Calcium isotope (δCa) fractionation along hydrothermal pathways, Logatchev field (Mid-Atlantic Ridge, 14°45′N)

We investigate the Logatchev Hydrothermal Field at the Mid-Atlantic Ridge, 14°45′N to constrain the calcium isotope hydrothermal flux into the ocean. During the transformation of seawater to a hydrothermal solution, the Ca concentration of pristine seawater ([Ca]_SW) increases from about 10 mM to about 32 mM in the hydrothermal fluid endmember ([Ca]_HydEnd) and thereby adopts a δ^44/40Ca_HydEnd of −0.95 ± 0.07‰ relative to seawater (SW) and a ⁸⁷Sr/⁸⁶Sr isotope ratio of 0.7034(4). We demonstrate that δ^44/40Ca_HydEnd is higher than that of the bedrock at the Logatchev field. From mass balance calculations, we deduce a δ^44/40Ca of −1.17 ± 0.04‰ (SW) for the host-rocks in the reaction zone and −1.45 ± 0.05‰ (SW) for the isotopic composition of the entire hydrothermal cell of the Logatchev field. The values are isotopically lighter than the currently assumed δ^44/40Ca for Bulk Earth of −0.92 ± 0.18‰ (SW) [Skulan J., DePaolo D. J. and Owens T. L. (1997) Biological control of calcium isotopic abundances in the global calcium cycle. Geochim. Cosmochim. Acta61,(12) 2505-2510] and challenge previous assumptions of no Ca isotope fractionation between hydrothermal fluid and the oceanic crust [Zhu P. and Macdougall J. D. (1998) Calcium isotopes in the marine environment and the oceanic calcium cycle. Geochim. Cosmochim. Acta62,(10) 1691-1698; Schmitt A. -D., Chabeaux F. and Stille P. (2003) The calcium riverine and hydrothermal isotopic fluxes and the oceanic calcium mass balance. Earth Planet. Sci. Lett. 6731, 1-16]. Here we propose that Ca isotope fractionation along the fluid flow pathway of the Logatchev field occurs during the precipitation of anhydrite. Two anhydrite samples from the Logatchev Hydrothermal Field show an average fractionation of about Δ^44/40Ca = −0.5‰ relative to their assumed parental solutions. Ca isotope ratios in aragonites from carbonate veins from ODP drill cores indicate aragonite precipitation directly from seawater at low temperatures with an average δ^44/40Ca of −1.54 ± 0.08‰ (SW). The relatively large fractionation between the aragonite precipitates and seawater in combination with their frequent abundance in weathered mafic and ultramafic rocks suggest a reconsideration of the marine Ca isotope budget, in particular with regard to ocean crust alteration.     

Conflicting imaginations: Archaeology, anthropology and geomorphology on Leskernick Hill, Bodmin Moor, southwest Britain

In this paper we view the different practices of archaeology, anthropology, environmental reconstruction and geomorphology through the lens of fieldwork on the clitter fields and Bronze Age settlement patterns on Leskernick Hill, Bodmin Moor, southwest Britain. The moor forms one of the best preserved fossil prehistoric landscapes of Europe and has undergone repeated periglacial episodes during the Quaternary. We show that the characterisation of patterned ground by archaeologists and anthropologists can be very different from that generated by geomorphology, particularly with respect to the spatial scales at which culture/nature questions are posed. We argue that the research project at Leskernick is a good example of how multi-disciplinary work is often more fruitful than mono-disciplinary and provides an example of how conversations across the divides of disciplinary practice can be held.     

Voracious planktonic hydroids: unexpected predatory impact on a coastal marine ecosystem

Hydroids are typically attached, benthic cnidarians that feed on a variety of small prey. During sampling on Georges Bank in spring 1994, we found huge numbers of hydroids suspended in the plankton. They fed on young stages of copepods that are an important prey for fish, as well as on young fish themselves. Two independent methods were used to estimate feeding rates of the hydroids; both indicate that the hydroids are capable of consuming from 50% to over 100% of the daily production of young copepods. These results suggest that hydroids can have a profound effect on the population dynamics of zooplankton and young fish on Georges Bank.     

