Acid leaching of ash and coal: Time dependence and trace element occurrences

The leaching of coal and coal/asphaltite/wood-ashes in sulfuric acid (pH 1.0, 25 °C, S/L, 1:10) was studied as a function of time; acid consumption and extracted metal concentrations are presented. Whole coals consumed acid rapidly during the first few minutes, followed by slow acid consumption. Wood-, lignite-, and asphaltite-ashes consumed acid in two stages, the rapid phase extending < 30 min and the slow phase extended up to 10 days. The rapid phase was dominated by the dissolution of Ca, K and Mg ions for wood-ash, by Ca, Al and Mg ions for lignite-ash and Ca and Mg ions for asphaltite-ash. The sulfur concentration in solution and the concentrations of Ca, Fe, K, Mg, Na, P, Al and Mn in the aqueous phase verified the neutralizing capacity of the untreated ashes as well as the formation of insoluble sulfates in the residues. The slow phase kinetics differed for different fuels and exhibited leaching of several abundant elements—Fe, Al, K, Na and Mn. Trace elements (Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Th, U, V, Zn) sometimes required up to 32 h for maximal extraction from ashes. Suggestions are presented regarding the chemical nature of trace elements in the untreated coals and ashes and suitable residence times for economical industrial processes. We think it possible to combine bacteriological oxidation of sulfidic concentrates of acid leaching from ash of various qualities or even whole coals.     

Modelling of GPR waves for lossy media obeying a complex power law of frequency for dielectric permittivity

The attenuation of ground‐penetrating radar (GPR) energy in the subsurface decreases and shifts the amplitude spectrum of the radar pulse to lower frequencies (absorption) with increasing traveltime and causes also a distortion of wavelet phase (dispersion). The attenuation is often expressed by the quality factor Q. For GPR studies, Q can be estimated from the ratio of the real part to the imaginary part of the dielectric permittivity. We consider a complex power function of frequency for the dielectric permittivity, and show that this dielectric response corresponds to a frequency‐independent‐Q or simply a constant‐Q model. The phase velocity (dispersion relationship) and the absorption coefficient of electromagnetic waves also obey a frequency power law. This approach is easy to use in the frequency domain and the wave propagation can be described by two parameters only, for example Q and the phase velocity at an arbitrary reference frequency. This simplicity makes it practical for any inversion technique. Furthermore, by using the Hilbert transform relating the velocity and the absorption coefficient (which obeys a frequency power law), we find the same dispersion relationship for the phase velocity. Both approaches are valid for a constant value of Q over a restricted frequency‐bandwidth, and are applicable in a material that is assumed to have no instantaneous dielectric response. Many GPR profiles acquired in a dry aeolian environment have shown a strong reflectivity inside dunes. Changes in water content are believed to be the origin of this reflectivity. We model the radar reflections from the bottom of a dry aeolian dune using the 1D wavelet modelling method. We discuss the choice of the reference wavelet in this modelling approach. A trial‐and‐error match of modelled and observed data was performed to estimate the optimum set of parameters characterizing the materials composing the site. Additionally, by combining the complex refractive index method (CRIM) and/or Topp equations for the bulk permittivity (dielectric constant) of moist sandy soils with a frequency power law for the dielectric response, we introduce them into the expression for the reflection coefficient. Using this method, we can estimate the water content and explain its effect on the reflection coefficient and on wavelet modelling.     

Growth, ionic and osmotic relations of an Allenrolfea occidentalis population in an inland salt playa of the Great Basin Desert

Variation in growth, physiology and ionic relations patterns of Allenrolfea occidentalis, a perennial halophyte of dry habitats, was studied under field conditions from May 1996 to November 1997. An A. occidentalis community has a characteristic soil pH of 7·3–8·3. During the two years, the population was exposed to great variations in soil salinity, from 29 to 146 dS m⁻¹, and soil moisture, ranging from drought (9·2%) to wet (19%). The salt concentrations were significantly higher in the surface soil layers than in the subsurface layers. Seasonal changes in dry weight are directly related to soil salinity stress. Allenrolfea occidentalis had greater growth and biomass production under saline conditions. Na⁺and Cl⁻ions were accumulated in plant tissues in much greater amounts than K⁺, Ca²⁺, and Mg²⁺. Soil salinities were significantly reduced at the end of the growing season. Water potentials of the shoots decreased significantly with increasing salinity. The plant (F_v/F_mratio) was more affected by salinity and irradiation levels during the summer period.     

Vendian and Permian–Triassic Plagiogranite Magmatism of the Ust-Belaya Mountains,West Koryak Fold System,Northeastern Russia

Geotectonics - Vendian and Permian–Triassic plagiogranite magmatism is distinguished for the Ust-Belsky and Algansky terranes of West Koryak fold system. The U‒Pb zircon ages from...     

The influence of tectonic subsidence on volcaniclastic sedimentation: The Cretaceous upper Daeri Member,Wido Island,Korea

The Daeri Member, a Cretaceous volcanic–sedimentary succession, can be divided into lower, middle, and upper parts based on vertical changes in its lithologic characters. The lower Daeri Member is composed of siliciclastic deposits formed in a semi‐arid floodplain environment, which is overlain by the middle Daeri Member consisting mainly of andesite lava flow. After the emplacement of the andesite, activities of intrabasinal normal faults created accommodation on hanging wall blocks together with the development of intrabasinal topographic relief. The upper Daeri Member occurs only in hanging wall blocks and is composed of rhyolitic volcaniclastic sediments formed during an explosive volcanic eruption. Following the eruption, owing to semi‐arid climatic conditions and the destruction of vegetation, the eruptive materials were easily remobilized and deposited by episodic sediment gravity flows, resulting in deposition of the resedimented volcaniclastic deposits with sheet‐like geometry. Away from the intrabasinal normal faults, the resedimented volcaniclastic deposits show a decrease in grain size together with changes in inferred depositional processes from debris flows to hyperconcentrated flows and supercritical sheetfloods. This suggests that the resedimented volcaniclastic deposits were stacked on alluvial fan environments induced by intrabasinal topographic relief associated with normal fault activities. In addition, episodic movement of the faults gave rise to periodic fluctuation of the accommodation and an increase in gradient of the alluvial fan surface, resulting in the development of coarsening‐upward trends in the resedimented volcaniclastic deposits. The development of the alluvial fan and the coarsening‐upward trends indicate that dynamic tectonic subsidence and concomitant changes in the intrabasinal physiographic relief influenced the depositional processes and sizes of the transported volcaniclastic sediments of the upper Daeri Member. Thus, it is necessary to carefully observe tectonic signatures in volcaniclastic successions, particularly the syneruptive lithofacies, in order to reconstruct the tectonic and volcanic histories of receiving basins.     

Assessment of occupational risks from human health and environmental perspectives: a new integrated approach and its application using fuzzy BWM and fuzzy MAIRCA

Stochastic Environmental Research and Risk Assessment - Occupational safety issues encountered in the worksite environment are the issues that companies should consider in improving their...