The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

The trouble with nature: Ambivalence in the lives of urban Australian environmentalists

The number and range of contests over the social production of nature is growing. Much environmentalist discourse, however, continues to appeal for unequivocal scientific support on clearly demarcated issues of pure, a-social nature. This paper explores the question of how participants in environmental movements view this demarcation in the context of their own lives. After introducing scholarly critique of dualistic ideas of nature and the ambivalence characteristic of environmentalist conceptions of nature, the paper draws upon a qualitative study with environmentalists in the Australian cities of Melbourne, Perth and Hobart. Inquiring into the interplay of discourse of nature and everyday worlds, interviews revealed a complex interdependence of dualistic and non-dualistic understandings of nature. This ecology of ideas was especially evident in spatial imaginaries of nature. Scientific terminology, social disaffection and pessimism were associated with abstract and mutually exclusive conceptions of society and nature. Reflections on personal experience, however, indicated more flexible and hopeful negotiations in everyday liminal spaces offering ‘the best of both worlds’. It is concluded that environmentalist resistance to dismantling of conceptual boundaries between society and nature may often stem not from failure to appreciate socionatural complexity, but from a strongly felt sense that the self can only truly be found in nature.     

Salt tectonics in the Cap Boujdour Area,Aaiun Basin,NW Africa

Seismic reflection data indicate the Moroccan salt basin extends to the Cap Boujdour area in the Aaiun Basin. Two salt diapir structures have been identified and several areas of collapsed strata indicate probable salt removal at the shelf edge. The presence of salt in this area correlates to the conjugate southern George's Bank Basin and the Baltimore Canyon area, and it is suggested that the salt extends southward from the known salt diapir province in the George's Bank Basin southward to the Great Stone Dome. The paucity of salt diapirs is attributed to the thick carbonate and anhydrite sequence, which was deposited soon after salt deposition that inhibited halokinesis. The presence of salt along this large segment of the Atlantic margin should increase its hydrocarbon potential with traps created around salt diapirs and provision of migration pathways from deep potential source rocks in the early Cretaceous and Jurassic strata to shallower levels.     

Differences in Kilometre‐scale wind and humidity boundary‐layer structure at GATE

Abstract

During the GARP Atlantic Tropical Experiment (GA TE) in the summer of 1974, identical tethersonde packages were flown to heights of 1,000 m from two ships with a crosswind separation of approximately 4 km. The differences in the profiles and fixed level time series from the two packages are a measure of spatial variability in the tropical marine boundary layer.

Correlation analysis indicate a cellular pattern in the large‐scale wind field. Similar analyses of the temperature and humidity fields give quite different results.     

Leveraging modern climatology to increase adaptive capacity across protected area networks

Human-driven changes in the global environment pose an increasingly urgent challenge for the management of ecosystems that is made all the more difficult by the uncertain future of both environmental conditions and ecological responses. Land managers need strategies to increase regional adaptive capacity, but relevant and rapid assessment approaches are lacking. To address this need, we developed a method to assess regional protected area networks across biophysically important climatic gradients often linked to biodiversity and ecosystem function. We plot the land of the southwestern United States across axes of historical climate space, and identify landscapes that may serve as strategic additions to current protected area portfolios. Considering climate space is straightforward, and it can be applied using a variety of relevant climate parameters across differing levels of land protection status. The resulting maps identify lands that are climatically distinct from existing protected areas, and may be utilized in combination with other ecological and socio-economic information essential to collaborative landscape-scale decision-making. Alongside other strategies intended to protect species of special concern, natural resources, and other ecosystem services, the methods presented herein provide another important hedging strategy intended to increase the adaptive capacity of protected area networks.     