4-tert-octylphenol and 17beta-estradiol applied by feeding to flounder Platichthys flesus: induction of vitellogenin and accumulation in tissues

In order to simulate a possible natural administration route of xenoestrogens male flounder Platichthys flesus were exposed via the diet to the alkylphenol 4-tert-octylphenol. Treatment with 4-tert-octylphenol (10, 50 and 100 mg OP kg(-1) BW) or 17beta-estradiol (0.05 mg kg(-1) BW) every second day during a period of 11 days resulted in a significant increase in plasma vitellogenin (Vtg) concentrations. The induction of Vtg was greatest in the fish receiving 50 mg OP kg-' BW. A significant accumulation of 4-tert-octylphenol was found in liver and muscle tissue of the OP treated groups. The tissue concentrations of 4-tert-octylphenol and the plasma vitellogenin concentration were positively correlated. The results show that 4-tert-octylphenol accumulates in liver and muscles of flounder P. flesus, and exerts estrogenic effects such as vitellogenin induction.     

Malthusian overfishing in Pulau Banggi?

We assess, based on fisheries and interview data collected on-site, whether Malthusian overfishing is occurring in Pulau Banggi, Sabah. Fisheries resources in Pulau Banggi have been perceived to be declining over the past 20 years, and characteristics of Malthusian overfishing are evident, although not at a magnitude comparable with other more heavily exploited artisanal fisheries in the Philippines. It appears that Pulau Banggi's reef fisheries are at an early stage of Malthusian overfishing, and this is therefore a critical time for addressing and mitigating drivers of overfishing to prevent inevitable and further decline of Pulau Banggi's reef fisheries.     

Primodial retention of carbon by the terrestrial planets

Chemical equilibrium calculations on the stability of pure and dissolved graphite and cohenite (Fe₃C), several other carbides, and several carbonates have been carried out for a system with solar elemental abundances over a very wide range of temperature and pressure. The calculated abundances of condensed carbon compounds are similar to the observed inventories on Earth and Venus, but fully 10 times smaller than the minimum carbon abundance found in ordinary chondrites. The total carbon content of most iron meteorites is compatible with their origin as a cooling FeNiCSP solution which was saturated with dissolved carbon at the solidus, such as would be produced by melting an ordinary chondrite, not by direct condensation from or equilibrium with the primitive solar nebula. It is argued that the carbon content of Mars need not be appreciably greater than that of the Earth. Material with even lower formation temperatures than Mars, such as the primitive material in the asteroid belt, may retain substantially more carbon as disequilibrium polymeric organic matter, possibly by the Fischer-Tropsch mechanism favored by Anders. Carbonates are not found as equilibrium products in a solar-composition system, and are probably secondary alteration products. CaCO₃ might, however, persist in a solar-composition gas at temperatures below 460°K and pressures below 10^?6.6 bar. The most stable condensed carbon compounds are found to be graphite, Fe₃C, and possibly TiC, all in solid solution in the metal phase.     

Observations of the Orion Nebula in Hα, [NII] and Hβ lines

Monochromatic photographs of the Orion Nebula taken through narrow bandpass interference filters (Δλ=10 Å) centred on Hα, Hβ and [NII] lines are presented. Ratio contours of Hα/[NII] and Hα/Hβ are derived. They enable a detailed study of the point-to-point variation in ionization structure and temperature throughout the nebula. Dust located within the ionized gas is studied from the Hα/Hβ ratio which varies from point to point over the nebula. Its strongest concentration, apart in the obvious ‘dark bay’, occurs in a shell surrounding the exciting stars, with about 2′ of diameter. Close to Θ¹ Ori the Hα/Hβ ratio, corrected for interstellar reddening, is about 3.0 in good agreement with the predicted value (Brocklehurst, 1971). To account for these measures, the following arguments are proposed:

1. Dust grains are completely or partially destroyed in region close to the exciting stars.
2. Radiation pressure and stellar wind push the remaining dust up to some equilibrium distance outwards. The consequence of this action is obviously the formation of a ‘dust mantle’ which is seen as a ring in projection.

