich matrix to form RC chondrules (i.e., ?¹⁷O shifts from ~1‰ to ~3‰). These interactions could have occurred at the same time as “exotic” clasts in brecciated samples formed such as NWA 10214 (LL3–6), Parnallee (LL3), PCA91241 (R3.8–6), and Dhofar 1671 (R3.6). We also infer that the source of the oxidation and ¹⁷O enrichment is the matrix, which may have been enriched in ¹⁷O‐rich water. The abundance of matrix in RCs relative to OCs, ensured that these rocks would be apparently more oxidized and appreciably ¹⁷O‐enriched. In situ analysis of Dhofar 1671 is recommended to further strengthen the link between OCs and RCs.     

Flood vulnerability and buildings’ flood exposure assessment in a densely urbanised city: comparative analysis of three scenarios using a neural network approach

Natural Hazards - Advances in the availability of multi-sensor, remote sensing-derived datasets, and machine learning algorithms can now provide an unprecedented possibility to predict flood events...     

Response of microbial community to petroleum stress and phosphate dosage in sediments of Jiaozhou Bay,China

The dynamic microcosms were used to evaluate the effect of oil spills on microbial ecological system in marine sediment and the enhancement of nutrient on the oil removal. The function and structure of microbial community caused by the oil pollution and phosphate dosage were simultaneously monitored by dehydrogenase activity assay and PCR-denaturing gradient gel electrophoresis (DGGE) techniques. The results indicated that the amount of total bacteria in all dynamic microcosms declined rapidly with incubation time. The number of petroleum-degrading bacteria and the activity of sediment dehydrogenase were gradually enhanced by petroleum in the oil-treated microcosms, while they both showed no obvious response to phosphate dosage. In comparison, phosphate spiked heterotrophic bacteria and they showed a significant increase in amount. DGGE profiles indicated that petroleum dosage greatly changed community structure, and the bacteria belonged to class Deltaproteobacteria, and phyla Bacteroidetes and Chlorobi were enriched. This study demonstrated that petroleum input greatly impacted the microbial community structure and consequently the marine sediment petroleum-degrading activity was enhanced. Phosphate dosage would multiply heterotrophic bacteria but not significantly enhance the petroleum degradation.     

Passive earth pressure on embedded vertical plate anchors in sand

Passive earth pressure on embedded anchor plates constitutes a viable resisting force for the design of underground structures. In the current practice, these forces are empirically calculated, ignoring the effects of the depth of embedment and the level of consolidation of the surrounding soil, which takes place during plate installation on the in situ stress levels. Accordingly, wide discrepancies between predicted and measured pullout capacities of these plates were reported in the literature. Numerical model was developed using finite-element technique and the constitutive law of Mohr?CCoulomb to simulate the case of a retaining wall partially supported by an embedded anchor plate in sand. The results produced in this investigation showed that the passive earth pressure acting on anchor plates increases due to the increase of angle of shearing resistance and the overconsolidation ratio of sand, and it decreases due to an increase of the embedment depth of anchor. Design theories were developed for the case of embedded anchor plate in overconsolidated sand. The theories developed will satisfy the design needed in terms of allowable pullout load and/or displacement.     

New triple oxygen isotope data of bulk and separated fractions from SNC meteorites: Evidence for mantle homogeneity of Mars

We report precise triple oxygen isotope data of bulk materials and separated fractions of several Shergotty–Nakhla–Chassigny (SNC) meteorites using enhanced laser‐assisted fluorination technique. This study shows that SNCs have remarkably identical Δ¹⁷O and a narrow range in δ¹⁸O values suggesting that these meteorites have assimilated negligibly small surface materials (<5%), which is undetectable in the oxygen isotope compositions reported here. Also, fractionation factors in coexisting silicate mineral pairs (px‐ol and mask‐ol) further demonstrate isotopic equilibrium at magmatic temperatures. We present a mass‐dependent fractionation line for bulk materials with a slope of 0.526 ± 0.016 (1SE) comparable to the slope obtained in an earlier study (0.526 ± 0.013; Franchi et al. 1999). We also present a new Martian fractionation line for SNCs constructed from separated fractions (i.e., pyroxene, olivine, and maskelynite) with a slope of 0.532 ± 0.009 (1SE). The identical fractionation lines run above and parallel to our terrestrial fractionation line with Δ¹⁷O = 0.318 ± 0.016‰ (SD) for bulk materials and 0.316 ± 0.009‰ (SD) for separated fractions. The conformity in slopes and Δ¹⁷O between bulk materials and separated fractions confirm oxygen isotope homogeneity in the Martian mantle though recent studies suggest that the Martian lithosphere may potentially have multiple oxygen isotope reservoirs.     

