Mineralogical sources of the buffer capacity in a granite catchment determined by strontium isotopes

The role of different minerals in base cation release and thus the increase of buffering capacity of groundwater against acid deposition is controversially discussed in the literature. The ⁸⁷Sr/⁸⁶Sr ratios and base cation concentration were investigated in whole rock leachates, mineral separates, precipitation, soil solution, groundwater and stream water samples in the Lehstenbach catchment (Germany) to identify the weathering sequence of the granite bedrock. Three different approaches were followed in parallel. It was assumed that the contribution of different minerals to base cation supply of the groundwater with increasing weathering intensity would be observed by investigating (1) unweathered rock leachates, deep groundwater and shallow groundwater, (2) groundwater samples from new groundwater wells, reflecting the initial weathering of the drilled bedrock, and groundwater from wells that were drilled in 1988, (3) stream water during baseflow, dominated by deep groundwater, and stream water during high flow, being predominantly shallow groundwater. Whereas the first approach yielded consistent patterns, there was some evidence that groundwater from the new wells initially reflected contamination by the filter gravel rather than cation release in an initial stage of weathering. Time series samples of stream water and groundwater solute concentrations and isotope ratios turned out to reflect varying fractions of soil water and precipitation water at baseflow and high flow conditions rather than varying contributions of different minerals that prevail at different stages of granite weathering.     

On the geologic structure of the Explora Escarpment (Weddell Sea,Antarctica) revealed by satellite and Shipboard data evaluation

Bathymetric, gravity, and magnetic data from Antarctic expeditions with RV POLARSTERN and satellite altimeter data from the Geosat Geodetic Mission are analysed using methods from geostatistics and geophysical inverse theory.The Explora Escarpment represents the edge between the Antarctic Continental Shelf and the Weddell Abyssal Plain. It is an important link in the reconstruction of Gondwana breakup, but a feature as large as the 2000 m deep Wegener Canyon was only discovered in 1984, when extensive bathymetric, gravimetric, and magnetic surveys with RV POLARSTERN began.Geostatistics, the theory of regionalized variables, is applied to integrate dense surveys of Wegener Canyon and sparse observations in adjacent areas into maps with full coverage of the 230 km by 330 km area at 10°–20° W/70°–72° S. The resultant highresolution bathymetric and gravity maps reveal detailed structures of the Explora Escarpment. Using geophysical inversion, the gravity terrain effect is calculated. Satellite data are used for their better coverage, but have much lower resolution. Nevertheless, the structures of Wegener Canyon and other more prominent features appear with surprisingly good correlation also in the Geosat altimeter data. While it was initially supposed that Wegener Canyon is purely an erosional structure, the magnetic map now provides evidence of the canyon's tectonic origin.     

Detection of DNA damage in mussels and sea urchins exposed to crude oil using comet assay

The single-cell microgel electrophoresis assay or the comet assay was used to evaluate DNA damage of dispersed crude oil on sea urchins (Strongylocentrotus droebachiensis) and mussels (Mytilus edulis L.). Sea urchins were exposed to 0.06 and 0.25 mg/L dispersed crude oil in a continuous flow system, while the mussels were exposed to 0.015, 0.06 and 0.25 mg/L dispersed crude oil. Sea urchin coelomocytes and mussel haemocytes were sampled after 4 and 5 weeks exposure, respectively. In the sea urchin coelomocytes, there was a significant concentration-related increase in the percentage of DNA in comet tail. In mussel haemocytes, there was a significantly higher percentage of DNA in comet tail for all treatments compared to the control. The responses were concentration-related up to 0.06 mg/L oil. The two highest exposure concentrations of mussels were not significantly different from each other. These results indicate that the comet assay can be used for biomonitoring of DNA damage in marine invertebrates following oil contamination.     

The deposit size frequency method for estimating undiscovered uranium deposits

The deposit size frequency (DSF) method has been developed as a generalization of the method that was used in the National Uranium Resource Evaluation (NURE) program to estimate the uranium endowment of the United States. The DSF method overcomes difficulties encountered during the NURE program when geologists were asked to provide subjective estimates of (1) the endowed fraction of an area judged favorable (factorF) for the occurrence of undiscovered uranium deposits and (2) the tons of endowed rock per unit area (factorT) within the endowed fraction of the favorable area. Because the magnitudes of factorsF andT were unfamiliar to nearly all of the geologists, most geologists responded by estimating the number of undiscovered deposits likely to occur within the favorable area and the average size of these deposits. The DSF method combines factorsF andT into a single factor (F·T) that represents the tons of endowed rock per unit area of the undiscovered deposits within the favorable area. FactorF·T, provided by the geologist, is the estimated number of undiscovered deposits per unit area in each of a number of specified deposit-size classes. The number of deposit-size classes and the size interval of each class are based on the data collected from the deposits in known (control) areas. The DSF method affords greater latitude in making subjective estimates than the NURE method and emphasizes more of the everyday experience of exploration geologists. Using the DSF method, new assessments have been made for the young, organic-rich surficial uranium deposits in Washington and idaho and for the solution-collapse breccia pipe uranium deposits in the Grand Canyon region in Arizona and adjacent Utah.     

