Multiple Isotopic Components in Quaternary Volcanic Rocks of the Cascade Arc near Crater Lake, Oregon

Quaternary lavas and pyroclastic rocks of Mount Mazama, CraterLake caldera, and the surrounding area have variable Sr, Nd,and Pb isotopic compositions. High-alumina olivine tholeiites(HAOT) have ⁸⁷Sr/⁸⁶Sr ratios of 0.70346–0.70364; basalticandesite, 0–70349–0.70372; shoshonitic basalticandesite, 0.70374–0.70388; and andesite, 0.70324–0.70383.Dacites of Mount Mazama have ⁸⁷Sr/⁸⁶Sr ratios of 0.70348–0.70373.Most rhyodacites converge on 0.7037. However, rhyodacite ofthe caldera-forming, climactic eruption has ⁸⁷Sr/⁸⁶Sr=0.70354because of an admixed low-⁸⁷Sr/⁸⁶Sr component. Andesitic tomafic-cumulate scoriae of the climactic eruption, and enclavesin preclimactic rhyodacites, cluster in two groups but shownearly the entire ⁸⁷Sr/⁸⁶Sr range of the data set, confirmingpreviously suggested introduction of diverse parental magmasinto the growing climactic chamber. Pb and Nd isotope ratiosdisplay less variation (²⁰⁶Pb/²⁰⁴Pb= 18.838–18.967, ²⁰⁷Pb/²⁰⁴Pb=15.556–15.616,²⁰⁸Pb/²⁰⁴Pb=38.405–38.619; _Nd= +3.9 to +6.1) and generallycovary with ⁸⁷Sr/⁸⁶ Sr ratios. Radiogenic isotope data fromCrater Lake plot with published data for other Cascade volcanoeson isotope ratio correlation diagrams. The isotopic data for the Crater Lake area require sources ofprimitive magmas to consist of depleted mantle and a subductioncomponent, introduced in variable quantity to the depleted mantlewedge. Variable degrees of melting of this heterogeneous mantle,possibly at different depths, produced the diversity of isotopiccompositions and large-ion lithophile element (LILE) abundancesin primitive magmas. Trace element ratios do not indicate presenceof an ocean island basalt (OIB) source component that has beenreported in lavas of some other Cascade volcanoes. Crustal contamination may have affected isotope ratios and LILEconcentrations in evolved HAOT, where initial LILE concentrationswere low. Contamination is more difficult to detect in the calcalkalinelavas because of their higher LILE concentrations and the smallisotopic contrast with likely contaminants, such as mid- tolower-crustal rocks thought to be equivalents of igneous rocksof the Klamath Mountains and associated lower crust. Crustalassimilation appears to be required for calcalkaline rocks onlyby ¹⁸O values, which vary from lows of +5.6 to + 6.0% in HAOTand primitive basaltic andesites to a high of +7.0% in dacite,a range that is too high to be explained by plagioclase-dominatedclosed-system fractional crystallization. Elevated ¹⁸O valuesof differentiated lavas may be attributed to interaction withrelatively ¹⁸O-rich, ⁸⁷Sr-poor crustal rocks. Variably fused granitoid blocks ejected in the climactic eruption,and rarely in late Pleistocene eruptive units, have ¹⁸Opl of–3.4 to +6.5% and ¹⁸O_qz of –2.2 to +8.0% but haveSr, Nd, and Pb isotope ratios similar to volcanic rocks (e.g.⁸⁷Sr/⁸⁶Sr0.7037). Rb and Sr data for glass separates from granodioritessuggest that the source pluton is Miocene. Glass from granodioritehas ⁸⁷Sr/⁸⁶Sr ratios as high as 0.70617. Oxygen isotope fractionationbetween quartz, plagioclase, and glass indicates requilibrationof O isotopes at magmatic temperatures, after ¹⁸O/¹⁶O had beenlowered by exchange with meteoric hydrothermal fluids. Unmeltedgranodiorite xenoliths from pre-climactic eruptive units have¹⁸O values that are consistent with onset of hydrothermal exchangeearly during growth of the climactic magma chamber. Assimilationof such upper-crustal granodiorite apparently lowered ¹⁸O valuesof rhyodacites without significantly affecting their magmaticcompositions in other ways.     

