The P-T-fO 2 stability of deerite,Fe 12 2+ Fe 6 3+ [Si12O40](OH)10

New equilibrium experiments have been performed in the 20–27 kbar range to determine the upper thermal stability limit of endmember deerite, Fe ₁₂ ²⁺ Fe ₆ ³⁺ [Si₁₂O₄₀](OH)₁₀. In this pressure range, the maximum thermal stability limit is represented by the oxygen-conserving reaction: deerite(De)=9 ferrosilite(Fs)+3 magnetite(Mag)+3 quartz(Qtz)+5 H₂O(W) (1). Under the oxygen fugacities of the Ni-NiO buffer the breakdown-reduction reaction: De=12 Fs+2 Mag+5 W+1/2 O₂ (10) takes place at lower temperatures (e.g. T=63° at 27 kbar). The experimental brackets can be fitted using thermodynamic data for ferrosilite, magnetite and quartz from Berman (1988) and the following 1 bar, 298 K data for deerite (per gfw): V^o=55.74 J.bar^-1, S^o=1670 J.K^-1, H _f ^o =-18334 kJ, =2.5x10^-5K^-1, =-0.18x10^-5 bar^-1. Using these data in conjunction with literature data on coesite, grunerite, minnesotaite, and greenalite, the P-T stability field of endmember deerite has been calculated for P _s=P _{H 2}O. This field is limited by 6 univariant oxygenconserving dehydration curves, from which three have positive dP/dT slopes, the other three negative slopes. The lower pressure end of the stability field of endmember deerite is thus located at an invariant point at 250±70°C and 10+-1.5 kbar. Deerite rich in the endmember can thus appear only in environments with geothermal gradients lower than 10°C/km and at pressures higher than about 10 kbar, which is in agreement with 4 out of 5 independent P-T estimates for known occurrences. The presence of such deerite places good constraints on minimum pressure and maximum temperature conditions. From log f _{O 2}-T diagrams constructed with the same data base at different pressures, it appears that endmember deerite is, at temperatures near those of its upper stability limit, stable only over a narrow range of oxygen fugacities within the magnetite field. With decreasing temperatures, deerite becomes stable towards slightly higher oxygen fugacities but reaches the hematite field only at temperatures more than 200°C lower than the upper stability limit. This practically precludes the coexistence deerite-hematite with near-endmember deerite in natural environments.     

Feasibility study of a multiple flyby mission of main belt asteroids

Specific information on the surface morphology, composition, mean density, and internal structure of asteroids, which is necessary to advance our understanding of asteroids, can be obtained only by a detailed investigation of individual bodies: this will require space missions to individual targets. Since an essential characteristic of the asteroids is their variety, several objects must be visited. The Ariane launcher developed presently in Europe makes a multiple flyby mission possible. The first results of our feasibility study are particularly encouraging: during one revolution, five to six preselected main belt asteroids may be approached to within 1000 km with relative velocities which lie between 3 and 14 km/sec using a total impulse correction on the order of 1 to 2 km/sec. The weight of the spacecraft, excluding the engine and the propellant, would be at least 250 kg. This allows a scientific payload of 50 to 60 kg, in which priority will be given to an imaging system and radar altimeter.     

The role of boundary organizations in climate change adaptation from the perspective of municipal practitioners

In climate change impact research it is crucial to carefully select the meteorological input for impact models. We present a method for model selection that enables the user to shrink the ensemble to a few representative members, conserving the model spread and accounting for model similarity. This is done in three steps: First, using principal component analysis for a multitude of meteorological parameters, to find common patterns of climate change within the multi-model ensemble. Second, detecting model similarities with regard to these multivariate patterns using cluster analysis. And third, sampling models from each cluster, to generate a subset of representative simulations. We present an application based on the ENSEMBLES regional multi-model ensemble with the aim to provide input for a variety of climate impact studies. We find that the two most dominant patterns of climate change relate to temperature and humidity patterns. The ensemble can be reduced from 25 to 5 simulations while still maintaining its essential characteristics. Having such a representative subset of simulations reduces computational costs for climate impact modeling and enhances the quality of the ensemble at the same time, as it prevents double-counting of dependent simulations that would lead to biased statistics.     

Analysis of Cassini/CIRS limb spectra of Titan acquired during the nominal mission II: Aerosol extinction profiles in the 600–1420 cm spectral range

