This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental
Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software
package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters
of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was
performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e.,
without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic
glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites,
fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and
a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements
(Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations,
similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis
which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to
the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture
of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger
of Sr and Ba is emphasized.
The Juqui circular intrusion, which is Cretaceous in age (130135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 335%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 55 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO2-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1429) for light rare earth elements(LREE) than for REE from Eu to Yb (4678),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K0 REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial 87Sr/86Sr ratios (mostly between07052 and 07057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0706007078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement. 相似文献
Robust decision-making is being increasingly used to support environmental resources decisions and policy analysis under changing climate and society. In this context, a robust decision is a decision that is as much as possible insensitive to a large degree of uncertainty and ensures certain performance across multiple plausible futures. Yet, the concept of robustness is neither unique nor static. Multiple robustness metrics, such as maximin, optimism-pessimism, max regret, have been proposed in the literature, reflecting diverse optimistic/pessimistic attitudes by the decision maker. Further, these attitudes can evolve in time as a response to sequences of favorable (or adverse) events, inducing possible dynamic changes in the robustness metrics. In this paper, we explore the impact of alternative definitions of robustness and their evolution in time for a case of water resources system management under changing climate. We study the decisions of the Lake Como operator, who is called to regulate the lake by balancing irrigation supply and flood control, under an ensemble of climate change scenarios. Results show a considerable variability in the system performance across multiple robustness metrics. In fact, the mis-definition of the actual decision maker’s attitude biases the simulation of its future decisions and produces a general underestimation of the system performance. The analysis of the dynamic evolution of the decision maker’s preferences further confirms the potentially strong impact of changing robustness definition on the decision-making outcomes. Climate change impact assessment studies should therefore include the definition of robustness among the uncertain parameters of the problem in order to analyze future human decisions under uncertainty. 相似文献
Since 2002 the Istituto Nazionale di Oceanografia e di Geofisica Sperimentale (OGS) in Udine (Italy), the Agencija Republike Slovenije za Okolje (ARSO) in Ljubljana (Slovenia) and the Zentralanstalt für Meteorologie und Geodynamik (ZAMG) in Vienna (Austria), are collecting, analyzing, archiving and exchanging seismic data in real time, initially in the framework of the EU Interreg IIIa Italia-Austria project “Trans-national seismological networks in the South-Eastern Alps”. As outcome of the successful cooperation, in the 2013 OGS, ARSO and ZAMG decided to officially merge their seismic monitoring efforts into the “Central and Eastern European Earthquake Research Network—CE3RN”. This work reports the results of a nine-month real-time test of the earthquake early warning (EEW) algorithm probabilistic and evolutionary early warning system carried out at the CE3RN. The study allowed identifying the actions to be implemented in order to let the CE3RN become in the next future an efficient cross-border EEW system.
The last few years have seen the debate on the geoethics of environmental and climatic protection growing to include resilience as a central idea within this new discipline, which holds many similarities with geography. Resilience analysis often looks at the capacity to re-establish conditions of equilibrium within a system which has been hit by a serious shock, e.g. a natural or man-made disaster. Geoethics works, in tandem with geological analyses and the geography of risk, to inform a population and develop integrated risk management in such a way as to strengthen a community’s resilience. The aim of this work is to study some people’s capacity to overcome what was potentially a disastrous event and, through a process of reconstruction, turn it into an occasion for growth. The experiment, carried out in the primary and middle schools in Aiello Calabro (Calabria, southern Italy), was conducted on the basis of the belief that there is a close relationship between a population’s having a realistic understanding of the risk of such an event, e.g. an earthquake, and high levels of resilience. We also tried to gain an insight into the relationship that may exist between resilience in primary and secondary school children and methods of coping which give an appropriate management of seismic risk. To be more precise, we try to discover whether there is a link between good/appropriate resilience and good/appropriate risk management.
Relative sea-level (RSL) evolution during Marine Isotopic Stage (MIS) 5 in the Mediterranean basin is still not fully understood despite a plethora of morphological, stratigraphic and geochronological studies carried out on highstand deposits of this area. In this review we assembled a database of 323 U/Th-dated samples (e.g. corals, molluscs, speleothems) which were used to chronologically constrain RSL evolution within MIS 5. The application of strict geochemical criteria to the U/Th samples indicates that only ~33% of data available for the Mediterranean Sea can be considered ‘reliable’. Most of these data (~65%) refer to the MIS 5e highstand, while only ~17% could be related to the MIS 5a. No attribution to MIS 5c can be unequivocally supported. Nevertheless, the resulting framework does not allow us to define a satisfactory RSL trend during the MIS 5e highstand and subsequent MIS 5 substages. Overall, the proposed selection of reliable/unreliable data would be useful for detecting areas where MIS 5 substage attributions are not supported by confident U/Th chronological data and thus the related reconstructions need to be revised. In this regard, the resulting framework calls for a reappraisal and re-examination of the Mediterranean records with advanced geochronological methodologies. 相似文献