Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.     

鲁苏榴辉岩的地球化学

以微量元素、稀土元素、Ｓｒ和Ｎｄ同位素变异特征为依据，确定鲁苏榴辉岩为多成因、多来源和多阶段，指出主要是在印支期扬子陆块与华北陆块碰撞造山作用过程中，挤入的上地幔碎片以及不同原岩类型的壳内高压变质岩碎块。燕山晚期的区域构造热事件使得某些榴辉岩的同位素体系再平衡。     

Geochemistry of the Mian-Lue ophiolites in the Qinling Mountains, central China: Constraints on the evolution of the Qinling orogenic belt and collision of the North and South China Cratons

The Anzishan ophiolite, a typical ophiolitic block of early Carboniferous age in the Mian-Lue suture zone of the Qinling Mountains, central China, consists of amphibolites/metabasalts, gabbros and gabbroic cumulates. All of these rocks, as well as those in the Hunshuiguan-Zhuangke (HZ) block, have compositions similar to normal MORB and back-arc basin basalts (BABB) with high ε_Nd(t) values, indicating that they were derived from a depleted mantle source. The Mian-Lue suture zone also contains blocks of other lithologies, e.g., rift volcanic rocks in the Heigouxia block and arc volcanic rocks in the Sanchazi block. Although they are in fault contact with each other, the presence of these different blocks in the Mian-Lue suture zone may represent a complete Wilson cycle, from initial rifting to open ocean basin to final subduction and continent-continent collision, during the late Paleozoic-early Triassic. In this region, the North and South China Cratons were separated by Paleo-Tethys at least until the early Carboniferous, and final amalgamation of both cratons along the Qinling orogenic belt took place in the Triassic.     

生物炭对磷石膏中磷的固化作用

磷石膏中的磷在雨水淋滤作用下浸出,将污染堆场附近水体。本研究采用生物炭固化磷石膏中的磷,以减少其对周遭水体的污染。主要通过模拟固化实验和对照浸出实验,分析生物炭用量、反应时间和温度、初始pH值对固化效果的影响,通过XRD、SEM-EDS分析固化后的生成物。实验结果显示,在生物炭用量为25 mg时,单位固化量达到最大值13.20 mg/g;在反应温度T=293 K、初始pH=7条件下,反应平衡时间72 h时浸出液的磷平衡浓度C_e= 1.40 mg/L;温度提升有助于提高生物炭的固化效果,当T=308 K时,浸出液的磷平衡浓度C_e=0.167 mg/L;碱性条件有利于固化反应持续进行,在pH=11条件下,浸出液的磷平衡浓度C_e=0.153 mg/L。实验结果表明生物炭对磷石膏中的磷具有明显的固化效果。磷石膏中的二水硫酸钙溶解后,Ca²⁺与表面带负电的生物炭结合,在生物炭显微结构的凹陷处,化学吸附溶液中的磷酸根生成了絮状、团簇状的羟基磷灰石(HAP)沉淀,从而使浸出磷得到有效控制。     

鄂尔多斯盆地的三维可视化及其应用

地形三维可视化作为测绘行业的一项新技术正处于蓬勃发展阶段。本文以鄂尔多斯盆地为例，着重介绍了基于ARCGIS9．0的三维可视化建库、实现过程，并指出其在矿产勘探中的具体应用。     

由一次西周日食记载得到的地球自转变化

本文结合１９９７年３月９日全食的新疆观测及地球自转变化趋势讨论了发生在中国西周时期的一次日食的记载，以及由此得到的地球自转速度变化值。     

Meteoric diagenesis in Pleistocene reef limestones of Xisha Islands, China

This paper focuses on a borehole, Xichen-1 well, drilled on the Chenhang Island, Xisha Islands in the South China Sea. Mineralogical, petrographic, stable isotopic and minor-element data from the Holocene to Pleistocene interval (0–179 m ) in the Xichen-1 well are discussed in detail. The 400-m-long core is divisible into four mineralogical facies: a high-Mg calcitic aragonite facies (0–16.91 m, Holocene), an aragonitic low- Mg calcite facies (16.91–30.60 m, Late Pleistocene), a low- Mg calcitic facies (30.60–179 m, Middle-Early Pleistocene) and a low- Mg calcitic and dolomitic facies (179–400 m, Early Pleistocene–Late Miocene). The Holocene section has much higher whole-rock δ¹⁸O and δ¹³C values and Mg and Sr content than the non-dolomitized Pleistocene limestones (16.91–179 m). The 16.91–165 m interval is characterized by a relatively invariant oxygen isotopic composition and very heterogeneous carbon isotopic composition. Between 165 and 179 m, there is a positively correlated increase of whole-rock δ¹⁸O and δ¹⁸C with depth, and Mg content also shows a gradual increase with depth. Petrographic data demonstrate that the Pleistocene reef sequence has been extensively affected by meteoric waters. We conclude that the Late Pleistocene section (16.91–30.60 m) and the Middle-Early Pleistocene section (30.60–165 m) have suffered incomplete and complete meteoric diagenesis, respectively, and that the Early Pleistocene interval (165–179 m) was diagenetically altered in a meteoric–marine mixing environment.     

极化分析研究及其在波场分离中的应用

不同的波在空间的质点运动轨迹和极化方向是不同的，利用三分量或二分量记录，在特定的以ｔ０为中心，长为Ｎ△ｔ的滑动时窗中计算出描述波的质点运动轨迹和极化方向的特征参数。利用这些参数可以设计出合适的极化滤波函数，保留那些满足特定要求的质点运动，而衰减那些不满足设计要求的质点运动，利用某些算子可以把弹性波分解成Ｐ波和ＳＶ波，而且衰减面波；利用另外一些算子可以把Ｐ波和ＳＶ波衰减而使面波增强。这些算子甚至可以在嗓音和信号具有相同频率的情况下，成功地提高信嗓比。     

生态系统地震灾害初步研究

研究地震灾害的目的是为了保护人类.人类与周围的环境组成一个密不可分的系统,这个系统即生态系统.截止目前地震灾害的研究还局限在直观的人员伤亡和建筑物破坏,尚未涉及地震对生态系统的灾害影响,从而也未注意地震给人类带来的间接、众多、较长期的灾害影响.要真正保护人类免受地震灾害,就需要研究认识生态系统地震灾害.以人类为核心,按照构成生态系统的主体和环境因子的不同,可将生态系统由内向外、逐层包容地划分成社会生态系统、环境生态系统和自然生态系统三个层次类型.     

基于GPS掩星技术反演大气参数模型的优化

准确掌握地球大气中的水气分布，了解水气变化趋势对天气现象、全球气候变化、数值预报具有理论研究及实用价值。以无线电掩星技术为基础，利用掩星数据反演大气参数剖面。对原反演模型的不足进行了论证，并给出了反演个例。详细地论述了通过引入MM5先验温度T再通过线性迭代的方法反演对流层下部水汽廓线原理，给出了优化后模型反演个例。并对模型优化后反演廓线中存在的问题进行了分析，提出了下一步优化方向。