Studies of some diatomic molecules in the F- and early G-type dwarf stars

A critical analysis of CH, NH, OH, C₂, and CN molecules/radicals has been made in twenty-four F- and early G-type dwarfs at different effective temperature as well as in new constructed model atmosphere. Molecular indices of bandheads ofA-X system of CH, NH, OH, C₂, and CN have been obtained by using the data available in the literature (thirteen-colour and eight-colour photometry).Besides, some interesting plots of the molecular indices vs _eff, molecular abundances and molecular indices vs dissociation energy, reduced equivalent widths and FCF's vs dissociation energy for respective molecules have also been enumerated. It is found that the molecular indices at bandheads ofA-X system of CH, NH, OH, C₂, and CN are approximately constant (5810–6570 K). It is to be noted that the molecular indices decrease in the order OH, NH, CH, C₂, and CN at a given temperature.The dissociation equilibrium of CH, NH, OH, C₂, and CN is considered at 5810, 6570, and 7160 K phases in model atmosphere. At standard scale of abundance the molecular abundance and molecular index decrease in the order OH, NH, CH, C₂, and CN at any given phase, however, CN abundance and index increase (_eff=0.867-0.767). The amplitude of abundance and index variation decrease in the order NH, OH, CH, C₂, and CN (_eff=0.767-0.704).The reduced equivalent width decrease in the order OH, NH, CH, and C₂ and FCF's decrease in the order CH, OH, NH, CN, and C₂.The confrontation of models and observations of spectra of F- and early G-type dwarfs of parent molecules is of primary importance to investigate the physical conditions within atmospheres. Reliable excitation models are also requisite for interpreting spectroscopic observations of parent molecules and deriving molecular abundances.     

Some vibrational bands of theC-X system of V0 molecules in the umbral spectrum of the Sun

Vibrational transition probabilities namely Franck-Condon factors and r-centroids have been evaluated using an approximate analytical method for theC-X system of V0. Morse potential energy curves forX _{4 –} andC _{4 –} states of V0 have been constructed using the latest spectroscopic data. The value of r-centroids for the band have been found to increase linearly with the corresponding wavelength. We show results for new transition and ten new bands in the umbral spectrum of the Sun.     

YO molecule in the sun

Vibrational transition probabilities, namely Franck—Condon factors and -centroids have been evaluated by an approximate analytical method for the (A–X), (A–X), and (A–X) system of YO molecule. Morse potential energy curves forX ²⁺,A ²₂,A²₂, andA²₂, states of YO have been constructed using the latest spectroscopic data. The value of -centroids for the band have been found to decrease linearly with the corresponding wavelengths. We show results for two new transitions of (A–X) and (A–X) and five new bands of (A–X) of YO in the umbral spectrum of the Sun.     

Morse pe-curves of AlH

Morse potential energy curves forC ¹⁺ andC ¹⁺ of AlH have been constructed. The energy values have been found to increase from vibrational levels 0 to 6 and decrease from vibrational levels 7 to 50 with the corresponding centre and half-width in the stateC ¹⁺. InC ¹⁺ state the energy values have been found to increase from vibrational levels 0 to 28 and decrease from vibrational levels 29 to 50 with the corresponding centre and half-width.     

Modelling long-term HFC emissions from India's residential air-conditioning sector: exploring implications of alternative refrigerants,best practices,and a sustainable lifestyle within an integrated assessment modelling framework

India's growing role in the global climate debate makes it imperative to analyse emission reduction policies and strategies across a range of GHGs, especially for under-researched non-CO₂ gases. Hydrofluorocarbons' (HFCs) usage in cooling equipment and subsequent emissions are expected to increase dramatically in India with the phase-out of hydrochlorofluorocarbons (HCFCs) as coolants in air-conditioning equipment. We focus on the residential air-conditioning sector in India and analyse a suite of HFC and alternative coolant gas scenarios for understanding the implications for GHG emissions from this sector within an integrated assessment modelling framework. We find that, if unabated, HFC410A emissions will contribute to 36% of the total global warming impact from the residential air-conditioner sector in India in 2050, irrespective of the future economic growth trajectory, and the remaining 64% is from energy to power residential air-conditioners. A move towards more efficient, low global warming potential (GWP) alternative refrigerants will significantly reduce the cumulative global warming footprint of this sector by 37% during the period 2010–2050, due to gains both from energy efficiency as well as low GWP alternatives. Best practices for reducing direct emissions are important, but only of limited utility, and if a sustainable lifestyle is adopted by consumers with lower floorspace, low GWP refrigerants, and higher building envelope efficiencies, cumulative emissions during 2010–2050 can be reduced by 46% compared to the Reference scenario.

