In situ strength measurements on natural upper-mantle minerals

Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with the residual pressure of fluid inclusions in mantle xenoliths.     

Issues of Globalization and Reflexivity in the Japanese Tourism Production System: The Case of Whistler,British Columbia

This article examines contemporary Japanese overseas tourism from a supplier‐side perspective using the concept of production systems. We first outline characteristics of the evolving structure of Japanese overseas tourism, with an emphasis on the global spread of Japanese travel companies. This provides a frame for presenting an empirical account of the transactional relationships in the Japanese package tour production system in Whistler, British Columbia, where Japanese tour operators play a pivotal role. We conclude that the recent expansion of Japanese travel companies is fostering the functional integration of the global tourism production system and exhibits increasing reflexivity.     

Observations of flux rope – associated particle bursts with GEOTAIL in the distant tail

Geotail energetic particle, magnetic field data and plasma observations (EPIC, MGF and CPI experiments) have been examined for a number of energetic particle bursts in the distant tail (120Re < |X_GSM| < 130 Re), associated with moving magnetic field structures, following substorm onsets. The features obtained from this data analysis are consistent with the distant magnetotail dynamics determined first by ISEE3 observations and explained in terms of the neutral line model. At the onset of the bursts, before plasma sheet entrance, energetic electrons appear as a field-aligned beam flowing in the tailward direction, followed by anisotro-pic ions. Within the flux rope region, suprathermal ions exhibit a convective anisotropy, which allows determination of the plasma flow velocity, assuming that the anisotropy arises from the Compton-Getting effect. The velocities thus determined in the plasma sheet are estimated to be 200–650 km/s, and compare favourably with the velocities derived from the CPI electron and proton experiment. The estimated length of magnetic field structures varies between 28 and 56 Re and depends on the strength of the westward electrojet intensification. Finally, the three structures reported here show clear magnetic field signatures of flux rope topology. The existence of a strong magnetic field aligned approximately along the Y-axis and centred on the north-to-south excursion of the field, and the bipolar signature in both By and/or Bz components, is consistent with the existence of closed field lines extending from Earth and wrapping around the core of the flux rope structure.     

Carbon isotopes and petrography of kerogens in ∼3.5-Ga hydrothermal silica dikes in the North Pole area, Western Australia

More than 600 specimens of ∼3.5 Ga-old hydrothermal silica dikes from the North Pole area, Pilbara craton, Western Australia, have been studied petrographically. The kerogens in 44 samples have been analyzed isotopically (C and N) and chemically (C, N, and H). The silica dikes are composed mainly of fine-grained silica (modal abundance: >97%) and are classified into two types by minor mineral assemblages: B(black)-type and G(gray)-type. The B-type silica dikes contain kerogen (0.37 to 6.72 mgC/g; average 2.44 mgC/g, n = 21) and disseminated sulfides, dominantly pyrite and Fe-poor sphalerite. In some cases, carbonate and apatite are also present. Their silica-dominated and sulfide-poor mineral assemblages suggest precipitation from low-temperature reducing hydrothermal fluid (likely 100-200°C). On the other hand, the G-type silica dikes are sulfide-free and concentrations of kerogen are relatively low (0.05 to 0.41 mgC/g; average 0.17 mgC/g, n = 13). They typically contain Fe-oxide (mainly hematite) which commonly replaces cubic pyrite and rhombic carbonate. Some G-types occur along secondary quartz veins. These textures indicate that the G-type silica dikes were formed by postdepositional metasomatism (oxidation) of the B-types, and that the B-types probably possess premetasomatic signatures. The δ¹³C values of kerogen in the B-types are −38.1 to −33.1‰ (average −35.9‰, n = 21), which are ∼4‰ lower than those of the G-types (−34.5 to −30.0‰; average −32.2‰, n = 19), and ∼6‰ lower than bedded chert (−31.2 to −29.4‰; average −30.5‰, n = 4). This indicates the preferential loss of ¹²C during the metasomatism (estimated fractionation factor: 0.9985). Considering the metasomatic effect on carbon isotopes with probably minor diagenetic and metamorphic overprints, we conclude that the original δ¹³C values of the kerogen in the silica dikes would have been heterogeneous (∼5‰) and at least some material had initial δ¹³C values of ≤ −38‰. The inferred ¹³C-depletions of organic carbon could have been produced by anaerobic chemoautotrophs such as methanogen, but not by aerobic photoautotrophs. This is consistent with the estimated physical and chemical condition of the hydrothermal fluid, which was probably habitable for anaerobic and thermophilic/hyperthermophilic chemoautotrophs. Alternatively, the organic matter may have been possibly produced by abiological reaction such as Fischer-Tropsch Type (FTT) synthesis under the hydrothermal condition. However, the estimated condition is inconsistent with the presence of the effective catalysts for the FTT reaction (i.e., Fe-Ni alloy, magnetite, and hematite). These lines of evidence suggest the possible existence of biosphere in the ∼3.5 Ga sub-seafloor hydrothermal system.     

