Sugar and Lipid Components in Sea Foam near Kelp Beds

Abstract. A component analysis of the sugar and lipid fraction in foam layers around kelp beds on the South African west coast showed the following trends: In the residue of foam drainage of both 12 h and 120 h old foam the sugar fraction is represented by mannose (33–41 %), galactose (4–30%), fucose (3–29%) and glucose (19–26%). With the exception of fucose, the same components could be found in foam filtration. In the lipid fraction the main fatty acids are palmitic (23.3–27.3%), oleic (14.0–5.5%) and timnodonic acid (11.2–9.1%). Selacholeinic acid was only found in 12 h old foam while lignoceric acid could not be located in foam filtration. Against expectation mannitol was not identified in quantifiable amounts in foam samples although it is the dominant component of kelp mucilage, whose presence is of major importance for foam formation. Hypotheses explaining the lack of mannitol are forwarded. Component sugar and lipid content for 11 of foam was calculated and estimation of sugar and lipid content in an average foam patch (volume of 30001) is given. The importance of foam formation as a mechanism for binding and transfer of energy in the marine environment is emphasized.     

The genotoxic disease syndrome

Since lower animals develop neoplasia rarely or not at all, the DNA- and chromosomal-alterations observed in them after exposure to genotoxic chemicals should be correlated to some genotoxic endpoint other than neoplasia. On the basis of good correlations between induction of DNA- and chromosomal-alterations and the induction of gene mutations, this paper argues that in natural species a variety of manifestations of the mutational event may actually prove to be of much greater biological and ecological importance than induction of neoplasia. These manifestations include impairments in enzyme function, altered protein turnover, impairments in general metabolism, production of initiators of cytotoxic injuries, inhibition of growth, degenerative processes and atrophy in tissues and organs, decreased scope for growth in organisms, faster ageing, decreased fitness and well-being, impairments in immunoresponse and reproduction, increased frequency of diseases and neoplasia, impairments in adaptation, survival, and succession, and finally, extinction of species. Taken together, these ‘symptoms’ constitute a syndrome of a disease which etiologically could be named the genotoxic disease syndrome.     

Geomagnetic Effects of Corotating Interaction Regions

We present an analysis of the geoeffectiveness of corotating interaction regions (CIRs), employing the data recorded from 25 January to 5 May 2005 and throughout 2008. These two intervals in the declining phase of Solar Cycle 23 are characterised by a particularly low number of interplanetary coronal mass ejections (ICMEs). We study in detail how four geomagnetic-activity parameters (the Dst, Ap, and AE indices, as well as the Dst time derivative, \(\mathrm{dDst}/\mathrm{d}t\)) are related to three CIR-related solar wind parameters (flow speed, \(V\), magnetic field, \(B\), and the convective electric field based on the southward Geocentric solar magnetospheric (GSM) magnetic field component, \(\mathit{VB}_{s}\)) on a three-hour time resolution. In addition, we quantify statistical relationships between the mentioned geomagnetic indices. It is found that Dst is correlated best to \(V\), with a correlation coefficient of \(\mathrm{cc}\approx0.6\), whereas there is no correlation between \(\mathrm{dDst}/\mathrm{d}t\) and \(V\). The Ap and AE indices attain peaks about half a day before the maximum of \(V\), with correlation coefficients ranging from \(\mathrm{cc}\approx0.6\) to \(\mathrm{cc}\approx0.7\), depending on the sample used. The best correlations of Ap and AE are found with \(\mathit{VB}_{s}\) with a delay of 3 h, being characterised by \(\mathrm{cc}\gtrsim 0.6\). The Dst derivative \(\mathrm{dDst}/\mathrm{d}t\) is also correlated with \(\mathit{VB}_{s}\), but the correlation is significantly weaker \(\mathrm{cc}\approx 0.4\)?–?0.5, with a delay of 0?–?3 h, depending on the employed sample. Such low values of correlation coefficients indicate that there are other significant effects that influence the relationship between the considered parameters. The correlation of all studied geomagnetic parameters with \(B\) are characterised by considerably lower correlation coefficients, ranging from \(\mathrm{cc}=0.3\) in the case of \(\mathrm{dDst}/\mathrm{d}t\) up to \(\mathrm{cc}=0.56\) in the case of Ap. It is also shown that peak values of geomagnetic indices depend on the duration of the CIR-related structures. The Dst is closely correlated with Ap and AE (\(\mathrm{cc}=0.7\)), Dst being delayed for about 3 h. On the other hand, \(\mathrm{dDst}/\mathrm{d}t\) peaks simultaneously with Ap and AE, with correlation coefficients of 0.48 and 0.56, respectively. The highest correlation (\(\mathrm{cc}=0.81\)) is found for the relationship between Ap and AE.     