     

Loi de titius-bode et formalisme ondulatoire

Several authors (Basano and Hughes, 1979; ter Haar and Cameron, 1963, Dermott, 1968; Prentice, 1976) give the revised Titius-Bode law in the form $$r_n = r_o C^n ,$$ wherer _n stands for the distance of thenth planet from the Sun;r _o andC are constant. They pointed out, in addition, that regular satellites systems around major planets obey also that law. It is now generally thought that the Kant-laplace primeval nebula accounts for the origin and evolution of the solar system (Reeves, 1976). Furthermore, it is shown (Prentice, 1976) that rings, which obey the Titius-Bode law, are formed through successive contractions of the solar nebula. Among difficulties encountered by Prentice's theory, the formation of regular satellites similar to the planatery system is the most important one. Indeed, the starting point of the planetary system is a rotating flattened circular solar nebula, whereas a gaseous ring must be the starting point of satellites systems. As far as the Titius-Bode law is concerned, we have the feeling that orbits of planets around the Sun and of satellites around their primaries do not depend on starting conditions. That law must be inherent to gravitation, in the same manner that electron orbits depend only on the atomic law instead of the starting conditions under which an electron is captured. If it is correct, then one may expect to formulate similarity between the T-B law and the Bohr law in the early quantum theory. Such a similarity is found (Louise, 1982) by using a postulate similar to the Bohr-Sommerfeld one — i.e., $$\int_{r_o }^{r_n } {U(r) dr = nk,}$$ whereU(r)=GM _⊙ /r is the potential created by the Sun,k is a constant, andn a positive integer. This similarity suggests the existence of an unknown were process in the solar system. The aim of the present paper is to investigate the possibility of such a process. The first approach is to study a steady wave encountered in special membrane, showing node rings similar to the Prentice's rings (1976) which obey the T-B law. In the second part, we try to apply the now classical Lindblad-Lin density wave theory of spiral galaxies to the solar nebula case. This theory was developed since 1940 (Lindblad, 1974) in order to account for the persistence of spiral structure of galaxies (Lin and Shu, 1964; Lin, 1966; Linet al., 1969; Contopoulos, 1973). Its basic assumption concerns the potential functionU expressed in the form $$U = U_0 + \tilde U,$$ whereU _o stands for the background axisymmetric potential due to the disc population, and ?«U _o is responsible of spiral density wave. Then, the corresponding mass-density distribution is \(\rho = \rho _o + \tilde \rho\) , with \(\tilde \rho \ll \rho _o\) . Both quantities ? and \(\tilde \rho\) must satisfy the Poisson's equation $$\nabla ^2 \tilde U + 4\pi G\tilde \rho = 0.$$ It is shown by direct observations that most spiral arms fit well with a logarithmic spiral curve (Danver, 1942; Considère, 1980; Mulliard mand Marcelin, 1981). From the physical point of view, they are represented by maxima of ? (or \(\tilde \rho\) ) which is of the form $$\tilde U = cte cos (q log_e r - m\theta ),$$ wherem is an integer (number of arms),q=cte, andr and θ are polar coordinates. The distancer is expressed in an arbitrary unit (r=d/d_o). In the case of an axisymmetric solar nebula (m=0), successive maxima of \(\tilde U\) are rings showing similar T-B law $$d = d_o C^n ,$$ withC=e ^{2 π/q} constant, andn is a positive integer. It is noted, in addition, that the steady wave equation within the special membrane quoted above and the new expression of the Poisson's equation derived from (5) are quite similar and expressed in the form $$\nabla ^2 \tilde U + cte\tilde U/r^2 = 0.$$ This suggests that both spiral structure of galaxies and Prentice's rings system result from a wave process which is investigated in the last section. From Equation (2) it is possible to derive the wavelength of the assumed wave ‘χ’, by using a procedure similar to the one by L. De Broglie (1923). The velocity of the wave ‘χ’ process is discussed in two cases. Both cases lead to a similar Planck's relation (E=hv).     