Correcting the Smoothing Effect of Ordinary Kriging Estimates

The smoothing effect of ordinary kriging is a well-known dangerous effect associated with this estimation technique. Consequently kriging estimates do not reproduce both histogram and semivariogram model of sample data. A four-step procedure for correcting the smoothing effect of ordinary kriging estimates is shown to be efficient for the reproduction of histogram and semivariogram without loss of local accuracy. Furthermore, this procedure provides a unique map sharing both local and global accuracies. Ordinary kriging with a proper correction for smoothing effect can be revitalized as a reliable estimation method that allows a better use of the available information.     

High-reliability zircon separation for hunting the oldest material on Earth: An automatic zircon separator with image-processing/microtweezers-manipulating system and double-step dating

Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons.     

A computational procedure for joining separate map sheets

Map sheets have been often used as a basic spatial unit for managing spatial data produced from paper maps. This often results in incompatibility between adjacent map sheets, because spatial objects do not cross the boundaries smoothly and even the boundaries themselves do not match their neighbors exactly. To solve the problem this paper proposes a computational procedure for joining separate map sheets to obtain seamless spatial data. Line objects digitized separately in different map sheets are considered, which are frequently used to represent road networks, gas pipelines, and boundaries of polygon objects. The procedure consists of three steps: (1) extraction of end nodes, (2) detection of matching nodes, and (3) transformation of the map sheet. Each step goes interactively so that unexpected errors can be avoided by human observation. To test the validity of the procedure, map sheets are combined containing the road network data of Tokyo 23-ku area, Japan. This revised version was published online in July 2006 with corrections to the Cover Date.     

Prediction method of sand-movement direction in water by geochemical elements

The analysis of sand samples by x-ray fluorescent spectroscopy (XRF) gives the ratio of the geochemical elements to construct the sand samples. The x-ray analysis therefore shows the geochemical characteristics of sand in the sampled area. In this study, sand is sampled on coasts and rivers of the Noto Peninsula to determine the geochemical elements and to show the geological characteristics that occur, especially iron and calcium. The experiments show the effect of rivers and Kotogahama beach on iron and calcium, respectively. Applying the method of ratio matching to the measured data of the geochemical elements, the direction of movement of sand on the coast is determined by considering the correlation matrix and the ratio of geochemical elements between sand samples at two locations. The predominant longshore direction movement of sand offshore in the study area is from south to north. Sand in rivers is not directly transported to adjacent beaches; however, offshore sand is transported to beaches. The estimated direction of movement of sand longshore near coastal structures agrees with observations. The proposed method to predict the direction of movement of sand gives the correct one in comparison with the observed data in rivers.     

Illawarra Reversal: The fingerprint of a superplume that triggered Pangean breakup and the end-Guadalupian (Permian) mass extinction

The Permian magnetostratigraphic record demonstrates that a remarkable change in geomagnetism occurred in the Late Guadalupian (Middle Permian; ca. 265 Ma) from the long-term stable Kiaman Reverse Superchron (throughout the Late Carboniferous and Early-Middle Permian) to the Permian–Triassic Mixed Superchron with frequent polarity changes (in the Late Permian and Triassic). This unique episode called the Illawarra Reversal probably reflects a significant change in the geodynamo in the outer core of the planet after a 50 million years of stable geomagnetism. The Illawarra Reversal was likely led by the appearance of a thermal instability at the 2900 km-deep core–mantle boundary in connection with mantle superplume activity. The Illawarra Reversal and the Guadalupian–Lopingian boundary event record the significant transition processes from the Paleozoic to Mesozoic–Modern world. One of the major global environmental changes in the Phanerozoic occurred almost simultaneously in the latest Guadalupian, as recorded in 1) mass extinction, 2) ocean redox change, 3) sharp isotopic excursions (C and Sr), 4) sea-level drop, and 5) plume-related volcanism. In addition to the claimed possible links between the above-listed environmental changes and mantle superplume activity, I propose here an extra explanation that a change in the core's geodynamo may have played an important role in determining the course of the Earth's surface climate and biotic extinction/evolution. When a superplume is launched from the core–mantle boundary, the resultant thermal instability makes the geodynamo's dipole of the outer core unstable, and lowers the geomagnetic intensity. Being modulated by the geo- and heliomagnetism, the galactic cosmic ray flux into the Earth's atmosphere changes with time. The more cosmic rays penetrate through the atmosphere, the more clouds develop to increase the albedo, thus enhancing cooling of the Earth's surface. The Illawarra Reversal, the Kamura cooling event, and other unique geologic phenomena in the Late Guadalupian are all concordantly explained as consequences of the superplume activity that initially triggered the breakup of Pangea. The secular change in cosmic radiation may explain not only the extinction-related global climatic changes in the end-Guadalupian but also the long-term global warming/cooling trend in Earth's history in terms of cloud coverage over the planet.