Post-drilling destabilization of temperature profile in borehole Yaxcopoil-1, Mexico

As part of the International Continental Scientific Drilling Program (ICDP), the 1.5-km-deep borehole Yaxcopoil-1, located in the Chixculub meteor impact structure in Mexico, has undergone further study after drilling operations ceased. Temperature logs were repeated ten times at intervals 0.3–0.8, 15, 24 and 34 months after borehole shut-in. The logs bear a distinct signature of transient heat transfer by groundwater flow manifested by a gradual distortion of the linear temperature profile when a cold wave of 0.8–1.6°C amplitude was detected propagating downward from 145 to 312 m at a rate of 4–6 m/month. To understand the nature of this moving anomaly, a 20-day monitoring of the cold wave was carried out at a depth of 307 m that showed further cooling of 0.6°C during the first 16 days of the passage followed by temperature stabilisation. As an explanation of this unusual phenomenon, a theory is proposed, whereby the drilling mud has accumulated within the overlying and cooler highly porous and permeable karstic rocks during the drilling and migrates downward. The observed migration rate suggests a permeability higher than 10^?11 m². This indicates a high vulnerability to contamination of the only freshwater aquifer in the Yucatan region.     

Evidence for a Long-Term Strength Threshold in Crystalline Rock

The mechanical response of brittle rock to long-duration compression loading is of particular concern in underground disposal of nuclear waste, where radionuclides must be isolated from the biosphere for periods of the order of a million years. Does the strength decrease without limit over such time, or is there, for some rock types, a lower “threshold” strength below which the rock will cease to deform? This paper examines the possibility of such a threshold in silicate crystalline rocks from several perspectives, including: (1) interpretation of the results of short-term creep tests on rock; (2) numerical analysis of the effect of decrease in fracture toughness due to stress corrosion on the strength of a crystalline rock; and (3) evidence from plate tectonics, and observations of in situ rock stress in granite quarries. The study concludes that there is clear evidence of threshold strength. The threshold is of the order of 40% of the unconfined compressive strength or higher for laboratory specimens under unconfined compressive loading, and increases rapidly in absolute value with confinement. Field evidence also leads to the conclusion that the long-term strength of crystalline rock in situ is of comparable magnitude to the laboratory value.     

Numerical solution to the oblique derivative boundary value problem on non-uniform grids above the Earth topography

The paper presents a numerical solution of the oblique derivative boundary value problem on and above the Earth’s topography using the finite volume method (FVM). It introduces a novel method for constructing non-uniform hexahedron 3D grids above the Earth’s surface. It is based on an evolution of a surface, which approximates the Earth’s topography, by mean curvature. To obtain optimal shapes of non-uniform 3D grid, the proposed evolution is accompanied by a tangential redistribution of grid nodes. Afterwards, the Laplace equation is discretized using FVM developed for such a non-uniform grid. The oblique derivative boundary condition is treated as a stationary advection equation, and we derive a new upwind type discretization suitable for non-uniform 3D grids. The discretization of the Laplace equation together with the discretization of the oblique derivative boundary condition leads to a linear system of equations. The solution of this system gives the disturbing potential in the whole computational domain including the Earth’s surface. Numerical experiments aim to show properties and demonstrate efficiency of the developed FVM approach. The first experiments study an experimental order of convergence of the method. Then, a reconstruction of the harmonic function on the Earth’s topography, which is generated from the EGM2008 or EIGEN-6C4 global geopotential model, is presented. The obtained FVM solutions show that refining of the computational grid leads to more precise results. The last experiment deals with local gravity field modelling in Slovakia using terrestrial gravity data. The GNSS-levelling test shows accuracy of the obtained local quasigeoid model.     

Wave Flow Simulations Over Arctic Leads

We investigate the flow over Arctic leads using a mesoscale numerical model, typical of both summer and winter, under idealised conditions. We find that Arctic leads may be the source of standing atmospheric internal gravity waves during both seasons. The summertime wave may be compared with the wave generated by a small ridge, though with the phase reversed. The mechanism for exciting the wave is found to be the internal boundary layer developing due to horizontal variations in surface temperature and roughness length. During the more exploratory wintertime simulations, with substantial temperature difference between the lead and the ice surface, we find that secondary circulations and intermittent wave-breaking may occur. The effects of the lead appear far downstream.