We have analyzed the continuum emission of limb spectra acquired by the Cassini/CIRS infrared spectrometer in order to derive information on haze extinction in the 3–0.02 mbar range (∼150–350 km). We focused on the 600–1420 cm⁻¹ spectral range and studied nine different limb observations acquired during the Cassini nominal mission at 55°S, 20°S, 5°N, 30°N, 40°N, 45°N, 55°N, 70°N and 80°N. By means of an inversion algorithm solving the radiative transfer equation, we derived the vertical profiles of haze extinction coefficients from 17 spectral ranges of 20-cm⁻¹ wide at each of the nine latitudes. At a given latitude, all extinction vertical profiles retrieved from various spectral intervals between 600 and 1120 cm⁻¹ display similar vertical slopes implying similar spectral characteristics of the material at all altitudes. We calculated a mean vertical extinction profile for each latitude and derived the ratio of the haze scale height (H_haze) to the pressure scale height (H_gas) as a function of altitude. We inferred H_haze/H_gas values varying from 0.8 to 2.4. The aerosol scale height varies with altitude and also with latitude. Overall, the haze extinction does not show strong latitudinal variations but, at 1 mbar, an increase by a factor of 1.5 is observed at the north pole compared to high southern latitudes. The vertical optical depths at 0.5 and 1.7 mbar increase from 55°S to 5°N, remain constant between 5°N and 30°N and display little variation at higher latitudes, except the presence of a slight local maximum at 45°N. The spectral dependence of the haze vertical optical depth is uniform with latitude and displays three main spectral features centered at 630 cm⁻¹, 745 cm⁻¹ and 1390 cm⁻¹, the latter showing a wide tail extending down to ∼1000 cm⁻¹. From 600 to 750 cm⁻¹, the optical depth increases by a factor of 3 in contrast with the absorbance of laboratory tholins, which is generally constant. We derived the mass mixing ratio profiles of haze at the nine latitudes. Below the 0.4-mbar level all mass mixing ratio profiles increase with height. Above this pressure level, the profiles at 40°N, 45°N, 55°N, at the edge of the polar vortex, display a decrease-with-height whereas the other profiles increase. The global increase with height of the haze mass mixing ratio suggest a source at high altitudes and a sink at low altitudes. An enrichment of haze is observed at 0.1 mbar around the equator, which could be due to a more efficient photochemistry because of the strongest insolation there or an accumulation of haze due to a balance between sedimentation and upward vertical drag.     

Outsider and insider views of Saigon/Ho Chi Minh City: The Lover/L'Amant, Cyclo/Xích lô, Collective Flat/Chung c and Bargirls/Gái nh y

This article addresses representations of Saigon/Ho Chi Minh City in four films made since đ     i m     i , the opening up of Vietnam to western influences, initiated in 1986. The Lover/L'Amant (1992) is a Franco-British heritage film which reconstructs the city from a Eurocentric neocolonial perspective, while Cyclo/Xích lô (1995), a French-funded film made by a France-based Vietnamese filmmaker, is a contemporary poetic thriller which treats the city expressively as the site of present-day corruption and violence. The nostalgia evident in these two 'outsider' films is contrasted with the more complex views of the city in two state-funded low-budget 'insider' films by local Vietnamese filmmakers, Collective Flat/Chung c     (1999) and Bargirls/Gái nh     y (2003); the first, an intellectual fable set in the decade or so following reunification/Independence in 1975 which recalls an attempt at collective living, the second, a hugely popular treatment of contemporary urban realities, both corrupt and progressive. Examining how the mise-en-scène and narratives of the city differ from film to film, the essay takes the representation of the city through changing historical, political, social and economic times, from colonial-orientalist Saigon to corrupt, capitalist Ho Chi Minh City via the slow degeneration of the postwar socialist/collectivist experiment. In so doing, it confirms the importance of the films' moments and contexts of production in the construction of Saigon/Ho Chi Minh City as a cinematic 'city-text'.     

Magnitude and frequency of grain flows on a desert sand dune

Preliminary studies of the magnitude and frequency of lee side avalanches (grain flows) on a Namib crescentic dune show that the frequency of grain flows for a given segment of the lee face is dependent on the wind speed and sand transport rate for the period preceding their initiation; and the magnitude of the flows as described by their area is inversely proportional to the interval between flows and thus wind speed and sand transport rates. These studies indicate the potential of using a simple digital video camera technique to document the magnitude, frequency and geometry of grain flows on desert sand dunes.     

Determination of mercury biogeochemical fluxes in the remote Mackenzie River Basin,northwest Canada,using speciation of sulfur and organic carbon

The Mackenzie River Basin (MRB) in NW Canada is one of the least human-impacted large watersheds in the world. The western and eastern sub-basins of the MRB are also marked by contrasting geology, geomorphology, hydrology, and biology. These remarkable differences in a remote river basin provide a unique opportunity to probe the biogeochemical processes governing the sources, transport, and bioavailability of Hg at the terrestrial-marine interface and ultimately in the Arctic Ocean. Based on a large dataset of the concentration and speciation of Hg, S and organic matter in surface sediments across the MRB, a source-apportioned budget was constructed for Hg in the MRB. The results indicate that the Hg flux in the basin originates primarily from the weathering of sulfide minerals in the western mountainous sub-basin (∼78% of the total), followed by the erosion of coal deposits along the mainstream of the Mackenzie River (∼10%), with the remainder split between atmospheric inputs and organic matter-bound Hg (6% and 5%, respectively). Although the Hg flux from the eastern peatland sub-basin only accounts for ∼10% of the total riverine Hg flux, Hg in this region correlates strongly with labile organic matter, and will likely have a much stronger influence on local biota.