全球现代海底块状硫化物战略性金属富集机理及资源前景初探

海底块状硫化物(SMS)蕴藏有丰富的Cu、Cd、Au、Fe、Ag、Co等战略性金属,是未来可供人类开发利用的战略资源.本文搜集了全球3 946组SMS化学成分数据,根据构造环境可将其分成4类(快速、中速、慢速、超慢速扩张)洋中脊型和2类(弧后扩张中心和弧火山)岛弧型SMS矿床.利用多元统计方法分析了SMS战略性金属的分布特征和主控因素,探讨了其资源前景.结果表明:洋中脊型SMS矿床富集Cu+Fe+Co±Mo,而岛弧型普遍富集Zn+Pb+Cd+Sb+Ag±Au等关键元素.分析表明,成矿温度、成矿物质来源、酸碱度和氧化还原条件是战略性金属富集的主要影响因素,其中流体温度主要受水深条件控制,成矿物质来源主要受控于构造地质环境,酸碱度和氧化还原性主要受控于围岩类型.Cu+Au+Fe+Co在水深超过约2 650 m的慢速—超慢速扩张脊非转换不连续带和拆离断层带等区域具较好的勘查前景;而Cu+Au+Cd+Ag在水深约1 080~2 160 m的弧后扩张中心区域具较好的勘查前景.      

Fractional crystallization processes of magma beneath the Carlsberg Ridge(57°–65°E)

Fractional crystallization of basaltic magma at variable depths in?uences strongly the geochemical compositions of mid-ocean ridge basalts(MORBs), especially at slow-spreading mid-ocean ridges. The Carlsberg Ridge is a typical slow-spreading ridge located in the northwestern Indian Ocean. In this study, we conducted petrological, geochemical and modelling studies of MORBs collected along the Carlsberg Ridge from 57°–65°E to understand the fractional crystallization processes of magma and the controls on variations in MORB geochemistry. Our results show that the mantle sources beneath the Carlsberg Ridge are heterogeneous even on the local scale of a segment; such heterogeneity may be ubiquitous beneath the Carlsberg Ridge. Mantle heterogeneity may be caused by the enriched components resulting in the "DUPAL" anomaly, whereas the ef fect of pyroxenite on mantle heterogeneity is negligible. The parental melts experienced crystallization of olivine, plagioclase and clinopyroxene prior to eruption, which played a signi?cant role in the major and trace element variations in MORBs from the Carlsberg Ridge. The liquid lines of descent(LLDs), deduced from the forward modelling of three parental magma compositions using the Petrolog3 program at pressures between 1 atm and 10 kbar, demonstrate that clinopyroxene joined the olivine and plagioclase cotectic. The over-enrichment in highly incompatible elements relative to LLDs may be caused by the processes of replenishment-tapping-crystallization in magma chambers. The calculated crystallization pressures suggest that parental magmas beneath the Carlsberg Ridge experienced moderateto high-pressure crystallization and that crystallization beneath the slow-spreading Carlsberg Ridge may start at upper mantle depths.     

中印度洋脊Edmond热液区成矿流体属性与来源:来自流体包裹体和He-Ar同位素的证据

To understand the source and nature of the ore-forming fluids of the Edmond hydrothermal field on the Central Indian Ridge, we studied the He-Ar isotope composition and fluid inclusions of the hydrothermal precipitates.Our results show that the sulfide samples contain noble gases He, Ne, Kr, and Xe with their abundances in between those of air-saturated water(ASW) and mid-ocean ridge basalt(MORB). The ~3He/~4He ratio varies from1.3 to 8.7 R_a(n=10, average: 5.1 R_a), whereas the ~(40)Ar/~(36) Ar ratio is from 285.3 to 314.7(n=10, average: 294.8). These results suggest that the He was derived from a mixture of MORB with variable amounts of seawater, but the Ar in the ore-forming fluids trapped in the sulfides is predominantly derived from seawater. The fluid inclusions of barite have a wide range of homogenization temperatures and salinities varying from 163°C to 260°C and 2.6 wt%to 8.5 wt% Na Cl equiv., respectively. It is suggested that the ore-forming fluids were produced by phase separation, which agreed with the present-day vent fluid study.     

Turbidite Events Recorded in Deep-sea Core IR-GC1 off Western Sumatra: Evidence from Grain-size Distribution

Sediment core IR-GC1, from the abyssal basin of the Indian Ocean off Sumatra, may provide important information on depositional events related to earthquakes and tsunamis. In this study, based on a combination of grain-size analysis with lithological studies and oxygen isotope stratigraphy, seven deep-sea turbidite layers were identified, corresponding to seven turbidity events that occurred at 128–130, 105–107, 98–100, 86–87, 50–53, 37–41 and 20–29 ka. The sediments of the turbidite deposits are characterized by coarse grain sizes, poor sorting, wide kurtosis, bimodal frequency distributions and clear depositional variations. Particle size grading is also an important signature of deep-sea turbidite deposits and can be used as an indicator to identify turbidite layers. Possible triggering mechanisms for the turbidite events include tsunamis, earthquakes, volcanic eruptions and sea-level changes.     

