Mafic Pegmatites Intruding Oceanic Plateau Gabbros and Ultramafic Cumulates from Bolivar, Colombia: Evidence for a 'Wet' Mantle Plume?

The fault-bounded Bolívar Ultramafic Complex (BUC) onthe eastern fringes of the Western Cordillera of Colombia wastectonically accreted onto the western coast of South Americain the late Cretaceous–early Tertiary, along with pillowbasalts of the Caribbean–Colombian Oceanic Plateau (CCOP).The complex consists of a lower sequence of ultramafic cumulates,successively overlain by layered and isotropic gabbroic rocks.The gabbros grade into, and are intruded by, mafic pegmatitesthat consist of large magnesiohornblende and plagioclase crystals.These pegmatites yield a weighted mean ⁴⁰Ar–³⁹Ar step-heatingage of 90·5 ± 0·9 Ma and thus coincidewith the timing of peak CCOP volcanism. The chemistry of theBUC is not consistent with a subduction-related origin. However,the similarity in Sr–Nd–Pb–Hf isotopes betweenthe CCOP and the BUC, in conjunction with their indistinguishableages, suggests that the BUC is an integral part of the plume-derivedCCOP. The parental magmas of the Bolívar complex wereprobably hydrous picrites that underwent 20–30% crystallization.The residual magmas from this fractionation contained     

A numerical model for porosity modification at a sandstone-mudstone boundary by quartz pressure dissolution and diffusive mass transfer

In many sandstones quartz cements significantly reduce porosity. The origin of these cements is often unclear. This paper investigates a possible mechanism for the generation of silica for quartz cement by pressure dissolution in interbedded mudstones. Theoretical models of quartz pressure dissolution, including the effects of silica precipitation kinetics, show that the concentration of dissolved silica in the pore fluids of a compacting sediment increases with decreasing grain size and silica precipitation constant. Quartz precipitation is strongly inhibited by the presence of small amounts of clay within a sediment, suggesting that siltstones and quartz-rich mudstones which are undergoing pressure dissolution may act as a source of dissolved silica for export to nearby, coarser sediments. A computational model for the diagenetic modification of a sandstone-mudstone interface due to pressure dissolution is described. Both sandstone and mudstone layers are assumed to be actively compacting by pressure dissolution, and mass transport by molecular diffusion is considered. As quartz precipitation in the mudstone layer is relatively slow compared to that in the sandstone, significant amounts of dissolved silica become available in the mudstone, and may be exported into the adjacent sandstone. In the absence of pore-fluid advection, this may result in the formation of extensive secondary quartz within the sandstone, close to the interface. The volume of silica exported from the mudstone is limited by the length scale over which diffusion through the mudstone is effective. This is typically 3–5 m. The volume of silica available therefore suggests that extensive porosity modification within the adjacent sandstone can only occur close to the mudstone. Thus it is possible that thin sandstones could become cemented by slow diffusive transfer of silica, but that in thicker sandstones the silica may become dispersed by pore-fluid advection.     

HYDROCHEMISTRY AS AN INDICATOR OF SUBGLACIAL DRAINAGE SYSTEM STRUCTURE: A COMPARISON OF ALPINE AND SUB-POLAR ENVIRONMENTS

The anion compositions (SO²₄, HCO⁻₃ and Cl⁻) of runoff from the Haut Glacier d'Arolla, Switzerland and Austre Brøggerbreen, Svalbard are compared to assess whether or not variations in water chemistry with discharge are consistent with current understanding of the subglacial drainage structure of warm- and polythermal-based glaciers. These glacial catchments have very different bedrocks and the subglacial drainage structures are also believed to be different, yet the range of anion concentrations show considerable overlap for SO²⁻₄ and HCO⁻₃. Concentrations of Cl⁻ are higher at Austre Brøggerbreen because of the maritime location of the glacier. Correcting SO²⁻₄ for the snowpack component reveals that the variation in non-snowpack SO²⁻₄ with discharge and with HCO⁻₃ is similar to that observed at the Haut Glacier d'Arolla. Hence, if we assume that the provenance of the non-snowpack SO²⁻₄ is the same in both glacial drainage systems, a distributed drainage system also contributes to runoff at Austre Brøggerbreen. We have no independent means of testing the assumption at present. The lower concentrations of non-snowpack SO²⁻₄ at Austre Brøggerbreen may suggest that a smaller proportion of runoff originates from a distributed drainage system than at the Haut Glacier d'Arolla.     