Policy relevance

Our analysis has important implications for Indian climate policy. We highlight that the Indian government's amendment proposal to the Montreal Protocol is a strong signal to the Indian market that the transition away from high GWP refrigerants towards low/zero GWP alternatives will happen sooner or later. The Bureau of Energy Efficiency should extend building energy conservation code policy to residential buildings immediately, and the government should mandate it. Government authorities should set guidelines and mandate reporting of data related to air-conditioner coolant recharge frequency and recovery of scrapped air-conditioner units. For contentious issues like flammability where there is no consensus within the industry, the government needs to undertake an independent technical assessment that can provide unbiased and reliable information to the market.     

Construction and Characterization of Transportable Calibration Pads for Calibration of Portable and Airborne Gamma Ray Spectrometers in India

Characterization of the Panandhro lignite deposits from western Indian state of Gujarat, based on the geochemical and palynological evidences, has been performed to assess the floral composition, maturity and hydrocarbon potential of the sequence. Elementally, the lignites consist of moderate carbon, low hydrogen and moderate sulfur contents. The samples are characterized by high TOC contents (lignite: av. 46.43 wt.%, resin: 62.47 wt.%). The average HI values for the lignite is 136 mg HC/g TOC, and that of the associated resin is 671 mg HC/g TOC. The highest T_max is recoded in lignite (422°C) and lowest in the resin (39°C) samples. The FTIR spectrum of lignite is characterized by highly intense OH stretching peak ~3350 cm^-1, aliphatic CH_x stretching peaks between 3000-2800 cm^-1, aromatic C=O stretching and an aromatic C=C stretching. The spectrum of resin shows strongest absorption due to aliphatic CHx stretching between 2940-2915 cm^-1 and 2870-2850 cm^-1, and deformation by the medium peak between 1450 and 1650 cm^-1. The recovered palynofloral assemblage indicates the dominance of angiosperm pollen grains with maximum abundance of Arecaceae family, and subdominant pteridophytic spores. Marine influence is indicated by the presence of abundant dinoflagellate cysts. The occurrence of flora from a variety of ecological niches suggests a luxuriant diverse vegetation pattern existed in the vicinity of depositional site under humid tropical conditions. The overall characteristics of the lignite deposits point towards their ability to generate (upon maturation) hydrocarbons as they have types III–II admixed kerogen (organic matters).     

Calibration of AGRS System Using Transportable Pads in India: An Application to AGRS Data of Aravalli Basin,Banswada Block,South Rajasthan

Calibration of airborne gamma ray spectrometric system (AGRS) over standard radioactive sources of known elemental abundances is essential before carrying out airborne surveys. In India, fixed calibration pads were constructed in 1985. Since then calibration of AGRS system was carried out over the fixed pads. However the fixed pads are expensive to build and maintain. Also the large pads are subject to variations in radiation output due to variable moisture content and radon loss. Alternate approach is to construct transportable calibration pads which are discussed in this paper.Atomic Minerals Directorate for Exploration & Research (AMD) under Department of Atomic Energy has recently constructed five transportable calibration pads. Three pads i.e. K, U and Th have been spiked with the respective radioelements while keeping the minor radioelements to the least in order to obtain pure spectra. A composite pad has been constructed which contains all the three radioelements. This helps in cross verifying the obtained calibration results. A background pad has also been constructed which is helpful to obtain the background values during calibration.Analysis of the data acquired over the transportable pads with airborne gamma ray spectrometer (16.8 ltr) has been carried out and presented in this paper. A comparison with the data acquired over the fixed calibration pads is also included. There is a good agreement of results which suggests the use of transportable pads in future.     