西南印度洋49°～56°E洋脊段的热液羽状流:来自深水中的氦同位素异常证据

海水中的氦同位素能对海底热液活动进行有效示踪。本文对在西南印度洋49°~56°E洋脊段采集的5条CTD拖曳剖面共14件深水样品进行了氦氖同位素分析。通过分析水体中存在的氦同位素异常,探讨调查区热液异常的特征和热液羽状流的分布。分析表明,5条CTD剖面均存在δ3He异常,其中CTD7-2(位置:37.927°S、49.412°E,水深2 140m,离底高度100m)的δ3He值最大,达到49.2%。根据δ3He分布特征,认为调查区内存在至少6处热液羽状流,其中37.927°S、49.412°E以西数千米范围内可能存在海底热液喷口。     

苏门答腊外海13.5万年来的火山灰记录:来自深海沉积物岩心IR-GC1的证据

Three volcanic ash layers were identified in a deep-sea Core IR-GC1 from the north-eastern Indian Ocean, adjacent to western Indonesian arc. They were dominated by glass shards with minor mineral crystals, such as plagioclase, biotite, and hornblende. According to the morphology and major element compositions of the representative glass shards, combined with the δ18O-based age, it is suggested that ash Layer A is correlated to the youngest Toba tuff(YTT), Layer B is supposed to be associated with a new eruption of Toba caldera in an age of 98 to 100 ka. Ash Layer C is different the geochemistry characteristics than those of Layer A and Layer B, suggesting that Layer C was not originated from Toba but registered another volcanic eruption event.     

西北印度洋脊的厘定及其地质构造特征

西北印度洋的洋脊系统目前以"中印度洋脊"和"卡尔斯伯格脊"分别指示南北两段,两者的分界点被认为是澳大利亚板块与印度板块的板块边界与洋脊的交点,但具体分布位置不明确.基于已有的地质、地球物理和地球化学等多方面特征,认为卡尔斯伯格脊和中印度洋脊可以统一称为"西北印度洋脊",从罗德里格斯三联点一直延伸到欧文断裂带.新的洋脊厘定将有助于更全面地了解整个西北印度洋的洋脊演化和地球动力学过程.西北印度洋脊地形上南北两端断裂较少,中间断层密集,形似吸管的弯折部位,调节洋脊的转向.重力异常显示沿脊轴方向两端高中间低的特征,表明两端岩浆供给相对充足,而中间断层密集区岩浆量少.磁异常特征显示清晰的分带性,指示多阶段的洋脊扩张历史.岩石地球化学特征显示南北两个同位素相对富集洋脊段,可能与热点作用相关,或与残留岩石圈或地壳物质对亏损软流圈地幔的富集改造有关.     

Hydrothermal Activity Events at Kairei Field,Central Indian Ridge 25°S

The Kairei hydrothermal field is located on the Central Indian Ridge at 70°02′E, 25°19'S, which was discovered in 2000. Eight representative hydrothermal product samples including massive sulfide, sulfide chimney and mineralized rock breccia samples collected from this field were age‐dated using the ²³⁰Th/²³⁴U and ²¹⁰Pb/Pb methods. Four episodes of hydrothermal activity were determined: 94.5 to 96.3 ka (event I), 56.6 to 61.2 ka (event II), 8.4 to 10.6 ka (event III), and <180 a to present (event IV). Among them, event I is the oldest and is characterized by the low‐temperature mineralization of rock breccias which probably represents for the onset of the hydrothermal activity of the field. Events II to IV represent the episodic high‐temperature hydrothermal activities characterized by Cu and Zn‐rich sulfides. The recent hydrothermal activity has lasted for at least 180 a.     

利用西北印度洋船测数据评估基于卫星的海表面温度

本文描述了一次夏季在西北印度洋进行的调查船水文测量,用船测数据评估卫星海面表温度,并寻找影响海表面温度误差的主要因素。我们考虑了两种卫星数据,第一种是微波遥感产品——热带降雨测量任务微波成像仪TMI数据,另外一种是融合了微波,红外线,以及少部分观测数据的融合数据产品——可处理海表温度和海冰分析OSTIA数据。结果表明融合数据的日平均海表面温度的平均误差和均方根误差都比微波遥感小。这一结果证明了融合红外线遥感,微波遥感以及观测数据来提高海表面温度数据质量的必要性。此外,我们分析了海表面温度误差与各项水文参数之间的相关关系,包括风速,大气温度,想对湿度,大气压力,能见度。结果表明风速与TMI海表面温度误差的相关系数最大。而大气温度是影响OSTIA海表面温度误差最重要的因素;与此同时,想对湿度与海表面温度误差的相关系数也很高。