Discrete element modelling of the influence of cover strength on basement-involved fault-propagation folding

A discrete element model is used to investigate the influence of sedimentary cover strength on the development of basement-involved fault-propagation folds. We find that uniformly weak cover best promotes the development of classical, trishear-like fault-related folds showing marked anticlinal thinning and synclinal thickening, with cover dips increasing downwards towards the fault tip. Uniformly strong cover results in more rounded fold forms with only minor hinge thickening/thinning and significant basement fault-propagation into the sedimentary cover. Heterogeneous, layered, cover sequences with marked differences in strength promote the development of more complex and variable fold forms, with a close juxtaposition of brittle and macroscopically ductile features, which diverge from the predictions of simple kinematic models. In these structures the upper layers are often poor indicators of deeper structure. In addition, we find that in layered cover sequences fault-propagation into the cover is a complex process and is strongly buffered by the weaker cover units.     

Continuous air rate measurement in flotation cells: Some fundamental considerations

A robust and reliable sensor to measure gas (air) superficial velocity (J_g) continuously in flotation systems is introduced. It is based on the sampling of bubbles by buoyancy with the accumulating air allowed to exit through an orifice. At steady state, pressure drop is measured and related to the J_g by prior calibration. The continuous device is readily automated and extended to a multi-unit set-up. The sensor and data collections are described. The governing gas flow equation and models of the dynamic response to air flow rate set point change and fluctuations in froth depth are derived. Model predictions are confirmed against plant data. By taking a moving average, the J_g remains valid in the face of typical plant disturbances.     

Strontium in coral aragonite: 2. Sr coordination and the long-term stability of coral environmental records

We have used X-ray Diffraction (XRD) and Sr K-edge Extended X-ray Absorption Fine Structure (EXAFS) to determine the structural state of Sr in a suite of coral aragonite samples. Our samples encompassed a selection of coral species (Porites lobata, Porites lutea, Pocillopora eydouxi, Montastrea annularis, Pavona gigantea and Pavona clavus) including some commonly used for palaeoenvironmental reconstruction. Aragonite was the only carbonate observed by XRD. We refined the isolated EXAFS against structural models for Sr in aragonite and two-phase strontianite/aragonite mixes. Our data are indistinguishable from Sr ideally substituted in aragonite and strontianite was present below detection levels (estimated at <5% of Sr present). Comparisons of recent and ancient coral aragonite show no sign of exsolution, either by spinodal decomposition or by the direct nucleation of strontianite domains. Published diffusion rates of Sr in ionic solids support the view that exsolution would occur prohibitively slowly. Coral aragonites are metastable materials with slow diffusion kinetics that have the potential to encode environments over timescales of millions of years.     

Geological implications of new biostratigraphic data from East and West Kalimantan, Indonesia

This paper presents palaeontological ages based on new nannofossil and foraminiferal studies from a range of sedimentary rocks from the provinces of West and East Kalimantan, Indonesia. The age of sedimentary rocks in Kalimantan, away from the main hydrocarbon exploration areas of the coastal regions, represents a major gap in our basic knowledge of the island of Borneo. The implications of these new results and existing and new correlations are reviewed and suggested. In particular, the base of the Tertiary section in the Kutai Basin is shown to be upper Middle Eocene in age, rather than Late Eocene as originally thought. The limestones of the Batu Belah member of the Ujoh Bilang Formation are dated as NP24–25, Late Oligocene, rather than Early Oligocene as earlier work had suggested. In the western part of the Mangkalihat Peninsula area the base of the Tertiary section is determined to be Late Oligocene. Various basement units from both East and West Kalimantan contained Late Jurassic to Late Cretaceous microfossils.     

Small-scale vegetation dynamics in semi-arid steppe in Inner Mongolia

Small-scale vegetation dynamics were followed for ecotones and in uniform stands inArtemisia-dominated steppe vegetation under grazing and when recovering from heavy grazing. Species composition was followed annually for 5 years in 1 m²and 0·25 m²plots for (1) presence–absence; (2) density; and (3) biomass.More rapid vegetation dynamics, in terms of change of type of vegetation and distance moved in DCA species space between sampling occasions, were observed in smaller plots and in early seral stages, where species were few and alpha diversity low. Only the plots recently protected from grazing showed a directional vegetation change; those protected for more than 3 years and those under continued grazing showed, at this scale, non-directional dynamics.