Out of the Rat Race

After the social policy reforms of 1991 important changes in internal migration in New Zealand occurred. These resulted in changing housing costs and falling incomes which led to the movement of low income households, particularly beneficiaries and state house tenants, from urban to rural areas and small towns. A survey of 404 people who moved to the Southern Wairarapa towns of Carterton, Martinborough and Featherston from New Zealand urban areas since 1985 shows that a proportional increase in beneficiary movement occurred after 1991. Housing costs, relative to income, are important factors in the decision to move for a range of migrants. This pattern of migration has important regional development ramifications.     

Sedimentology and origin of deposits from a small ice-dammed lake, Leirbreen, Norway

This paper describes recent proglacial lacustrine sediments exposed by the drainage of a small (probably never more than 0·03 km²) ice-dammed lake basin at Leirbreen, central Jotunheimen, Norway. The dominant facies include ripple-laminated, massive and horizontally-stratified sands, massive and horizontally-laminated silts, and irregularly-laminated fine sands and silts. The major control on lake circulation and the nature and distribution of these facies was an underflow driven by a subglacial meltwater stream which formed the major lake input. Although much of the sedimentary sequence indicates a pulsatory input, the proximal character of this small lake prevented the development of classic varved silts. Compressional deformation of shoreline sediments was due to winter lake ice push. Other deformational processes included the grounding of icebergs, water escape and syn-sedimentary downslope collapse. Observations from an adjacent small ice-marginal lake at Leirbreen provide support for several of the inferences drawn from the sediments of the former ice-dammed lake.     

Determination of Beryllium and Zirconium In 45 Geochemical Reference Samples By Inductively Coupled Plasma Emission Spectrometry

The beryllium and zirconium contents of 45 geochemical reference samples have been determined by inductively coupled plasma after fusion of the samples with lithium metaborate and dissolution of the melt in dilute nitric acid. The method described here is rapid and sample preparation straightforward. Good agreement is shown with previously published results for these two elements. A correction has to be made for an interference due to vanadium in determining the beryllium content, and there is a slight interference due to yttrium in the determination of zirconium. The detection limit for beryllium is about 0.2 μg g^-1 and for zirconium about 15 μg g^-1 in the sample.     

Calc-alkaline, Shoshonitic, and Primitive Tholeiitic Lavas from Monogenetic Volcanoes near Crater Lake, Oregon

Quaternary monogenetic volcanism in the High Cascades of Oregonis manifested by cinder cones, lava fields, and small shields.Near Crater Lake caldera, monogenetic lava compositions include:low-K (as low as 0?09% K₂O) high-alumina olivine tholeiite (HAOT);medium-K. calc-alkaline basalt, basaltic andesite, and andesite;and shoshonitic basaltic andesite (2?1% K₂O, 1750 ppm Sr at54% SiO₂). Tholeiites have MORB-like trace element abundancesexcept for elevated Sr, Ba, and Th and low high field strengthelements (HFSE), and they represent near-primary liquids. Theyare similar to HAOTs from the Cascades and adjacent Basin andRange, and to many primitive basalts from intraoceanic arcs.Calc-alkaline lavas show a well-developed arc signature of highlarge-ion lithophile elements (LILE) and low HFSE. Their Zrand Hf concentrations are at least partly decoupled from thoseof Nb and Ta; HREE are low relative to HAOT. Incompatible elementabundances and ratios vary widely among basaltic andesites.Some calc-alkaline lavas vented near Mount Mazama contain abundantgabbroic microxcnoliths, and are basaltic andesitic magmas contaminatedwith olivine gabbro. A calc-alkaline basalt and a few basaltic andesites have MgOand compatible trace element contents that suggest only minorfractionation. There appears to be a compositional continuumbetween primitive tholeiitic and calc-alkaline lavas. Compositionalvariation within suites of comagmatic primitive lavas, boththoleiitic and calc-alkaline, mainly results from differentdegrees of partial melting. Sources of calc-alkaline primarymagmas were enriched in LILE and LREE by a subduction componentand contained residual garnet, whereas sources of HAOTs hadlower LILE and LREE concentrations and contained residual clinopyroxene.High and variable LILE and LREE contents of calc-alkaline lavasreflect variations in fluid-transported subduction componentadded to the mantle wedge, degree of partial melting, and possiblyalso interaction with rocks or partial melts in the lower crust. Andesites were derived from calc-alkaline basaltic andesitesby fractionation of plagioclase+augite+magnetite+apatite ? orthopyroxeneor olivine, commonly accompanied by assimilation. Many andesitesare mixtures of andesitic or dacitic magma and a basaltic orbasaltic andesitic component, or are contaminated with gabbroicmaterial. Mingled basalt, andesite, and dacite of Williams Craterformed by multi-component, multi-stage mixing of basaltic andesiticmagma, gabbro, and dacitic magma. The wide range of compositionsvented from monogenetic volcanoes near Crater Lake is a resultof the thick crust coupled with mild tectonic extension superimposedon a subduction-related magmatic arc.     