Trace metal dynamics in a seasonally anoxic lake

Selected results are presented from a detailed 12-month study of trace metals in a seasonally anoxic lake. Dissolved concentrations of Fe, Mn, organic carbon, Cd, Cu, Pb, Zn, and pH were determined in the water column and the interstitial waters on 39 occasions. Trace metal concentrations remained low throughout the year in both water column and pore waters. There was evidence for some remobilization at the sediment-water interface but sediments deeper than 3 cm acted as a sink throughout the year. Variations in the water concentrations were largely associated with increased loading during periods of heavy rainfall. During the summer, concentrations of Cu and Zn in the waters overlying the sediments were enhanced by release from decomposing algal material. Similarly, enhanced concentrations of Cd, Cu, Pb, and Zn were observed during periods of much reduced mixing during ice-cover. Although there were large seasonal variations in the concentrations of dissolved and particulate Fe and Mn, there were no comparable changes in the concentrations of trace metals.     

Specific-lon electrode determinations of sulfide preconcentrated from San Francisco Bay waters

Measurements of low-level dissolved-sulfide concentrations in estuarine water from San Francisco Bay have been made using the sulfide-specific electrode after preservation, separation, and preconcentration of the sulfide species. The separation and preconcentration were acheived by coprecipitation of ZnS with Zn(OH)₂ followed by collection and dissolution of the precipitate, giving concentration factors up to 160-fold Preconcentration provided sulfide solutions that were adequately measurable within the practical working range of the specific-ion electrode The sulfide detection limit with the preconcentration step is 0 02 μg/l Spike recoveries in the range of 81 to 10 1% have been achieved for laboratory-prepared samples having S²⁻ concentrations as low as 0 6 μg/l and 84 to 100% for an estuarine sample spiked in the field with 2 μg/l (S(−II) Positive correlations have been found between dissolved S(−II) concentrations and concentrations of dissolved Cd, Cu, and Ni, negative correlations have been found between bisulfide (HS⁻) activity and activities of Cd²⁺, Cu²⁺, and Ag⁺ species     

‘Copernicus’ observations of extragalactic X-ray sources

The MSSL X-ray detectors onCopernicus have been used to study a number of extragalactic objects. At least three classes of unresolved sources are found and we suggest that accretion may be the dominant mechanism. The mass of the accreting object then determines the X-ray emission properties.Paper presented at the COSPAR Symposium on Fast Transients in X- and Gamma-Rays, held at Varna, Bulgaria, 29–31 May, 1975.     

Geometric similarity for the temperature field in the unstable atmospheric surface layer

Davenport's geometric similarity is applied to the temperature field in the unstable atmospheric surface layer for displacements in all three orthogonal directions. The decay constants for lateral displacements are over 50 times as large as for vertical displacements. Such large lateral decay constants mean that the measurement of longitudinal constants will be very difficult.Some of the assumptions inherent in geometric similarity were not satisfied. Two regimes, plume scales and larger scales, having different decay constants, were observed. The possibility of a similar scale dependency of the decay constants for the wind field is discussed.     

Application of the SHETRAN basin‐scale,landslide sediment yield model to the Llobregat basin,Spanish Pyrenees

The first application of the SHETRAN basin‐scale, landslide erosion and sediment yield model is carried out for a major landsliding event in the upper 505 km² of the Llobregat basin, in the eastern Spanish Pyrenees, in November 1982. The model simulates the spatial distribution of shallow landslides and their sediment yield. Acknowledging uncertainty in the model parameter evaluation, the aim of the application was not to reproduce the observed occurrence of landslides as accurately as possible with one simulation, but to bracket the observed pattern with several simulations representing uncertainty in the key input conditions. Bounds on the landslide simulations were thus determined as a function of uncertainty in the vegetation root cohesion (used in the model factor of safety calculations). The resulting upper bound considerably overestimates the observed pattern (17 000 landslides compared with an observation of around 700), but it reproduces several of the principal clusters in the observed pattern. The lower bound contains around 500 landslides. The sediment yield estimates (2670–14 630 t km^?2) are comparable to measurements elsewhere in the Pyrenees for extreme events. The results demonstrate an ability to simulate the basin‐scale landslide response to a rainfall event and the resulting sediment yield. They also highlight the need for further research in setting the uncertainty bounds and in avoiding large overestimates of landslide occurrence arising in part from a current inability to model small‐scale controls for a basin of the given size. Copyright © 2006 John Wiley & Sons, Ltd.