Methane content in coal seam is an essential parameter for the assessment of coalbed gas reserves and is a threat to underground coal mining activities. Compared with the adsorption-isotherm-based indirect method, the direct method by sampling methane-bearing coal seams is apparently more accurate for predicting coalbed methane content. However, the traditional sampling method by using an opened sample tube or collecting drill cuttings with air drilling operation would lead to serious loss of coalbed methane in the sampling process. The pressurized sampling method by employing mechanical-valve-based pressure corer is expected to reduce the loss of coalbed methane, whereas it usually results in failure due to the wear of the mechanical valve. Sampling of methane-bearing coal seams by freezing was proposed in this study, and the coalbed gas desorption characteristics under freezing temperature were studied to verify the feasibility of this method. Results show that low temperature does not only improve the adsorption velocity of the coalbed gas, but also extend the adsorption process and increase the total adsorbed gas. The total adsorbed methane gas increased linearly with decreasing temperature, which was considered to be attributed to the decreased Gibbs free energy and molecular average free path of the coalbed gas molecular caused by low temperature. In contrast, the desorption velocity and total desorbed gas are significantly deceased under lower temperatures. The process of desorption can be divided into three phases. Desorption velocity decreases linearly at the first phase, and then, it shows a slow decreases at the second phase. Finally, the velocity of desorption levels off to a constant value at the third phase. The desorbed coalbed gas shows a parabolic relation to temperature at each phase, and it increases with increasing temperature at the first phase, and then, it poses a declining trend with increasing temperature at the rest phases. The experimental results show that decreasing the system temperature can restrain desorption of coalbed methane effectively, and it is proven to be a feasible way of sampling methane-bearing coal seams.
Tropical subseasonal variability of precipitation from five global reanalyses (RAs) is evaluated against Global Precipitation Climatology Project (GPCP) and Tropical Rainfall Measuring Mission (TRMM) observations. The RAs include the three generations of global RAs from the National Center for Environmental Prediction (NCEP), and two other RAs from the European Centre for Medium-Range Weather Forecasts (ECMWF) and the National Aeronautics and Space Administration/Goddard Space Flight Center (NASA/GSFC). The analysis includes comparisons of the seasonal means and subseasonal variances of precipitation, and probability densities of rain intensity in selected areas. In addition, the space–time power spectrum was computed to examine the tropical Madden-Julian Oscillation (MJO) and convectively coupled equatorial waves (CCEWs). The modern RAs show significant improvement in their representation of the mean state and subseasonal variability of precipitation when compared to the two older NCEP RAs: patterns of the seasonal mean state and the amplitude of subseasonal variability are more realistic in the modern RAs. However, the probability density of rain intensity in the modern RAs show discrepancies from observations that are similar to what the old RAs have. The modern RAs show higher coherence of CCEWs with observed variability and more realistic eastward propagation of the MJO precipitation. The modern RAs, however, exhibit common systematic deficiencies including: (1) variability of the CCEWs that tends to be either too weak or too strong, (2) limited coherence with observations for waves other than the MJO, and (3) a systematic phase lead or lag for the higher-frequency waves. 相似文献
Variations of global evapotranspiration (ET) and fresh water discharge from land to oceans (D) are important components of global climate change, but have not been well monitored. In this study, we present an estimate of twenty years (1989 to 2008) variations of global D and ET derived from satellite remote-sensed measurements and recent reanalysis products, ERA-Interim and CFSR, by using a novel application of the water balance equations separately over land and over oceans. Time series of annual mean global D and ET from both satellite observations and reanalyses show clear positive and negative trends, respectively, as a result of modest increase of oceanic evaporation (Eo). The inter-annual variations of D are similar to the in-situ-based observations, and the negative trend of ET supports the previous result that relative humidity has decreased while temperature has increased on land. The results suggest considerable sensitivity of the terrestrial hydrological cycles (e.g., D and ET) to small changes in precipitation and oceanic evaporation. 相似文献