The Holocene vegetation history of the Arfon Platform, North Wales, UK

Detailed pollen, charcoal and loss on ignition profiles were analysed from Llyn Cororion, North Wales, UK. The chronology was based on 11 radiocarbon dates. This site is particularly important for this region because its high-resolution record improves the spatial and temporal resolution of records of Holocene vegetation change in an area characterized by a highly variable environment. An early Holocene phase of Juniperus-Betula scrub was succeeded by Betula-Corylus woodland. Quercus and Ulmus were established by c. 8600 ¹⁴C yr BP, with Pinus dominating at c. 8430 ¹⁴C yr BP. Local disturbance then allowed the spread of Alnus; Tilia was a common component of the forest by 5650 ¹⁴C yr BP. Charcoal and pollen records suggest that by c. 2600 ¹⁴C yr BP there was progressive deforestation, increased use of fire and spread of grassland; the first cereal grain was recorded at c. 2900 ¹⁴C yr BP. Compared with data from upland Snowdonia, the results show that within a topographically diverse region there were significant local variations in forest composition. These variations developed as a response to interactions between many environmental parameters and were further complicated by the influence of human activity. In an area such as North Wales it is therefore unlikely that one site can be representative of regional Holocene vegetational development. The site is additionally important because it contributes to the data available for meta-analyses of environmental change in the North Atlantic region, particularly as detailed pollen diagrams from coastal lake sites around western Europe are rare.     

The potential of perennial cave ice in isotope palaeoclimatology

Perennial ice from caves on and to the east of the Canadian Great Divide yield δ¹⁸O and δD values, which are unusually high measurements when compared with the average precipitation for the region. Furthermore, these ice data fall below and along lines of lower slope than the Global Meteoric Water Line. To explain the observed relationships, we propose the following process. A vapour-ice isotopic fractionation mechanism operates on warm-season vapour when it precipitates as hoar ice on entering the caves. The subsequent fall of hoar to the cave floor through mechanical overloading, along with ice derived from ground-water seepage (with a mean annual isotopic composition), results in massive ice formation of a mixed composition. This mixed composition is what is observed in the characteristic relationships found here. Such findings suggest that a warm versus cold climate interpretation for ancient cave ice may be the opposite of that found in the more familiar polar and glacial ice cores.     

RAPID ESTIMATION OF THE NUMBER OF COELUTING COMPONENTS IN LIQUID CHROMATOGRAPHY BY FACTOR ANALYSIS

Evaluation of the results of factor analysis of sets of spectroscopically detected chromatograms is carriedout by examining the shapes of the abstract factors.This is done either by visual inspection or by analysisof the power density spectra produced from them.Owing to constraints imposed by the column functionand the spectroscopic instrument function,the information content of the chromatograms necessarilyoccurs at low spatial frequencies.As a consequence,it appears as relatively broad features in the abstractchromatograms and as a peak in the low-frequency region of the corresponding power density plot.Onthe basis of examination of the power density distribution,a well-defined distinction is made betweenprimary and secondary abstract factors.The major uncertainty encountered in determining the numberof chemical components appears to arise from effects of contaminants in reagents.