Influence of climatic teleconnections on the temporal isotopic variability as recorded in a firn core from the coastal Dronning Maud Land,East Antarctica

Ice and firn core studies provide one of the most valuable tools for understanding the past climate change. In order to evaluate the temporal isotopic variability recorded in ice and its relevance to environmental changes, stable isotopes of oxygen and hydrogen were studied in a firn core from coastal Dronning Maud Land, East Antarctica. The annual δ ¹⁸O profile of the core shows a close relation to the El Niño Southern Oscillation (ENSO) variability. The ENSO indices show significant correlation with the surface air temperatures and δ ¹⁸O values of this region during the austral summer season and support an additional influence related to the Southern Annular Mode (SAM). The correlation between the combined ENSO-SAM index and the summer δ ¹⁸O record seems to have been caused through an atmospheric mechanism. Snow accumulation in this region illustrates a decreasing trend with opposite relationships with δ ¹⁸O data and surface air temperature prior and subsequent to the year 1997. A reorganization of the local water cycle is further indicated by the deuterium excess data showing a shift around 1997, consistent with a change in evaporation conditions. The present study thus illustrates the utility of ice-core studies in the reconstruction of past climate change and suggests possible influence of climatic teleconnections on the snow accumulation rates and isotopic profiles of snow in the coastal regions of east Antarctica.     

Root structure,distribution and biomass in five multipurpose tree species of Western Himalayas

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The tree root distribution pattern and biomass of seventeen year old trees of Grewia optiva, Morus alba, Celtis australis, Bauhinia variegata and Robinia pseudoacacia were studied by excavation method. B. variegata roots penetrated to a maximum depth of 4.78 m, whereas, M. alba roots were found down to 1.48 m depth. Lateral spread was minimum in B. variegata （1.10 m）and maximum inR. pseudoacacia （7.33 m）. Maximum root biomass of 6.30 kg was found in R. pseudoacacia and minimum （2.43 kg） was found in M. alba. For four species viz.,G. optiva, M. alba, C. australis andR. pseudoacacia, 68%-87% root biomass occurred within top 0-30 cm soil depth, but forB. variegata this was only45%. The soil binding factor was maximum in G. optiva and minimum in B. variegata. Soil physico-chemical properties also showed wide variation. The study suggests thatB. variegata with a deep root system is the most suitable species for plantation under agroforestry systems. R. pseudoacacia and G. optiva with deep root systems, more lateral spread and high soil binding factor are suitable for plantation on degraded lands for soil conservation.     

Hydrogeochemistry of coal mine water of North Karanpura coalfields,India: implication for solute acquisition processes,dissolved fluxes and water quality assessment

Mine water samples collected from different mines of the North Karanpura coalfields were analysed for pH, electrical conductivity, total dissolved solids (TDS), total hardness (TH), major anions, cations and trace metals to evaluate mine water geochemistry and assess solute acquisition processes, dissolved fluxes and its suitability for domestic, industrial and irrigation uses. Mine water samples are mildly acidic to alkaline in nature. The TDS ranged from 185 to 1343 mg L^?1 with an average of 601 mg L^?1. Ca²⁺ and Mg²⁺ are the dominant cations, while SO₄ ^2? and HCO₃ ^? are the dominant anions. A high concentration of SO₄ ^2? and a low HCO₃ ^?/(HCO₃ ^? + SO₄ ^2?) ratio (<0.50) in the majority of the water samples suggest that either sulphide oxidation or reactions involving both carbonic acid weathering and sulphide oxidation control solute acquisition processes. The mine water is undersaturated with respect to gypsum, halite, anhydrite, fluorite, aluminium hydroxide, alunite, amorphous silica and oversaturated with respect to goethite, ferrihydrite, quartz. About 40% of the mine water samples are oversaturated with respect to calcite, dolomite and jarosite. The water quality assessment shows that the coal mine water is not suitable for direct use for drinking and domestic purposes and needs treatment before such utilization. TDS, TH, F^?, SO₄ ^2?, Fe, Mn, Ni and Al are identified as the major objectionable parameters in these waters for drinking. The coal mine water is of good to suitable category for irrigation use. The mines of North Karanpura coalfield annually discharge 22.35 × 10⁶ m³ of water and 18.50 × 10³ tonnes of solute loads into nearby waterways.