Gendering Climate Change: Geographical Insights

Although climate change is expected to increase vulnerabilities, marginalization, and sufferings of many in the Global South, impacts will be unevenly felt across social strata. Intersectionalities of social difference, especially along gender and class lines, differentiate the ways in which impacts of climate change are experienced and responded to. Feminist political ecology and feminist geography insights can explain how different groups of people understand, respond to, and cope with variability and uncertainties in nuanced and critical ways, thereby elucidating the gendered implications of climate change. With a regional focus on South Asia, the article underscores the key issues that can be applied geographically elsewhere. Gendered implications of climate change in South Asia are particularly poignant as patriarchal norms, inequities, and inequalities often place women and men in differentiated positions in their abilities to respond to and cope with dramatic changes in socioecological relations but also foreground the complex ways in which social power relations operate in communal responses to adaptation strategies. This is particularly evident in water-related productive and reproductive tasks in agrarian societies that constitute the majority of South Asia. As climate change is expected to exacerbate both ecological degradation (e.g., water shortages) and water-related natural hazards (e.g., floods, cyclones), thereby transforming gender–water geographies, it becomes imperative to undertake careful multiscalar and critical analyses to better inform policymaking. This article elucidates the complex ways that climate change will affect gender and social relations, thereby highlighting the ways that existing policy narratives and adaptation programs might be better informed by geographical insights. To this end, the article encourages feminist and critical geographers to more forcefully and fruitfully engage with global debates on climate change.     

Chemical changes in fluid composition due to CO2 injection in the Altmark gas field: preliminary results from batch experiments

Dissolution?Cprecipitation phenomena induced by CO₂ injection to Altmark Permian sandstone were observed through laboratory experiments carried out under simulated reservoir conditions (125?°C and 50 bars of pressure). The rock sample was collected from the Altmark gas reservoir, which is being considered for enhanced gas recovery. Two sets of experiments were performed with pulverized rock samples in a closed batch reactor with either pure water (run 1) or 3?M aqueous NaCl solution (run 2) and reacted with injected CO₂ for 3, 5, and 9?days. The liquid samples were analyzed by inductively coupled plasma optical emission spectroscopy and total reflection X-ray fluorescence, where the latter proved to be a feasible alternative to conventional analytical techniques, especially since only small sample volumes (about 10???l) are needed. Chemical analysis for both fluids (water and NaCl brine) indicated a significant dissolution of calcite and anhydrite in the solution, which might be a crucial process during CO₂ injection. The brine solution enhanced the dissolution of calcite and anhydrite compared to pure water at the beginning of the reaction. Moreover, the progressive higher Si⁴⁺/Al³⁺ molar ratios (in average by a factor of 3) in the brine experiments indicated quartz dissolution. Thermodynamic calculations of mineral saturation indices highlighted the dissolution of the Ca-bearing minerals, which was in agreement with experimental results. Modeling enabled an evaluation of the dissolution processes of minerals in a low-salinity region, yet hindrances to model more saline conditions emphasize the need for further laboratory studies in order to parameterize models for deep aquifer conditions.     