Coastal permafrost landscape development since the Late Pleistocene in the western Laptev Sea,Siberia

Winterfeld, M., Schirrmeister, L., Grigoriev, M. N., Kunitsky, V. V., Andreev, A., Murray, A. & Overduin, P. P. 2011: Coastal permafrost landscape development since the Late Pleistocene in the western Laptev Sea, Siberia. Boreas, 10.1111/j.1502‐3885.2011.00203.x. ISSN 0300‐9483. The palaeoenvironmental development of the western Laptev Sea is understood primarily from investigations of exposed cliffs and surface sediment cores from the shelf. In 2005, a core transect was drilled between the Taymyr Peninsula and the Lena Delta, an area that was part of the westernmost region of the non‐glaciated Beringian landmass during the late Quaternary. The transect of five cores, one terrestrial and four marine, taken near Cape Mamontov Klyk reached 12 km offshore and 77 m below sea level. A multiproxy approach combined cryolithological, sedimentological, geochronological (¹⁴C‐AMS, OSL on quartz, IR‐OSL on feldspars) and palaeoecological (pollen, diatoms) methods. Our interpretation of the proxies focuses on landscape history and the transition of terrestrial into subsea permafrost. Marine interglacial deposits overlain by relict terrestrial permafrost within the same offshore core were encountered in the western Laptev Sea. Moreover, the marine interglacial deposits lay unexpectedly deep at 64 m below modern sea level 12 km from the current coastline, while no marine deposits were encountered onshore. This implies that the position of the Eemian coastline presumably was similar to today's. The landscape reconstruction suggests Eemian coastal lagoons and thermokarst lakes, followed by Early to Middle Weichselian fluvially dominated terrestrial deposition. During the Late Weichselian, this fluvial landscape was transformed into a poorly drained accumulation plain, characterized by widespread and broad ice‐wedge polygons. Finally, the shelf plain was flooded by the sea during the Holocene, resulting in the inundation and degradation of terrestrial permafrost and its transformation into subsea permafrost.     

Exploring till bed kinematics using AMS magnetic fabrics and pebble fabrics: the Weedsport drumlin field,New York State,USA

Gentoso, M. J., Evenson, E. B., Kodama, K. P., Iverson, N. R., Alley, R. B., Berti, C. & Kozlowski, A. 2012 (January): Exploring till bed kinematics using AMS magnetic fabrics and pebble fabrics: the Weedsport drumlin field, New York State, USA. Boreas, Vol. 41, pp. 31–41. 10.1111/j.1502‐3885.2011.00221.x. ISSN 0300‐9483. Thick, relatively homogeneous basal tills exposed in the drumlins and flutes of the Weedsport drumlin and flute field in New York State exhibit anisotropy of magnetic susceptibility (AMS) and pebble fabrics that are consistently oriented parallel to the streamlined bedforms. The pebble fabrics and AMS fabrics are concordant. In this study, six drumlins and five flutes were sampled. Thermally induced, incremental reduction of isothermal remanent magnetization indicates that AMS is caused by primarily elongate maghaemite grains. The orientations of principal axes of maximum susceptibility (k₁) are generally parallel to pebble long‐axis orientations, and tend to plunge mildly up‐glacier. Fabric directions are generally parallel to drumlin long‐axis orientations, but deviate by 12°–23° from flute directions. Fabrics of the flutes are stronger and more unidirectional than those of the drumlins. These results support the use of AMS as a fast and objective method for characterizing fabrics in tills, and suggest hypotheses about basal processes linked to glacially streamlined landforms.     

Glauconitization of detrital silica substrates in the Barton Formation (upper Eocene) of the Hampshire Basin, southern England

Upper Eocene detrital silica grains (chert and quartz) of the Hampshire Basin display alteration and replacement fabrics by glauconite. Silica grains have etched surfaces due to glauconitization which appear green in reflected light and thin section. Quartz grains were glauconitized by surface nucleation and replacement, which spreads from the margin with progressive glauconitization, replacing the quartz grain interior. Chert grains were glauconitized by surface replacement and nucleation internally along cracks and in pores. Different forms of glauconite are associated with the two minerals; glauconite associated with quartz is generally highly-evolved whereas glauconite associated with chert is of the evolved variety. This is interpreted as being due to different surface-reaction control mechanisms associated with the two forms of silica. There is no evidence to suggest that glauconite evolved in stages from a nascent form. Two crystalline morphological forms of glauconite are found associated with both quartz and chert. Glauconite growing within a confined space has a laminated morphology whilst glauconite occurring on the surface has a rosette morphology.