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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff 下载免费PDF全文
We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
The effects of natural fish oil,DHA oil and soybean lecithin in microparticulate diets on stress tolerance of larval gilthead seabream(Sparus aurata)were investigated after 15 days feeding trials.The tolerance of larval gilthead seabream to various stress factors such as exposure to air(lack of dissolved oxygen),changes in water temperature(low)and salinity(high) were determined.This study showed that microparticulate diet with natural fish oil and soybean lecithin was the most effective for in-creasing the tolerance of larval gilthead seabream to various stresses,and that microparticulate diet with natural fish oil and palmitic acid(16:0)was more effective than microparticulate diet with DHA oil and soybean lecithin. 相似文献
3.
Xie Rui-xiang Wang Min Shi Shuo-biao Xu Chun Li Wei-hua Yan Yi-hua 《Chinese Astronomy and Astrophysics》2003,27(4):426-434
Using the decimetric (700–1500 MHz) radio spectrometer and the synchronous observational system with high temporal resolution at four frequencies (1420, 2130, 2840 and 4260 MHz) of Yunnan Observatory, two rare events were observed on 2001 June 24 and 1990 July 30. The former was a small radio burst exhibiting pulsations with short periods (about 29, 40 and 100 ms) in the impulsive phase. The latter was a large radio burst, which at 2840 MHz produced radio pulsations with period of about 30 ms. This paper focuses on pulsations with very short periods in the range of 29–40 ms. The mechanism of generation of such pulsations may be modulation of radio radiation by the periodic trains of whistler packets originating in unstable regions of the corona. Alternatively, these pulsations can be attributed to wave-wave non-linear interactions of electrostatic upper hybrid waves driven by beams of precipitating electrons in flaring loops. 相似文献
4.
The characteristics of Asian dust events in Northeast Asia during the springtime from 1993 to 2004 总被引:3,自引:1,他引:2
The characteristics of Asian dust events that occurred in Northeast Asia during the springtime from 1993 to 2004 are investigated using 3-hourly SYNOP reports (World Meteorological Organization). Occurrences of blowing sand and dust storm are low in 1997 and 1999, but have increased rapidly since 2000. The maximum occurrence was recorded in 2002. Wind velocity of 6.5 m s− 1 as a threshold wind velocity is not so exactly consistent with the occurrence of blowing sand. However, wind velocity of 14 m s− 1 as a strong wind causing dust storm had similar tendency to those of dust storm and Dust Storm Index.Source regions of Asian dust are divided into three regions (A: dry arid, B: semi-arid, and C: cultivated), based upon the occurrence of blowing sand and dust storm. Eight meteorological stations are selected in three regions, which have frequent occurrences of blowing sand. Source regions of Asian dust that affect the Korean peninsula are gradually extending eastward. Positive anomalies of NDVI occurred in 1994, 1995, and 1998 when temperature was high and precipitation was heavy. However, the frequent occurrence of the dust phenomena is not always consistent with lots of vegetation, high temperature, and much precipitation in this study. 相似文献
5.
对CPLD(复杂可编程逻辑器件)技术的基本特征和发展趋势作了简要介绍,揭示了该技术在现代数字系统中的重要地位及作用.利用CPLD对时统设备IRIG-B码产生器进行集成,其实验结果表明,集成了的B码产生器不但简单、可靠,而且便于调试,克服了以往硬件电路复杂的缺点. 相似文献
6.
Pco2 of air and seawater samples from the East China Sea(ECS) were measured in situ in autumn, 1994,Ocean currents,terrestrial fluviation,biological activities,etc.,Pco2 char-acters in air and seawater were investigated,CO2 flux and its character in the East China Sea are discussed on the basis of the Pco2 profiles of air and seawater,It was clear that the nearshore was the source of CO2;and tht the oulter sea area was the sink of CO2; and that the shelf area of the EXS is a net sink for atmospheric CO2 in autumn. 相似文献
7.
SORPTION AND DESORPTION CHARACTERISTICS OF CADMIUM BY FOUR DIFFERENT SOILS IN NORTHEAST CHINA 总被引:3,自引:0,他引:3
ZHANG Lei SONG Feng-bin 《中国地理科学(英文版)》2005,15(4):343-347
1IN TR O D U C TIO NA s a persistentand toxic pollutant, cadm ium (C d) canresultin m any adverse health effects in a variety oftis-suesand organssuch asthe lung,kidney,urinary,blad-der,pancreas,breast and prostate (SA TA R U G etal.,2003).C adm ium in so… 相似文献
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10.
APPLICATION OF GEOGRAPHICAL PARAMETER DATABASE TO ESTABLISHMENT OF UNIT POPULATION DATABASE 总被引:1,自引:1,他引:0
Now GIS is turning into a good tool in handling geographical, economical, and population data, so we can obtain more and more information from these data. On the other hand, in some cases, for a calamity, such as hurricane, earthquake, flood, drought etc., or a decision-making, such as setting up a broadcasting transmitter, building a chemical plant etc., we have to evaluate the total population in the region influenced by a calamity or a project. In this paper, a method is put forward to evaluate the population in such special region. Through exploring the correlation of geographical parameters and the distribution of people in the same region by means of quantitative analysis and qualitative analysis, unit population database (1km× 1km) is established. In this way, estimating the number of people in a special region is capable by adding up the population in every grid involved in this region boundary. The geographical parameters are obtained from topographic database and DEM database on the scale of 相似文献