Monazite U-Pb dating of staurolite grade metamorphism in pelitic schists

A study of the occurrence of and relations between rare-earth element (REE) minerals in pelitic schists indicates that monazite forms at or near the P and T of the staurolite isograd. Samples at staurolite grade from the Silurian Perry Mountain Formation in the Rumford quadrangle of Maine yield monazite in sufficient quantities to permit accurate dating of the metamorphic events forming the monazites. The bulk chemistry of the metapelites, as seen in the major element abundances and REE patterns, does not vary significantly across the study area. Thus the appearance and disappearance of REE phases is assumed to reflect changes in metamorphic grade. In a sample from the biotite zone, scanning electron microscope and microprobe studies show allanite and monazite intimately associated on a 10 m scale. The texture suggest that metastable detrital monazite breaks down, distributing its REE components to allanite. From samples below staurolite grade in which monazite is not present, our observations suggest that REEs are partitioned into allanite. At or near the staurolite isograd monazite forms as a metamorphic mineral, initiating its role as a geochronometer. Garnet-biotite geothermometry on samples at this grade from this and other studies places constraints on the minimum temperature necessary to form monazite: 525° C±25°C at 3.1±0.25 kbar. A total of 15 separates from nine schist samples ranging up to sillimanite grade have been dated. Each date is remarkably concordant, even though petrologic and textural studies by previous workers have shown that the rocks in the area have been affected by at least three metamorphic episodes. Calculations indicate insignificant Th disequilibrium in these monazites. The conditions associated with the metamorphic events suggest that monazite remains closed to lead loss provided that subsequent metamorphisms are at or below sillimanite grade. Two distinct metamorphic events are resolved, one at around 400 Ma and one at about 370 Ma. The latter was due to thermal effects of a nearby pluton that yields concordant monazite ages of 363 Ma. This work suggests that in addition to dating plutonism and high-grade metamorphism, monazite should be viewed as a reliable geochronometer for moderate metamorphism of pelitic schists.     

Gas maturity and alteration systematics across the Western Canada Sedimentary Basin from four mud gas isotope depth profiles

Carbon isotope and molecular compositions of Mississippian to Upper Cretaceous mud gases have been examined from four depth profiles across the Western Canada Sedimentary Basin (WCSB). The profiles range from the shallow oil sands in the east (R₀ = 0.25) to the very mature sediments in the overthrust zone to the west (R₀ = 2.5). In the undisturbed WCSB, δ¹³C₁–δ¹³C₂ and δ¹³C₂–δ¹³C₃ cross-plots show three maturity and alteration trends: (1) pre-Cretaceous gas sourced from type II kerogen; (2) Cretaceous Colorado Group gas; and (3) Lower Cretaceous Mannville Group biodegraded gas. A fourth set of distinctly different maturity trends is recognized for Lower Cretaceous gas sourced from type III kerogen in the disturbed belt of the WCSB. Displacement of these latter maturity trends to high δ¹³C₂ values suggests that the sampled gas was trapped after earlier formed gas escaped, probably as a result of overthrusting. Unusually ¹³C-enriched gas (δ¹³C₁ = −34‰, δ¹³C₂ = −13‰, and δ¹³C₃ = 0‰), from the Gething Formation in the disturbed belt, is the result of late stage gas cracking in a closed system. In general, gas maturity is consistent with the maturity of the host sediments in the WCSB, suggesting that migration and mixing of gases was not pervasive on a broad regional and stratigraphic scale. The ‘Deep Basin’ portion of the WCSB is an exception. Here extensive cross-formational homogenization of gases has occurred, in addition to updip migration along the most permeable stratigraphic units.