Suffering for water, suffering from water: Emotional geographies of resource access, control and conflict

This article argues that resource access, use, control, ownership and conflict are not only mediated through social relations of power, but also through emotional geographies where gendered subjectivities and embodied emotions constitute how nature-society relations are lived and experienced on a daily basis. By engaging the insights from feminist political ecology literatures and emotional geographies literatures, the article demonstrates that resource struggles and conflicts are not just material challenges but emotional ones, which are mediated through bodies, spaces and emotions. Such a focus fleshes out the complexities, entanglements and messy relations that constitute political ecologies of resources management, where practices and processes are negotiated through constructions of gender, embodiments, and emotions. Abstractions of ‘resource struggles’ and ‘resource conflicts’ are thereby grounded in embodied emotional geographies of places, peoples, and resources, enabling us to better understand the ways resources and emotions come to matter in everyday survival struggles. This framing can enrich feminist political ecology theorizations and texture our understandings of commonly-used terms such as access, use, control, conflict and struggles vis-à-vis natural resources in any context. In other words, we are better able to conceptualize and explain how and why people access, use, and struggle over resources the ways they do. A case study of drinking water contamination from Bangladesh is used to develop the theoretical arguments in contributing to existing debates in (feminist) political ecologies.     

Efficiently implementable algebra for distributed in-network spatial analysis

Existing sensor network query processors (SNQPs) have demonstrated that in-network processing is an effective and efficient means of interacting with wireless sensor networks (WSNs) for data collection tasks. Inspired by these findings, this article investigates the question as to whether spatial analysis over WSNs can be built upon established distributed query processing techniques, but, here, emphasis is on the spatial aspects of sensed data, which are not adequately addressed in the existing SNQPs. By spatial analysis, we mean the ability to detect topological relationships between spatially referenced entities (e.g. whether mist intersects a vineyard or is disjoint from it) and to derive representations grounded on such relationships (e.g. the geometrical extent of that part of a vineyard that is covered by mist). To support the efficient representation, querying and manipulation of spatial data, we use an algebraic approach. We revisit a previously proposed centralized spatial algebra comprising a set of spatial data types and a comprehensive collection of operations. We have redefined and re-conceptualized the algebra for distributed evaluation and shown that it can be efficiently implemented for in-network execution. This article provides rigorous, formal definitions of the spatial data types, points, lines and regions, together with spatial-valued and topological operations over them. The article shows how the algebra can be used to characterize complex and expressive topological relationships between spatial entities and spatial phenomena that, due to their dynamic, evolving nature, cannot be represented a priori.     

The oxygen isotope compositions of olivine in main group (MG) pallasites: New measurements by adopting an improved laser fluorination approach

Oxygen isotope measurements of olivine in main group (MG) pallasites by traditional laser fluorination method are associated with some uncertainties including terrestrial weathering, incomplete olivine reaction, and sample state. We improved our laser fluorination approach by pretreating olivine grains with acid to remove terrestrial weathering products and by modifying the sample holder for an efficient and complete laser reaction. Our experiments on Brahin olivine demonstrate that acid-washing successfully removes the terrestrial weathering with <0.1‰ variation in δ¹⁸O value and, at the same time, improving the ∆¹⁷O value significantly. We also achieved a complete olivine fluorination by employing a custom-designed sample holder with “V”-shaped profile having rounded bottom because incomplete/partial reaction of olivine gives comparatively lighter δ¹⁸O values. Using these new techniques, we present precise triple oxygen isotope data (N = 72) of 25 olivine samples separated from main group pallasites. The data are, on average, ~0.5‰ heavier in δ¹⁸O relative to the values published in the literature for the same samples. Critically, the ∆¹⁷O values of MG pallasites and to some extent their Fo-contents suggest that there are at least two populations of olivine. Based on our improved data set, we propose that MG pallasites potentially have high-∆¹⁷O- and low-∆¹⁷O-bearing subgroups that are statistically distinct. The subgroups present average ∆¹⁷O values of −0.166 ± 0.003 (2SE; N = 16) and −0.220 ± 0.003 (2SE; N = 9), respectively. Furthermore, the high-∆¹⁷O-bearing subgroup samples trend toward lower Fo-contents compared to the other subgroup. Taken together, our data provide evidence that argues against a single parent body origin for MG pallasites.