乙酰褐藻酸丙二酯的制备与表征

为了改变褐藻酸丙二酯的溶解性,本文以氢碘酸为催化剂,将褐藻酸丙二酯与乙酐反应,制备了乙酰褐藻酸丙二酯。生成物不溶于水,可溶于多种中等极性的有机溶剂。本文用IR,~1H-NMR,HGPC对其进行了表征,并对反应条件对产率的影响进行了探讨。     

水下发射超空泡射弹对UUV平台姿态影响分析

超空泡射弹武器能够突破普通射弹水中运动极限,有效打击水雷等水下目标。针对水下发射超空泡射弹武器的平台适应性开展了初步研究,建立了超空泡射弹武器及 UUV 搭载平台仿真模型,计算分析了水下超空泡射弹武器在不同方位、不同角度发射时 UUV 平台姿态角的变化,得到了水下发射超空泡射弹对 UUV 平台姿态的影响规律,为水下超空泡射弹武器系统及其平台适配性研究提供了依据。     

康古尔塔格硅灰石矿床地质特征与成矿条件分析

作者首次在该区找到了硅灰石矿。在专题研究基础上，分析了区域地层、构造、岩浆活动和硅灰石矿床地质特征等，提出该硅灰石矿主要产于康古尔断裂带内的花岗岩与碳酸盐地层接触带，属矽卡岩型硅灰石矿。对区内花岗岩、碳酸盐地层、矽卡岩、大地构造等硅灰石成矿条件作了分析，初步提出了该矿主要应用领域为建筑陶瓷工业。     

Geology and isotopic composition of helium,neon, xenon and metallogenic age of the Jinding and Baiyangping ore deposits,northwest Yunnan,China

TheJindingoredeposit,locatedinthenorthwestYunnanProvince,isthelargestPb-Zndeposit(Pb Zn>15Mt1),averagingZn=6.08%andPb/Zn=1/4.7)inChinaatpresent.Toitsnorth,alargeCu-Co-AgdeposithasbeenfoundatBaiyangpingrecently1).TheJindingPb-Zndepositishostedinsandstonesa…     

电活化硫酸盐处理四环素类废水的研究

本文构建以掺硼金刚石(Boron-doped diamond,BDD)为阳极、不锈钢为阴极、硫酸盐为电解质的电化学体系,考察了电流密度、pH值、硫酸盐浓度以及初始四环素浓度等四个因素对电化学氧化降解废水中四环素的影响,运用响应曲面法对运行参数进行优化;通过电子自旋共振检测技术分析电化学反应中产生的自由基,探究了间歇通电模式下电化学体系持续氧化机理。结果表明,四个因素对TOC去除率的影响大小次序为:电流密度>初始四环素浓度>初始pH值>硫酸盐浓度,其中初始pH值和硫酸盐浓度与电流密度和初始四环素浓度的交互作用对TOC去除率的影响较为显著;最佳运行参数为pH值为5,电流密度为100 mA·cm^-2,硫酸盐浓度为0.25 mol·L^-1,初始四环素浓度为1000 mg·L^-1;间歇通电模式下,BDD电极表面产生的SO₄^·-等高活性物质间相互转化提供了体系的可持续氧化能力。该研究结果为电化学氧化技术的实际应用提供了节省能耗的有效途径。     

南秦岭主要类型热水沉积岩的REE地球化学

南秦岭泥盆纪沉积柱中产有多种类型海底热水沉积岩．它们的ΣＲＥＥ偏低（平均６３．０９×１０－６），ＲＥＥ配分曲线平缓右倾，Ｌａ／Ｙｂ＝２～８，Ｃｅ亏损，总体上与海水相似。产于Ｓｅｄｅｘ含矿层中的热水沉积岩具有正Ｅｕ异常，与现代海底热液及红海热液沉积物可比；而产在Ｓｅｄｅｘ含矿层以下地层中的热水沉积岩Ｅｕ亏损，与ＥＰＲ热液沉积物相似。ＲＥＥ地球化学研究和岩石学研究结果一致，支持热水沉积岩ＲＥＥ来源于海水及部分下伏沉积柱（包括基底），含矿热水沉积岩是盆地热演化到一定阶段具有一定深度和规模的循环对流体系在海底的化学沉积，而Ｓｅｄｅｘ含矿层以下地层中的热水沉积岩则是浅部热水对流循环的海底显示．成岩和变质作用对岩石的ＲＥＥ未造成影响。     

甘肃桦树沟铁铜矿床地球化学及成因

甘肃桦树为铁铜矿床地质、同位素地球化学、包裹体地球化学、同位素年代学研究表明，该矿床形成于震旦纪裂陷海盆环境，矿床成因属典型的热水沉积成矿。     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.     

Giant Mineral Deposits and Their Geodynamic Setting in the Lanping Basin, Yunnan, China

There are giant mineral deposits, including the Jinding Zn-Pb and Baiyangping Ag-Co-Cu, and otherimportant mineral deposits (e.g., Baiyangchang Ag-Cu, Jinman Cu deposits, etc.) in the Lanping Mesozoic-Cenozoic Basin, Yunnan Province, China. The tabular ore-bodies and some veins hosted in terrestrial clastic rocks of the Mesozoic-Cenozoic age and no outcropping of igneous rocks in the giant deposits lead to the proposal of syngenetic origin, but the giant mineral deposits are not stratabound (e.g. MVT, sandstone- and Sedex-type). They formed in a continental red basin with intense crust movement. The mineralization is controlled by structures and lithology and occurs in different strata, and no sedimentary nature and no exhalative sediments are identified in the deposits. The deposits show some relations with organic matter (now asphalt and petroleum) and evaporates (gypsum). The middle-low-temperature (mainly 110℃ to 280℃) mineralization took place at a depth of about 0.9 km to 3.1 km during the early